Exam 13: Nuclear Magnetic Resonance Spectroscopy

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Compound I has a molecular formula of C7H16. In 13C NMR, compound I gave 3 peaks and in 1H NMR it also gave 3 peaks, a doublet, a triplet and a multiplet. Provide a structure for compound I.

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On a 90 MHz spectrometer, calculate the frequency at which a proton absorbs if it appears at 4.20 ppm.

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Why is carbon-carbon splitting typically not seen in 13C NMR spectra?

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Give one reason why 13C NMR is less sensitive than 1H NMR.

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How might the proton spectrum of ultrapure dimethylamine, (CH3)2NH, differ from the spectrum of this compound to which D2O has been added?

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Provide a structure that is consistent with the data below. C7H14O2 IR (cm-1): 2950, 1740 1H NMR ( d): 2.3 (2H, q), 1.0 (3H, t), 0.9 (9H, s) 13C NMR (d ): 185 (s), 78 (s), 29 (t), 14 (q), 12 (q)

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Describe the number of signals and their splitting in the 1H NMR spectrum of (CH3)2CHOCH3.

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The energy difference between the allowed spin states for an 1H nucleus is ________ the strength of the external magnetic field in which it is placed.

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How many peaks appear in the proton spin decoupled 13C NMR spectrum of the compound below? How many peaks appear in the proton spin decoupled <sup>13</sup>C NMR spectrum of the compound below?

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How many peaks appear in the proton spin decoupled 13C NMR spectrum of the compound below? How many peaks appear in the proton spin decoupled <sup>13</sup>C NMR spectrum of the compound below?

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