Exam 16: Thermodynamics: Entropy, free Energy, and Equilibrium

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What is the sign of ΔS for each of the following processes? I.The separation of gaseous molecules of UF6,into 238UF6 and 235UF6 at Constant temperature and pressure. II.The dissolving of I2(s)in CCl4(l).

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For the evaporation of water during perspiration on a hot,dry day,

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In figure (1)below argon atoms,represented by unshaded spheres,and neon atoms,represented by shaded spheres,are in separate compartments.Figure (2)shows the equilibrium state of the system after the stopcock separating the two compartments is opened.Assuming that argon and neon behave as ideal gases,what are the signs (+,-,or 0)of ΔH,ΔS,and ΔG for this process? In figure (1)below argon atoms,represented by unshaded spheres,and neon atoms,represented by shaded spheres,are in separate compartments.Figure (2)shows the equilibrium state of the system after the stopcock separating the two compartments is opened.Assuming that argon and neon behave as ideal gases,what are the signs (+,-,or 0)of ΔH,ΔS,and ΔG for this process?

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If ΔG° is negative for a reaction,

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The standard molar entropy for Br2(g)is 245.46 J/(mol ∙ K)at 25°C.Given that ΔS° = 104.58 J/K for the dissociation of one mole of Br2(g)into Br(g)at 25°C,find the standard molar entropy for Br(g)at 25°C.

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Consider the reaction 2A(g)⇌ A2(g).The following pictures represent two possible initial states and the equilibrium state of the system. Consider the reaction 2A(g)⇌ A<sub>2</sub>(g).The following pictures represent two possible initial states and the equilibrium state of the system.   -What are the signs (+ or -)of ΔH,ΔS,and ΔG when the system spontaneously goes from initial state 1 to the equilibrium state? -What are the signs (+ or -)of ΔH,ΔS,and ΔG when the system spontaneously goes from initial state 1 to the equilibrium state?

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Standard free energies of formation,ΔG°,in kJ/mol,are given below each reactant and product in the reaction shown below.The standard free energy of reaction,ΔG°,for this reaction is ________ kJ. CH4(g)+ 2 O2(g)→ CO2(g)+ 2 H2O(l) -50.8 0 -394.4 -237.2

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Which has the highest standard molar entropy at 25°C?

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Which of the following statements must be true for the entropy of a pure solid to be zero? I.The temperature must be 0 K. II.The solid must be crystalline,not amorphous. III).The solid must be perfectly ordered. IV.The solid must be an element.

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ΔS° = -198.7 J/K for the reaction shown below.Calculate S° for NH3(g). N2(g)+ 3 H2(g)→ 2 NH3(g) ΔS° = -198.7 J/K for the reaction shown below.Calculate S° for NH<sub>3</sub>(g). N<sub>2</sub>(g)+ 3 H<sub>2</sub>(g)→ 2 NH<sub>3</sub>(g)

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Under which of the following conditions would one mole of He have the highest entropy,S?

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What is the entropy of 105 molecules in 1010 boxes?

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Predict the sign of ΔS of the system for both of the following. I.2 C(graphite)+ O2(g)→ 2 CO(g) II.C4H10(g)→ C4H10(l)

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For a particular process,ΔG = ΔH at a given temperature and pressure.Therefore,

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What is the entropy of 10 molecules in a system of 100 boxes?

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The following pictures represent three equilibrium mixtures for the interconversion of A,B,and C molecules (unshaded spheres)into X,Y,and Z molecules (shaded spheres),respectively.What is the sign of ΔG ° for each of the three reactions? The following pictures represent three equilibrium mixtures for the interconversion of A,B,and C molecules (unshaded spheres)into X,Y,and Z molecules (shaded spheres),respectively.What is the sign of ΔG ° for each of the three reactions?

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The chemical system shown below is at equilibrium.Which change in conditions will not result in a spontaneous forward reaction? N2(g)+ 3 H2(g)⇌ 2 NH3(g)Kp = 4 × 105

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Calculate Ksp for PbI2 at 25°C based on the following data: Calculate K<sub>sp</sub> for PbI<sub>2</sub> at 25°C based on the following data:

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Consider the reaction 2A(g)⇌ A2(g).The following pictures represent two possible initial states and the equilibrium state of the system. Consider the reaction 2A(g)⇌ A<sub>2</sub>(g).The following pictures represent two possible initial states and the equilibrium state of the system.   -What are the signs (+ or -)of ΔH,ΔS,and ΔG when the system spontaneously goes from initial state 2 to the equilibrium state? -What are the signs (+ or -)of ΔH,ΔS,and ΔG when the system spontaneously goes from initial state 2 to the equilibrium state?

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At 25°C,ΔG° = -198 kJ for the reaction,NO(g)+ O3(g)⇌ NO2(g)+ O2(g). Calculate ΔG under the following conditions: At 25°C,ΔG° = -198 kJ for the reaction,NO(g)+ O<sub>3</sub>(g)⇌ NO<sub>2</sub>(g)+ O<sub>2</sub>(g). Calculate ΔG under the following conditions:

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