Exam 19: Enolate Anions and Enamines

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Which of the following compounds can be prepared by an aldol condensation by treating a single carbonyl compound with base? Which of the following compounds can be prepared by an aldol condensation by treating a single carbonyl compound with base?

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______ ______

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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The following compound can act as a nucleophile in an aldol reaction. The following compound can act as a nucleophile in an aldol reaction.

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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What is the major organic product obtained from the following sequence of reactions? What is the major organic product obtained from the following sequence of reactions?

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What is the major organic product obtained from the following sequence of reactions? What is the major organic product obtained from the following sequence of reactions?

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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How many different β\beta -hydroxyaldehydes and β\beta -hydroxyketones, including constitutional isomers and stereoisomers, are formed upon treatment of a mixture of acetone and benzaldehyde with base?

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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In a Claisen condensation the following substance could be produced by the reaction of ethylbenzoate and _______________. Enter the name of the substance. In a Claisen condensation the following substance could be produced by the reaction of ethylbenzoate and _______________. Enter the name of the substance.

(Short Answer)
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What is the major organic product obtained from the following sequence of reactions? What is the major organic product obtained from the following sequence of reactions?

(Multiple Choice)
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What is the major organic product obtained from the following sequence of reactions? What is the major organic product obtained from the following sequence of reactions?

(Multiple Choice)
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How many different β\beta -hydroxyaldehydes and β\beta -hydroxyketones, including constitutional isomers and stereoisomers, are formed upon treatment of a mixture of butanal and acetone with base?

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_______ _______

(Short Answer)
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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

(Multiple Choice)
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Which combination of organic bromide(s) and dicarbonyl compound can be used to prepare the following product (in a multistep synthesis)? Which combination of organic bromide(s) and dicarbonyl compound can be used to prepare the following product (in a multistep synthesis)?

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An aldol condensation using 3-methylbutanal could produce the following compound. An aldol condensation using 3-methylbutanal could produce the following compound.

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Consider the steps in the mechanism for a base catalyzed aldol condensation. The _______ step in the base catalyzed aldol condensation is addition of an enolate to a carbonyl group.

(Short Answer)
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