Exam 6: Energy Relationships in Chemical Reactions

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What would be the standard enthalpy change for the reaction of one mole of H2(g)with one mole of Cl2(g)to produce two moles of HCl(g)at standard state conditions? [ Δ\Delta H°f (HCl(g))= -92.3 kJ/mol]

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A 0.3423 g sample of pentane, C5H12, was burned in a bomb calorimeter. The temperature of the calorimeter and the 1.000 kg of water contained therein rose from 20.22°C to 22.82°C. The heat capacity of the calorimeter is 2.21 kJ/°C. The heat capacity of water = 4.184 J/g·°C. How much heat was given off during combustion of the sample of pentane?

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When an automobile engine starts, the metal parts immediately begin to absorb heat released during the combustion of gasoline. How much heat will be absorbed by a 165 kg iron engine block as the temperature rises from 15.7°C to 95.7°C? (The specific heat of iron is 0.489 J/g·°C.)

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The specific heat of gold is 0.129 J/g·°C. What is the molar heat capacity of gold?

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How many grams of ethylene (C2H4)would have to be burned to produce 450 kJ of heat? C2H4(g)+ 3O2(g) →\rarr 2CO2(g)+ H2O(l) Δ\Delta H°rxn= -1411 kJ/mol

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For which of these reactions will the difference between Δ\Delta H° and Δ\Delta E° be the greatest?

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The specific heats of water and iron are 4.184 and 0.444 J/g°C, respectively. When equal masses of water and iron both absorb the same amount of heat, the temperature increase of the water will be 5.42 times greater than that of the iron.

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The residential rate for natural gas is about $15 per thousand cubic foot. Burning one cubic foot of natural gas releases about 1080 kJ of heat. How much would it cost to heat the water in a 25,000 gallon swimming pool from 52°F to 78°F, assuming all of the heat from burning the natural gas went towards warming the water? (1 gal = 3.785 L; the specific heat of water = 4.184 J/g·°C)

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Find Δ\Delta H°rxn for the reaction 2Ag2S(s)+ 2H2O(l) →\rarr 4Ag(s)+ 2H2S(g)+ O2(g). [ Δ\Delta H°f (Ag2S(s))= -32.6 kJ/mol; Δ\Delta H°f (H2S(g))= -20.5 kJ/mol; Δ\Delta H°f (H2O(l))= -285.5 kJ/mol]

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The heat of neutralization of HCl by NaOH is Δ\Delta H°rxn = -56.2 kJ/mol. How much heat is released when 125 mL of 1.750 M HCl is mixed with 195 mL of 0.667 M NaOH?

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Given the thermochemical equation 2SO2(g)+ O2(g) →\rarr 2SO3(g), Δ\Delta H°rxn= -198 kJ/mol, how much heat is evolved when 600. g of SO2 is burned?

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Calculate the amount of work done, in joules, when 2.5 mole of H2O vaporizes at 1.0 atm and 25°C. Assume the volume of liquid H2O is negligible compared to that of vapor. (1 L·atm = 101.3 J)

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A glass containing 200. g of H2O at 20°C was placed in a refrigerator. The water loses 11.7 kJ as it cools to a constant temperature. What is its new temperature? The specific heat of water is 4.184 J/g·°C.

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A feverish student weighing 75 kilograms was immersed in 400. kg of water at 4.0°C to try to reduce the fever. The student's body temperature dropped from 40.0°C to 37.0°C. Assuming the specific heat of the student to be 3.77 J/g·°C, what was the final temperature of the water?

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Given that CaO(s)+ H2O(l) →\rarr Ca(OH)2(s), Δ\Delta H°rxn = -64.8 kJ/mol, how many grams of CaO must react in order to liberate 525 kJ of heat?

(Multiple Choice)
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Glycine, C2H5O2N, is important for biological energy. The combustion reaction of glycine is given by the equation 4C2H5O2N(s)+ 9O2(g) →\rarr 8CO2(g)+ 10H2O(l)+ 2N2(g) Δ\Delta H°rxn = -3857 kJ/mol Given that Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol and Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol, calculate the enthalpy of formation of glycine.

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A beaker contains 115 g of ethanol at 18.2°C. If the ethanol absorbs 1125 J of heat without losing heat to the surroundings, what will be the final temperature of the ethanol? The specific heat of ethanol is 2.46 J/g.°C.

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Copper metal has a specific heat of 0.385 J/g·°C. Calculate the amount of heat required to raise the temperature of 22.8 g of Cu from 20.0°C to 875°C.

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At 25°C, the standard enthalpy of formation of KCl(s)is -435.87 kJ/mol. When one mole of KCl(s)is formed by reacting potassium vapor and chlorine gas at 25°C, the standard enthalpy of reaction is -525.86 kJ/mol. Find Δ\Delta H° for the sublimation of potassium, K(s) →\rarr K(g), at 25°C.

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Ozone (O3)in the atmosphere can be converted to oxygen gas by reaction with nitric oxide (NO). Nitrogen dioxide is also produced in the reaction. What is the enthalpy change when 8.50L of ozone at a pressure of 1.00 atm and 25°C reacts with 12.00 L of nitric oxide at the same initial pressure and temperature? [ Δ\Delta H°f(NO)= 90.4 kJ/mol; Δ\Delta H°f(NO2)= 33.85 kJ/mol; Δ\Delta H°f(O3)= 142.2 kJ/mol]

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