Exam 25: Carbohydrates

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From the sugars below, choose the one that best fits each description below. Place the letter of the sugar in the blank to the left of the description. There is only one correct answer for each question. -_____ is a deoxy sugar.

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What is the relationship between D-threose and L-threose? What is the relationship between D-threose and L-threose?

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What are the two major organic products obtained from the following reaction? What is the relationship between them? (What type of isomers are they?) What are the two major organic products obtained from the following reaction? What is the relationship between them? (What type of isomers are they?)

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A 1,4- α\alpha -linkage between two glucose units produces a disaccharide called maltose.

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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What are the R/S stereochemical designations of C2 and C3 of D-erythrose? What are the R/S stereochemical designations of C2 and C3 of D-erythrose?

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What is the major organic product obtained from the reaction of glucose with glucose oxidase? What is the major organic product obtained from the reaction of glucose with glucose oxidase?

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Consider the following structures. Consider the following structures.   Answer the following questions by placing the appropriate number or indicated letter in the blank. -The formula for maltose is:   The number of the acetal carbon is _____. Answer the following questions by placing the appropriate number or indicated letter in the blank. -The formula for maltose is: Consider the following structures.   Answer the following questions by placing the appropriate number or indicated letter in the blank. -The formula for maltose is:   The number of the acetal carbon is _____. The number of the acetal carbon is _____.

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Which of the following structures represent the same carbohydrate? Which of the following structures represent the same carbohydrate?

(Multiple Choice)
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Complete the structure on the right so that it represents the pyranose form of the carbohydrate shown on the left as a Fischer projection. Place the substituents carefully so that their position in axial or equatorial positions accurately reflects the stereochemistry of the carbohydrate. Complete the structure on the right so that it represents the pyranose form of the carbohydrate shown on the left as a Fischer projection. Place the substituents carefully so that their position in axial or equatorial positions accurately reflects the stereochemistry of the carbohydrate.

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From the sugars below, choose the one that best fits each description below. Place the letter of the sugar in the blank to the left of the description. There is only one correct answer for each question. -The name of the following Fischer projection including stereochemistry is _____________________. From the sugars below, choose the one that best fits each description below. Place the letter of the sugar in the blank to the left of the description. There is only one correct answer for each question. -The name of the following Fischer projection including stereochemistry is _____________________.

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Which of the following structures represent the same carbohydrate? Which of the following structures represent the same carbohydrate?

(Multiple Choice)
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From the sugars below, choose the one that best fits each description below. Place the letter of the sugar in the blank to the left of the description. There is only one correct answer for each question. -_____ is a sugar with three chirality centers.

(Multiple Choice)
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The following are two different methods of representing the same structure. The following are two different methods of representing the same structure.    The following are two different methods of representing the same structure.

(True/False)
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Complete the structure on the right so that it represents the pyranose form of the carbohydrate shown on the left as a Fischer projection. Place the substituents carefully so that their position in axial or equatorial positions accurately reflects the stereochemistry of the carbohydrate. Complete the structure on the right so that it represents the pyranose form of the carbohydrate shown on the left as a Fischer projection. Place the substituents carefully so that their position in axial or equatorial positions accurately reflects the stereochemistry of the carbohydrate.

(Essay)
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Consider the following structures. Consider the following structures.   Answer the following questions by placing the appropriate number or indicated letter in the blank. -The structures that represent reducing sugars are: a. only the ketoses. b. only the aldoses. c. all of these structures. Answer the following questions by placing the appropriate number or indicated letter in the blank. -The structures that represent reducing sugars are: a. only the ketoses. b. only the aldoses. c. all of these structures.

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

(Multiple Choice)
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Which of the following represent a ketose? Which of the following represent a ketose?

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A glycoside is formed upon reaction of glucopyranose with NaBH4.

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What is the relationship between D-erythrose and D-threose? What is the relationship between D-erythrose and D-threose?

(Multiple Choice)
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