Exam 9: Chemical Bonding I: the Covalent Bond

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A nonpolar covalent bond (i.e., pure covalent)would form in which one of the following pairs of atoms?

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Which one of the following is most likely to be an ionic compound?

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Assuming the octet rule is obeyed, how many covalent bonds will a nitrogen atom form to give a formal charge of zero?

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Write a Lewis structure for the nitrate ion, NO3-, showing all non-zero formal charges.

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Which of the elements listed below has the greatest electronegativity?

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What is the formal charge on the oxygen atom in N2O (the atomic order is N-N-O)?

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Use the Born-Haber cycle to calculate the lattice energy of MgO (s)given the following data: Δ\Delta H(sublimation)Mg = 130 kJ/mol I1 (Mg)= 738.1 kJ/mol I2 (Mg)= 1450 kJ/mol Bond energy (O=O)= 498.7 kJ/mol EA (O)= 141 kJ/mol EA (O-)= -780 kJ/mol Δ\Delta H  Use the Born-Haber cycle to calculate the lattice energy of MgO (s)given the following data:  \Delta H(sublimation)Mg = 130 kJ/mol I<sub>1</sub> (Mg)= 738.1 kJ/mol I<sub>2</sub> (Mg)= 1450 kJ/mol Bond energy (O=O)= 498.7 kJ/mol EA (O)= 141 kJ/mol EA (O<sup>-</sup>)= -780 kJ/mol  \Delta H   (MgO(s))= -601.8 kJ/mol (MgO(s))= -601.8 kJ/mol

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Assuming the octet rule is obeyed, how many covalent bonds will a carbon atom form to give a formal charge of zero?

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Use the bond enthalpy data given to estimate the heat released when 6.50 g of nitrogen gas reacts with excess hydrogen gas to form ammonia at 25°C. BE(N ≡\equiv N)= 941.4 kJ/mol BE(H-H)= 436.4 kJ/mol BE(N-H)= 393 kJ/mol

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Which of the following covalent bonds is the most polar (i.e., highest percent ionic character)?

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The standard enthalpy of formation of ammonia at 25°C is -46.3 kJ/mol. Estimate the N-H bond enthalpy at this temperature. (Given: BE(N ≡\equiv N)=941.4 kJ/mol, BE(H-H)= 436.4 kJ/mol)

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Write a Lewis structure for the chlorite ion, ClO2-, that obeys the octet rule, showing all non-zero formal charges, and give the total number of resonance structures for ClO2- that obey the octet rule.

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The Lewis dot symbol for the S 2- ion is

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Write the Lewis dot symbol for the sulfide ion.

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For which of these species does the best Lewis structure have two or more equivalent resonance structures?

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The total number of bonding electrons in a molecule of formaldehyde (H2CO)is

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Write the Lewis structure of boron trifluoride.

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Which one of the following molecules has an atom with an expanded octet?

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Dichloromethane, CH2Cl2, is an important solvent in synthetic chemistry. Write a Lewis structure for CH2Cl2.

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Which one of the following compounds does not follow the octet rule?

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