Exam 3: Stereoisomerism and Chirality

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A solution containing 0.2 g/mL of a pure R enantiomer in a 1 dm polarimeter rotates plane polarized light by +2.8 ∘\circ . What is the rotation of a solution containing 0.4 g/mL of the R isomer in the same polarimeter?

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What is the relationship between the following pair of structures? What is the relationship between the following pair of structures?

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How many stereoisomers of 2,3-butanediol, CH3CH(OH)CH(OH)CH3, exist?

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Complete the following zig-zag structure so that it represents (2R,3R)-3-chlorobutan-2-ol. Complete the following zig-zag structure so that it represents (2R,3R)-3-chlorobutan-2-ol.

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Which of the following is the best definition of a pair of atropisomers?

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How many stereoisomers of 3-chloro-2-methylbutane, (CH3)2CHCHClCH3, exist?

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Complete the following Fischer diagram so that it represents (2R,3S)-butane-2,3-diol. Complete the following Fischer diagram so that it represents (2R,3S)-butane-2,3-diol.

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Which of the following have the R configuration? Which of the following have the R configuration?

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How many stereoisomers of 3-bromo-2-butanol, CH3CH(OH)CHBrCH3, exist?

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What is the configuration of the two chiral centers in the following molecule? What is the configuration of the two chiral centers in the following molecule?

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Complete the following diagram so that it represents (R)-2-bromobutane. Complete the following diagram so that it represents (R)-2-bromobutane.

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Complete the following Newman projection so that it represents (2R,3R)-2,3-dibromobutane. Complete the following Newman projection so that it represents (2R,3R)-2,3-dibromobutane.

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The following two compounds represent a pair of enantiomers. The following two compounds represent a pair of enantiomers.

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For the compound shown below the number of chiral stereoisomers that can be drawn is_____. CH3CHClCHBrCH3

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Which of the following compounds is a meso compound?

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What is the relationship between the following pair of structures? What is the relationship between the following pair of structures?

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A solution containing 0.04 g/mL of a pure S enantiomer in a 1 dm polarimeter rotates plane polarized light by +2 ∘\circ . What is the specific rotation of the R isomer?

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What is the relationship between the following pair of structures? What is the relationship between the following pair of structures?

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In muscle tissue only (+)-lactic acid is found but in sour milk both (+)-lactic acid and (-)-lactic acid are present. This difference might be explained by the fact that the production of lactic acid in muscle tissue is catalyzed by biological catalysts or enzymes.

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Which of the following compounds is/are chiral? Which of the following compounds is/are chiral?

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