Exam 19: Redox Reactions and Electrochemistry

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How many minutes would be required to electroplate 25.0 grams of chromium by passing a constant current of 4.80 amperes through a solution containing CrCl3?

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Iron objects such as storage tanks and underground pipelines can be protected from corrosion by connecting them through a wire to a piece of

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Calculate the cell emf for the following reaction: Cu2+(0.10 M)+ H2(1 atm) →\rarr Cu(s)+ 2H+(pH = 3.00)

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Consider the reaction Hg2+(aq)+ Hg(l) →\rarr Hg22+(aq). Find the equilibrium constant for this reaction at 25°C.

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Find the emf of the cell described by the cell diagram Fe | Fe2+ (1.500M)|| Au3+ (0.00400M)| Au

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The half-reaction that occurs at the cathode during electrolysis of an aqueous CuCl2 solution is

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Given the following standard reduction potentials in acid solution O2 + 4H+ + 4e- →\rarr 2H2O E° = +1.23 V Sn4+ + 2e- →\rarr Sn2+ E° = +0.13 V Zn2+ + 2e- →\rarr Zn(s)E° = -0.76 V write the formula of the weakest reducing agent.

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Consider the reaction Fe + Sn2+(1 * 10-3 M) →\rarr Fe2+(1.0 M)+ Sn. Sketch a diagram of such a cell. Be sure to label the anode and cathode, and show the direction of electron flow in the external circuit. Write the half-reactions occurring at the electrodes.

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Which of these metals will not be oxidized in hydrochloric acid under standard conditions at 25°C?

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Consider the reaction Fe + Sn2+(1 *10-3 M) →\rarr Fe2+(1.0 M)+ Sn. Calculate the voltage theoretically generated by the cell.

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Calculate E°cell for a silver-aluminum cell in which the cell reaction is Al(s)+ 3Ag+(aq) →\rarr Al3+(aq)+ 3Ag(s)

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Given the following standard reduction potentials in acid solution O2 + 4H+ + 4e- →\rarr 2H2O E° = +1.23 V Sn4+ + 2e- →\rarr Sn2+ E° = +0.13 V Zn2+ + 2e- →\rarr Zn(s)E° = -0.76 V write the formula of the strongest reducing agent.

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An electroplating solution is made up of nickel(II)sulfate. How much time would it take to deposit 0.500 g of metallic nickel on a custom car part using a current of 3.00 A?

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Complete and balance the following redox reaction under acidic conditions: Cu(s)+ NO3-(aq) →\rarr Cu2+(aq)+ NO2(g)

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Consider an electrochemical cell constructed from the following half cells, linked by an external circuit and by a KCl salt bridge. - an Al(s)electrode in 1.0 M Al(NO3)3 solution - a Pb(s)electrode in 1.0 M Pb(NO3)2 solution The balanced overall (net)cell reaction is

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Given the following standard reduction potentials, Ag+(aq)+ e- →\rarr Ag(s)E° = 0.80 V Ag(NH3)2+(aq)+ e- →\rarr Ag(s)+ 2NH3(aq)E° = 0.04 V Calculate the formation constant of Ag(NH3)2+ at 25°C.

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Complete and balance the following redox equation. The sum of the smallest whole-number coefficients is MnO4- + H+ + Br- →\rarr Mn2+ + Br2 + H2O (acidic solution)

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The reduction of 1.00 mole of Cr3+ to Cr requires 9.65 *104 C of electrical charge.

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How many faradays are transferred in an electrolytic cell when a current of 2.0 amperes flows for 12 hours?

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A battery is constructed by placing copper and lead electrodes in contact with 1.0 molar CuSO4(aq)and Pb(NO3)2 (aq)solutions, respectively. If sulfuric acid is then added to the Pb(NO3)2 solution, thereby forming a precipitate of PbSO4, what will happen to the cell potential?

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