Exam 16: Acid-Base Equilibria and Solubility Equilibria

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Solid sodium iodide is slowly added to a solution that is 0.0050 M Pb2+ and 0.0050 M Ag+.[Ksp (PbI2)= 1.4 × 10-8; Ksp (AgI)= 8.3 × 10-17] What percent of Ag+ remains in solution at this point?

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Calculate the concentration of fluoride ions in a saturated barium fluoride (Ksp = 1.7 × 10-6)solution.

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Which of the following is the most acidic solution?

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Will Fe(OH)3 precipitate from a buffer solution that is 0.60 M CH3COOH and 0.10 M CH3COONa, if the solution is also made to be 0.001 M in Fe3+? For Fe(OH)3, Ksp = 6.8 × 10-36.

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You are asked to go into the lab and prepare an acetic acid - sodium acetate buffer solution with a pH of 4.00 ± 0.02.What molar ratio of CH3COOH to CH3COONa should be used?

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Will a precipitate of magnesium fluoride form when 300.mL of 1.1 × 10-3 M MgCl2 are added to 500.mL of 1.2 × 10-3 M NaF? [Ksp (MgF2)= 6.9 × 10-9]

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Assuming equal concentrations of conjugate base and acid, which one of the following mixtures is suitable for making a buffer solution with an optimum pH of 4.6-4.8?

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A 50.0 mL sample of 2.0 × 10-4 M CuNO3 is added to 50.0 mL of 4.0 M NaCN.The formation constant of the complex ion Cu(CN)32- is 1.0 × 109.What is the copper(I)ion concentration in this system at equilibrium?

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Calculate the percent ionization of formic acid in a 0.010 M HCOOH solution. (Ka = 1.7 × 10-4)

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Calculate the pH of a buffer solution that contains 0.25 M benzoic acid (C6H5CO2H)and 0.15M sodium benzoate (C6H5COONa).[Ka = 6.5 × 10-5 for benzoic acid]

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Calculate the pH of a solution that is 0.410 M in HOCl and 0.050 M in NaOCl.[Ka(HOCl)= 3.2 × 10-8]

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Calculate the percent ionization of formic acid in a solution that is 0.010 M HCOOH and 0.050 M HCOONa.(Ka = 1.7 × 10-4)

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You have 500.0 mL of a buffer solution containing 0.20 M acetic acid (CH3COOH)and 0.30 M sodium acetate (CH3COONa).What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka = 1.8 × 10-5]

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Calculate the concentration of chloride ions in a saturated lead(II)chloride (Ksp = 2.4 × 10-4)solution.

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Which of the following compounds is more soluble in a 0.10 M NH3(aq)solution than in pure neutral water?

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The Ksp for silver(I)phosphate is 1.8 × 10-18.Calculate the molar solubility of silver(I)phosphate.

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Which of the following compounds is more soluble in acidic solution than in pure neutral water?

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The solubility of lead(II)iodide is 0.064 g/100 mL at 20ºC.What is the solubility product for lead(II)iodide?

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Write a net ionic equation for the reaction occurring when a small amount of sodium hydroxide solution is added to a buffer solution containing NH4Cl and NH3.

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The molar solubility of tin(II)iodide is 1.28 × 10-2 mol/L.What is Ksp for this compound?

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