Exam 16: Acid-Base Equilibria and Solubility Equilibria

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At 25 °C, the base ionization constant for NH3 is 1.8 * 10-5. If 0.0800 mole of solid magnesium chloride is dissolved in a solution prepared by adding 0.0500 mol of solid ammonium chloride to 100.ml of 0.150 M ammonia, will a precipitate of magnesium hydroxide form? (Assume the volume of the solution is unchanged.The solubility product constant for magnesium hydroxide is 1.5 * 10-11.)

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Calculate the concentration of fluoride ions in a saturated barium fluoride (Ksp = 1.7 * 10-6)solution.

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Methyl red is a common acid-base indicator. It has a Ka equal to 6.3 * 10-6. Its un-ionized form is red and its anionic form is yellow. What color would a methyl red solution have at pH = 7.8?

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What is the optimum pH of a sodium formate/formic acid buffer? (For formic acid, Ka = 1.7 * 10-4)

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All indicators are weak acids that are one color in acidic solution and another color in basic solution.

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What is the net ionic equation for the reaction that occurs when small amounts of hydrochloric acid are added to a HOCl/NaOCl buffer solution?

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What volume of 0.0500 M sodium hydroxide should be added to 250.mL of 0.100 M HCOOH to obtain a solution with a pH of 4.50? [Ka(HCOOH)= 1.7 * 10-4]

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What is the pH at the equivalence point in the titration of 100 mL of 0.10 M HCl with 0.10 M NaOH?

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Calculate the silver ion concentration in a saturated solution of silver(I)sulfate (Ksp = 1.4 * 10-5).

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What mass of sodium fluoride must be added to 250.mL of a 0.100 M HF solution to give a buffer solution having a pH of 3.50? [Ka(HF)= 7.1 *10-4]

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Bromothymol blue is a common acid-base indicator. It has a Ka equal to 1.6 * 10-7. Its un-ionized form is yellow and its conjugate base is blue. What color would a solution have at pH = 5.8?

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Calculate the pH at the equivalence point for the titration of 0.25 M CH3COOH with 0.25 M NaOH. (For CH3COOH, Ka= 1.8 * 10-5)

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Will a precipitate of AgCl form when 0.050 mol NaCl(s)and 0.050 mol AgNO3(s)are dissolved in 500.mL of 3.0 M NH3? [Kf for Ag(NH3)2+ is 1.5 * 107; Ksp(AgCl)= 1.6 * 10-10]

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For PbCl2 (Ksp = 2.4 * 10-4), will a precipitate of PbCl2 form when 0.10 L of 3.0 * 10-2 M Pb(NO3)2 is added to 400 mL of 9.0 *10-2 M NaCl?

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The pH of a solution that is 0.20 M CH3COOH and 0.20 M CH3COONa should be higher than the pH of a 0.20 M CH3COOH solution.

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Calculate the pH of a buffer solution prepared by dissolving 0.20 mole of sodium cyanate (NaCNO)and 1.0 mole of cyanic acid (HCNO)in enough water to make 1.0 liter of solution.[Ka(HCNO)= 2.0 * 10-4]

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A saturated sodium carbonate solution at 100°C contains 45.5 g of dissolved sodium carbonate per 100.mL of solution. The solubility product constant for sodium carbonate at this temperature is

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Acid dissociation constants for phosphoric acid are given below. Acid dissociation constants for phosphoric acid are given below.   A buffer with a pH = 7.4 can best be made by using A buffer with a pH = 7.4 can best be made by using

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You are asked to go into the lab and prepare an acetic acid - sodium acetate buffer solution with a pH of 4.00 ± 0.02. What molar ratio of CH3COOH to CH3COONa should be used?

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For which type of titration will the pH be basic at the equivalence point?

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