Exam 16: Acid-Base Equilibria and Solubility Equilibria

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Calculate the percent ionization of formic acid in a solution that is 0.010 M HCOOH and 0.005 M HCOONa and compare your answer to the percent ionization you would calculate if the sodium formate were not present. Explain the difference, if any.(Ka = 1.7 * 10-4)

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The solubility of lead(II)iodide is 0.064 g/100 mL at 20ºC. What is the solubility product for lead(II)iodide?

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The pH at the equivalence point of a titration may differ from 7.0 due to

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Calculate the pH of a buffer solution prepared by dissolving 0.20 mole of cyanic acid (HCNO)and 0.80 mole of sodium cyanate (NaCNO)in enough water to make 1.0 liter of solution. [Ka(HCNO)= 2.0 * 10-4]

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Calculate the percent ionization of formic acid in a 0.010 M HCOOH solution. (Ka = 1.7 *10-4)

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A solution is prepared by mixing 500.mL of 0.10 M NaOCl and 500.mL of 0.20 M HOCl.What is the pH of this solution? [Ka(HOCl)= 3.2 * 10-8]

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Which one of the following is a buffer solution?

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Write a net ionic equation for the reaction occurring when a small amount of sodium hydroxide solution is added to a buffer solution containing NH4Cl and NH3.

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Calculate the pH at the equivalence point for the titration of 0.20 M HCl with 0.20 M NH3 (Kb = 1.8 * 10-5).

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Calculate the percent ionization of formic acid in a solution that is 0.010 M HCOOH and 0.050 M HCOONa.(Ka = 1.7 * 10-4)

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To 1.00 L of a 0.100 M aqueous solution of the week base pyridine (C5H5N)is added 1.00 mL of 14.0 M NaOH. What fraction of the pyridine molecules in the resulting solution react with water to release hydroxide ions? [Kb(C5H5N)= 1.7 * 10-9]

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The solubility of strontium carbonate is 0.0011 g/100 mL at 20ºC. Calculate the Ksp value for this compound.

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Calculate the pH at the equivalence point for the titration of 0.22 M HCN with 0.22 M NaOH. (Ka = 4.9 * 10-10 for HCN)

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Solid sodium iodide is slowly added to a solution that is 0.0050 M Pb2+ and 0.0050 M Ag+.[Ksp (PbI2)= 1.4 * 10-8; Ksp (AgI)= 8.3 * 10-17] What percent of Ag+ remains in solution at this point?

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Calculate the pH of a buffer solution that contains 0.25 M benzoic acid (C6H5CO2H)and 0.15M sodium benzoate (C6H5COONa). [Ka = 6.5 * 10-5 for benzoic acid]

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Write a net ionic equation for the reaction occurring when a small amount of sodium hydroxide is added to a NaNO2/HNO2 buffer.

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Calculate the pH of the solution resulting from the addition of 10.0 mL of 0.10 M NaOH to 50.0 mL of 0.10 M HCN (Ka = 4.9 * 10-10)solution.

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Find the concentration of calcium ions in a solution made by adding 3.50 g of calcium fluoride to 750.mL of 0.125 M NaF. [For CaF2, Ksp = 3.95 * 10-11.]

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The solubility product for barium sulfate is 1.1 * 10-10. Calculate the molar solubility of barium sulfate.

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You have 500.0 mL of a buffer solution containing 0.20 M acetic acid (CH3COOH)and 0.30 M sodium acetate (CH3COONa). What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka = 1.8 * 10-5]

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