Exam 17: Electrochemistry

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Based on the half-reactions and their respective standard reduction potentials below,which addition to an aqueous solution containing Fe(NO3)2 will result in a reaction under standard-state conditions? O2(g)+ 4 H+ +4 e- → 2 H2O(l)1.23 V Fe3+(aq)+ e- → Fe2+(aq)0.77 V Cu2+(aq)+ 2 e- → Cu(s)0.34 V 2 H+(aq)+ 2 e- → H2(g)0.00 V Ni2+(aq)+ + 2 e- → Ni(s)-0.26 V Fe2+(aq)+ 2 e- → Fe(s)-0.45 V

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Which of the following statements concerning a lithium battery is false?

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If a constant current of 1.50 × 108 A is passed through a molten mixture of aluminum oxide and cryolite for 4.00 hour ________ kg of aluminum can be produced.

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In the shorthand notation for a galvanic cell,a single vertical line (|)represents a ________,and a double vertical line (||)represents a ________.

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Consider the galvanic cell shown below. Consider the galvanic cell shown below.   -What is the quantitative change in the cell voltage on increasing the ion concentration in the anode compartment by a factor of 10? -What is the quantitative change in the cell voltage on increasing the ion concentration in the anode compartment by a factor of 10?

(Multiple Choice)
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Shown below is a galvanic cell with anode compartment b containing anode a and cathode compartment d containing cathode c.Electrons flow through wire f,ions flow through salt bridge e,and the cell potential is read using voltmeter g. This galvanic cell uses the reaction: Cu(s)+ 2 Ag+(aq) →\rarr 2 Ag(s)+ Cu2+(aq).  Shown below is a galvanic cell with anode compartment b containing anode a and cathode compartment d containing cathode c.Electrons flow through wire f,ions flow through salt bridge e,and the cell potential is read using voltmeter g. This galvanic cell uses the reaction: Cu(s)+ 2 Ag<sup>+</sup>(aq)  \rarr  2 Ag(s)+ Cu<sup>2+</sup>(aq).   -Identify and give the sign of each electrode. -Identify and give the sign of each electrode.

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What is the balanced equation for the galvanic cell reaction expressed using shorthand notation below? Mg(s)∣ Mg2+(aq)∣∣ Cl2(g)∣ Cl-(aq)∣ C(s)

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How many grams of nickel metal are plated out when a constant current of 15.0 A is passed through aqueous NiCl2 for 80.0 minutes?

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For a galvanic cell that uses the following two half-reactions, Cr2O72-(aq)+ 14 H+(aq)+ 6 e- → 2 Cr3+(aq)+ 7 H2O(l) Pb(s)→ Pb2+(aq)+ 2 e- How many moles of Pb(s)are oxidized by one mole of Cr2O72-?

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What is the shorthand notation that represents the following galvanic cell reaction? Pb(s)+ Cu(NO3)2(aq)→ Pb(NO3)2(aq)+ Cu(s)

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What is the shorthand notation that represents the following galvanic cell reaction? Fe(s)+ Cu(NO3)2(aq)→ Fe(NO3)2(aq)+ Cu(s)

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Shown below is a galvanic cell with anode compartment b containing anode a and cathode compartment d containing cathode c.Electrons flow through wire f,ions flow through salt bridge e,and the cell potential is read using voltmeter g. This galvanic cell uses the reaction: Cu(s)+ 2 Ag+(aq) →\rarr 2 Ag(s)+ Cu2+(aq).  Shown below is a galvanic cell with anode compartment b containing anode a and cathode compartment d containing cathode c.Electrons flow through wire f,ions flow through salt bridge e,and the cell potential is read using voltmeter g. This galvanic cell uses the reaction: Cu(s)+ 2 Ag<sup>+</sup>(aq)  \rarr  2 Ag(s)+ Cu<sup>2+</sup>(aq).   -Identify the electrodes and the direction of electron flow. -Identify the electrodes and the direction of electron flow.

(Multiple Choice)
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Given that E° = +0.897 V,calculate E at 25°C for Pb(s)∣ Pb2+(0.0400 M)∣∣ Fe3+(0.200 M),Fe2+(0.0100 M)∣ Pt(s)

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Consider the following galvanic cell. Consider the following galvanic cell.   -What is the shorthand notation for the cell? -What is the shorthand notation for the cell?

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Electrolysis of a metal nitrate solution M(NO3)2(aq)for 3.00 hours with a constant current of 20.0 A gives 119 g of the metal M.The identity of the metal M in the metal ion M2+ is ________.

(Short Answer)
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For the hypothetical reaction A + Bx → Ax + B,E° = 1.30 V and ΔG° = -251 kJ.For this reaction the value of x = ________.

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What species is oxidized in the reaction: CuSO4(aq)+ Fe(s)→ FeSO4(aq)+ Cu(s)?

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Given pH2 = 0.100 atm,[Cd2+] = 0.200 M,and [H+] = 1.00 × 10-5 M,calculate E at 25°C for a cell based on the reaction: Cd(s)+ 2 H+(aq) →\rarr H2(g)+ Cd2+(aq)Eo = +0.40 V.

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In a galvanic cell,the half-reaction H2(g)+ 2 OH-(aq)→ 2 H2O(l)+ 2 e- is

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What is the shorthand notation for a galvanic cell that represents the following galvanic cell reaction? Br2(l)+ 2 I-(aq)→ 2 Br-(aq)+ I2(s)

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