Exam 17: Electrochemistry

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What is the relationship between the standard cell potentials,E°,for the following two galvanic cell reactions? I.2 Ag+(aq)+ Sn2+(aq)→ Sn4+(aq)+ 2 Ag(s) II.Ag(s)+ 1/2 Sn4+(aq)→ 1/2 Sn2+(aq)+ Ag+(aq)

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What is the relation between ΔG° and E° for the cell reaction below? Ni2+(aq)+ Cd(s)→ Cd2+(aq)+ Ni(s)

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Shown below is an electrochemical cell with anode a and cathode c.Both the anode and the cathode are inert electrodes.The liquid shown in compartment b of the cell is molten potassium chloride,KCl(l). Shown below is an electrochemical cell with anode a and cathode c.Both the anode and the cathode are inert electrodes.The liquid shown in compartment b of the cell is molten potassium chloride,KCl(l).   -Determine whether this is a galvanic or an electrolytic cell and give the reaction occurring at the anode and the reaction occurring at the cathode. -Determine whether this is a galvanic or an electrolytic cell and give the reaction occurring at the anode and the reaction occurring at the cathode.

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A galvanic cell uses the reaction Mg(s)+ Pb2+(aq)→ Mg2+(aq)+ Pb(s). Mg(s)→ Mg2+(aq)+ 2 e- is the ________ half-reaction,which occurs at the ________.

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Consider the galvanic cell,Pt(s)| H2(1 atm)| H+(1 M)|| Cl-(1 M)| Hg2Cl2(s)| Hg(l).Which one of the following changes to the cell would cause the cell potential to increase (i.e. ,become more positive)?

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Given that E°red = -0.26 V for Ni2+/Ni at 25°C,find E° and E for the concentration cell expressed using shorthand notation below. Ni(s)∣ Ni2+(aq,1.0 × 10-5 M)∣∣ Ni2+(aq,0.100 M)∣ Ni(s)

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  -Using Table 17.1,find E° for 2 H<sub>2</sub>O(l)→ 2 H<sub>2</sub>(g)+ O<sub>2</sub>(g). -Using Table 17.1,find E° for 2 H2O(l)→ 2 H2(g)+ O2(g).

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For the hypothetical reaction A + Bx → Ax + B,E° = 1.19 V = and ΔG° = -115 kJ.For this reaction the value of x = .

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Reduction half-reactions with corresponding standard half-cell potentials are shown below. Zn2+(aq)+ 2 e- → Zn(s)E° = - 0.76 V Al3+(aq)+ 3 e- → Al(s)E° = - 1.66 V The standard potential for the galvanic cell that uses these two half-reactions is ________ V.

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Consider the galvanic cell shown below. Consider the galvanic cell shown below.   -What is the quantitative change in the cell voltage on increasing the ion concentration in the cathode compartment by a factor of 10? -What is the quantitative change in the cell voltage on increasing the ion concentration in the cathode compartment by a factor of 10?

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The standard reduction potential E° = -0.45 V for the half-reaction Fe2+ + 2 e- → Fe.If the measured cell potential at 25°C is 0.35 V,the pH in the anode compartment of the following cell is ________. Pt(s)|H2(1 atm)|H+(? M)||Fe2+(1 M)|Fe(s)

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Consider the following galvanic cell. Consider the following galvanic cell.   -What is the quantitative change in the cell voltage on increasing the ion concentration in the anode compartment by a factor of 10? -What is the quantitative change in the cell voltage on increasing the ion concentration in the anode compartment by a factor of 10?

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When a cell reaction reaches equilibrium,

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Consider the half-reaction: MnO4- (aq)+ 8 H+ (aq)+ 5 e- → Mn2+ (aq)+ 4 H2O(l).The formation of MnO4- from Mn2+ occurs most readily when the solution is

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How long must a constant current of 50.0 A be passed through an electrolytic cell containing aqueous Cu2+ ions to produce 3.00 moles of copper metal?

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The iron content of foods can be determined by dissolving them in acid (forming Fe3+),reducing the iron(III)to iron(II),and titrating with cerium(IV): Fe2+(aq)+ Ce4+(aq)→ Fe3+(aq)+ Ce3+(aq). Identify the two half-reactions in the above reaction.

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Which of the following reactions is most suitable for a fuel cell?

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Which statement below is not true?

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The Hall-Heroult process for the production of aluminum involves the electrolysis of

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The bright colors of anodized titanium are due to

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