Exam 14: Chemical Kinetics

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The overall order of a reaction is 2. The units of the rate constant for the reaction are ________.

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Consider the following reaction: A → 2C The average rate of appearance of C is given by Δ[C]/Δt. Comparing the rate of appearance of C and the rate of disappearance of A, we get Δ[C]/Δt = ________ × (-Δ[A]/Δt).

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A compound decomposes by a first-order process. If 17.0% of the compound decomposes in 30 minutes, the half-life of the compound is ________.

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At elevated temperatures, dinitrogen pentoxide decomposes to nitrogen dioxide and oxygen: 2N2O5(g) → 4NO2 (g) + O2 (g) When the rate of formation of O2 is 2.2 × 10-4 M/s, the rate of decomposition of N2O5 is ________ M/s.

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The data in the table below were obtained for the reaction: A + B → P The data in the table below were obtained for the reaction: A + B → P   -The order of the reaction in B is ________. -The order of the reaction in B is ________.

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The uptake of molecules into the interior of another substance is referred to as ________.

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The reaction 2NOBr (g) → 2 NO (g)+ Br2 (g) Is a second-order reaction with a rate constant of 0.80 M-1s-1 at 11 °C. If the initial concentration of NOBr is 0.0440 M, the concentration of NOBr after 6.0 seconds is ________.

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A first-order reaction has a rate constant of 0.33 min-1. It takes ________ min for the reactant concentration to decrease from 0.13 M to 0.066 M.

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The Earth's ozone layer is located in the ________.

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The rate constant for a particular second-order reaction is 0.47 M-1s-1. If the initial concentration of reactant is 0.25 mol/L, it takes ________ s for the concentration to decrease to 0.20 mol/L.

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The reaction A → B is first order in [A]. Consider the following data. The reaction A → B is first order in [A]. Consider the following data.   -The rate constant for this reaction is ________ s<sup>-1</sup>. -The rate constant for this reaction is ________ s-1.

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Which one of the following graphs shows the correct relationship between concentration and time for a reaction that is second order in [A]?

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In general, as activation energy increases, reaction rate ________.

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The following reaction is second order in [A] and the rate constant is 0.025 M-1s-1: A → B The concentration of A was 0.65 M at 33 s. The initial concentration of A was ________ M.

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