Exam 6: Alkyl Halides: Nucleophilic Substitution and Elimination

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When 3-iodo-3-ethylpentane is treated with sodium methoxide in methanol, the major organic product is an ________ that is generated through an ________ mechanism.

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Provide the structure of the major organic product which results in the following reaction. Provide the structure of the major organic product which results in the following reaction.

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Which of the following is a secondary halide?

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Provide the major organic product of the reaction below. Provide the major organic product of the reaction below.

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Which of the following is a tertiary halide?

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Draw two reasonable resonance structures and the hybrid of the intermediate formed in the following reaction. Draw two reasonable resonance structures and the hybrid of the intermediate formed in the following reaction.

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Which of the following alkyl chlorides would undergo substitution most rapidly when treated with Which of the following alkyl chlorides would undergo substitution most rapidly when treated with     or   Provide the structure of the substitution product. Which of the following alkyl chlorides would undergo substitution most rapidly when treated with     or   Provide the structure of the substitution product. or Which of the following alkyl chlorides would undergo substitution most rapidly when treated with     or   Provide the structure of the substitution product. Provide the structure of the substitution product.

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Draw the structure of cis-1,3-dichlorocyclopentane.

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List the following bromides in order of their increasing reactivity as substrates in SN1 reactions: PhBr, PhCH2Br, and PhCH(CH3)Br.

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Complete the following SN2 reaction by providing structures for the necessary starting materials. Complete the following S<sub>N</sub>2 reaction by providing structures for the necessary starting materials.

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Predict the most likely mechanism for the reaction shown below. Predict the most likely mechanism for the reaction shown below.

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Which of the following is a vicinal dihalide?

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What type of solvent is best for SN2 reactions which employ anionic nucleophiles: polar, protic solvents; polar, aprotic solvents; or nonpolar solvents? Explain.

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Provide an acceptable name for CH3CH2CH2C(CH3)2I.

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Which of the following is a primary alkyl halide?

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Which of the following alkyl halides reacts most rapidly via an SN1 solvolysis reaction in hot methanol?

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Which of the following is classified as a vinylic halide?

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Provide the structure of the major organic product in the following reaction. (CH3)3N + CH3CH2CH2I →

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List the following alkyl halides in order of their increasing reactivity as substrates in SN2 reactions: 2-chlorobutane, 2-iodobutane, and 1-iodobutane.

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Provide the structure of the major organic product in the reaction below. Provide the structure of the major organic product in the reaction below.

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