Question 1

What is the relationship between alcohols I and II?   They are:

Accepted Answer

A)  different conformations of the same compound. 
B)  constitutional isomers. 
C)  enantiomers. 
D)  diastereomers. 
E)  identical. 
A)  different conformations of the same compound. 
B)  constitutional isomers. 
C)  enantiomers. 
D)  diastereomers. 
E)  identical.

Question 2

What is the relationship between alcohols I and II?   They are:

Accepted Answer

A)  different conformations of the same compound. 
B)  constitutional isomers. 
C)  enantiomers. 
D)  diastereomers. 
E)  identical. 
A)  different conformations of the same compound. 
B)  constitutional isomers. 
C)  enantiomers. 
D)  diastereomers. 
E)  identical.

Question 3

Oxymercuration-demercuration of 3-methylcyclopentene produces this/these product(s):

Accepted Answer

A)  I 
B)  II 
C)  III 
D)  IV 
E)  Both III and IV 
A)  I 
B)  II 
C)  III 
D)  IV 
E)  Both III and IV

Question 4

Which of the reagents listed below would serve as the basis for a simple chemical test to distinguish between

Accepted Answer

A)  AgNO3 in alcohol 
B)  NaOH in H2O 
C)  Br2 in CCl4 
D)  Cold concd.H2SO4 
E)  KMnO4 in H2O 
A)  AgNO3 in alcohol 
B)  NaOH in H2O 
C)  Br2 in CCl4 
D)  Cold concd.H2SO4 
E)  KMnO4 in H2O

Question 5

Draw all of the primary alcohols corresponding to the formula C5H12O,including stereoisomers.

Accepted Answer

Question 6

When 3-methyl-2-pentene is treated with mercuric acetate,Hg(O2CCH3)2,in a THF-ethanol mixture and the resulting product reacted with NaBH4 in basic solution,the principal product formed is which of these?

Accepted Answer

A)  3-methyl-3-pentanol 
B)  3-ethoxy-3-methylpentane 
C)  3-methyl-2-pentanol 
D)  2-ethoxy-3-methylpentane 
E)  1-ethoxy-3-methylpentane 
A)  3-methyl-3-pentanol 
B)  3-ethoxy-3-methylpentane 
C)  3-methyl-2-pentanol 
D)  2-ethoxy-3-methylpentane 
E)  1-ethoxy-3-methylpentane

Question 7

Anti-Markovnikov hydration of the carbon-carbon double bond occurs when an alkene reacts with:

Accepted Answer

A)  BH3:THF;then H2O2/OH- 
B)  BH3:THF;then CH3COOH 
C)  Hg(OAc)2,THF,H2O;then NaBH4,OH- 
D)  Hg(OAc)2,THF,CH3OH;then NaBH4,OH- 
E)  Hg(OAc)2,THF,H2O;then BH3:THF 
A)  BH3:THF;then H2O2/OH- 
B)  BH3:THF;then CH3COOH 
C)  Hg(OAc)2,THF,H2O;then NaBH4,OH- 
D)  Hg(OAc)2,THF,CH3OH;then NaBH4,OH- 
E)  Hg(OAc)2,THF,H2O;then BH3:THF

Question 8

Supply the missing reagents A and B.

Accepted Answer

The answer of Supply the missing reagents A and B....

Question 9

Which of the following could be used to synthesize 2-iodobutane?

Accepted Answer

A)  CH3CH2CH$ \equiv$CH2 + I2 (aq)$\rightarrow$ 
B)  CH3CH2C$ \equiv$CH3 + HI $\rightarrow$ 
C)  CH3CH2C$ \equiv$CH + HI $\rightarrow$ 
D)  CH3CH2C$ \equiv$CH + I2 $\rightarrow$ 
E)  None of the above 
A)  CH3CH2CH$ \equiv$CH2 + I2 (aq)$\rightarrow$ 
B)  CH3CH2C$ \equiv$CH3 + HI $\rightarrow$ 
C)  CH3CH2C$ \equiv$CH + HI $\rightarrow$ 
D)  CH3CH2C$ \equiv$CH + I2 $\rightarrow$ 
E)  None of the above

Question 10

A correct IUPAC name for isobutyl alcohol is:

Accepted Answer

A)  2-Methyl-1-propanol 
B)  2-Methyl-1-butanol 
C)  1-Methyl-1-propanol 
D)  1,1-Dimethyl-1-ethanol 
E)  3-Methyl-1-propanol 
A)  2-Methyl-1-propanol 
B)  2-Methyl-1-butanol 
C)  1-Methyl-1-propanol 
D)  1,1-Dimethyl-1-ethanol 
E)  3-Methyl-1-propanol

Question 11

Which is a correct IUPAC name for CH3CH2OCH2CH2CH2OCH2CH3?

Accepted Answer

A)  1,4-Dioxane 
B)  Ethylene glycol diethyl ether 
C)  1,3-Diethoxypropane 
D)  1,2-Diethoxyethane 
E)  1,2-Diethoxymethane 
A)  1,4-Dioxane 
B)  Ethylene glycol diethyl ether 
C)  1,3-Diethoxypropane 
D)  1,2-Diethoxyethane 
E)  1,2-Diethoxymethane

Question 12

Which would be the best way to carry out the following synthesis?

Accepted Answer

A)  (1)HA,heat; (2)H3O+,H2O,heat 
B)  (1)(CH3)3COK / (CH3)3COH; (2)BH3:THF,then H2O2,OH- 
C)  (1)(CH3)3COK / (CH3)3COH; (2)H3O+,then H2O,heat 
D)  (1)KOH,C2H5OH; (2)BH3:THF,then H2O2,OH- 
E)  (1)KOH,C2H5OH; (2)HA,heat; (3)H3O+,H2O,heat 
A)  (1)HA,heat; (2)H3O+,H2O,heat 
B)  (1)(CH3)3COK / (CH3)3COH; (2)BH3:THF,then H2O2,OH- 
C)  (1)(CH3)3COK / (CH3)3COH; (2)H3O+,then H2O,heat 
D)  (1)KOH,C2H5OH; (2)BH3:THF,then H2O2,OH- 
E)  (1)KOH,C2H5OH; (2)HA,heat; (3)H3O+,H2O,heat

What is the relationship between alcohols I and II? They are:

What is the relationship between alcohols I and II? They are:

Oxymercuration-demercuration of 3-methylcyclopentene produces this/these product(s):

Which of the reagents listed below would serve as the basis for a simple chemical test to distinguish between

Draw all of the primary alcohols corresponding to the formula C₅H₁₂O,including stereoisomers.

When 3-methyl-2-pentene is treated with mercuric acetate,Hg(O₂CCH₃)₂,in a THF-ethanol mixture and the resulting product reacted with NaBH₄ in basic solution,the principal product formed is which of these?

Anti-Markovnikov hydration of the carbon-carbon double bond occurs when an alkene reacts with:

Supply the missing reagents A and B.

Which of the following could be used to synthesize 2-iodobutane?

A correct IUPAC name for isobutyl alcohol is:

Which is a correct IUPAC name for CH₃CH₂OCH₂CH₂CH₂OCH₂CH₃?

Which would be the best way to carry out the following synthesis?

Carbon Compounds and Chemical Bonds

Representative Carbon Compounds: Functional Groups, Intermolecular Forces, and Infrared Ir Spectroscopy

An Introduction to Organic Reactions: Acids and Bases

Alkanes: Nomenclature, Conformational Analysis, and an Introduction to Synthesis

Stereochemistry: Chiral Molecules

Ionic Reactions - Nucleophilic Substitution and Elimination Reactions of Alkyl Halides

Alkenes and Alkynes I: Properties and Synthesis, Elimination Reactions of Alkyl Halides

Alkenes and Alkynes Ii: Addition Reactions

Nuclear Magnetic Resonance and Mass Spectrometry: Tools for Structure Determination

Radical Reactions

Alcohols From Carbonyl Compounds Oxidation-Reduction and Organometallic Compounds

Conjugated Unsaturated Systems

Aromatic Compounds

Reactions of Aromatic Compounds

Aldehydes and Ketones I Nucleophilic Addition to the Carbonyl Group

Aldehydes and Ketones Ii Aldol Reactions

Carboxylic Acids and Their Derivatives Nucleophilic Addition - Elimination at the Acyl Carbon

Synthesis and Reactions of Beta-Dicarbonyl Compounds: More Chemistry of Enolate Ions

Amines

Phenols and Aryl Halides: Nucleophilic Aromatic Substitution

Carbohydrates

Lipids

Amino Acids and Proteins

Nucleic Acids and Protein Synthesis

Filters

Exam 11: Alcohols and Ethers

What is the relationship between alcohols I and II? They are:

What is the relationship between alcohols I and II? They are:

Oxymercuration-demercuration of 3-methylcyclopentene produces this/these product(s):

Which of the reagents listed below would serve as the basis for a simple chemical test to distinguish between

Draw all of the primary alcohols corresponding to the formula C5H12O,including stereoisomers.

When 3-methyl-2-pentene is treated with mercuric acetate,Hg(O2CCH3)2,in a THF-ethanol mixture and the resulting product reacted with NaBH4 in basic solution,the principal product formed is which of these?

Anti-Markovnikov hydration of the carbon-carbon double bond occurs when an alkene reacts with:

Supply the missing reagents A and B.

Which of the following could be used to synthesize 2-iodobutane?

A correct IUPAC name for isobutyl alcohol is:

Which is a correct IUPAC name for CH3CH2OCH2CH2CH2OCH2CH3?

Which would be the best way to carry out the following synthesis?

Carbon Compounds and Chemical Bonds

Representative Carbon Compounds: Functional Groups, Intermolecular Forces, and Infrared Ir Spectroscopy

An Introduction to Organic Reactions: Acids and Bases

Alkanes: Nomenclature, Conformational Analysis, and an Introduction to Synthesis

Stereochemistry: Chiral Molecules

Ionic Reactions - Nucleophilic Substitution and Elimination Reactions of Alkyl Halides

Alkenes and Alkynes I: Properties and Synthesis, Elimination Reactions of Alkyl Halides

Alkenes and Alkynes Ii: Addition Reactions

Nuclear Magnetic Resonance and Mass Spectrometry: Tools for Structure Determination

Radical Reactions

Alcohols From Carbonyl Compounds Oxidation-Reduction and Organometallic Compounds

Conjugated Unsaturated Systems

Aromatic Compounds

Reactions of Aromatic Compounds

Aldehydes and Ketones I Nucleophilic Addition to the Carbonyl Group

Aldehydes and Ketones Ii Aldol Reactions

Carboxylic Acids and Their Derivatives Nucleophilic Addition - Elimination at the Acyl Carbon

Synthesis and Reactions of Beta-Dicarbonyl Compounds: More Chemistry of Enolate Ions

Amines

Phenols and Aryl Halides: Nucleophilic Aromatic Substitution

Carbohydrates

Lipids

Amino Acids and Proteins

Nucleic Acids and Protein Synthesis

Filters

Draw all of the primary alcohols corresponding to the formula C₅H₁₂O,including stereoisomers.

When 3-methyl-2-pentene is treated with mercuric acetate,Hg(O₂CCH₃)₂,in a THF-ethanol mixture and the resulting product reacted with NaBH₄ in basic solution,the principal product formed is which of these?

Which is a correct IUPAC name for CH₃CH₂OCH₂CH₂CH₂OCH₂CH₃?