Exam 9: Chemical Bonding I: the Covalent Bond

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How many covalent bonds will be drawn to phosphorous in PO43- for the dot structure that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s)?

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Which of the elements listed below has the greatest electronegativity?

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Calculate the energy change for the reaction K(g)+ I(g) →\rarr K+(g)+ I - (g) Given the following ionization energy (IE)and electron affinity (EA)values.  Calculate the energy change for the reaction K(g)+ I(g) \rarr  K<sup>+</sup>(g)+ I<sup> -</sup> (g) Given the following ionization energy (IE)and electron affinity (EA)values.

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Use the Born-Haber cycle to calculate the standard enthalpy of formation ( Δ\Delta H  Use the Born-Haber cycle to calculate the standard enthalpy of formation ( \Delta H   )for LiCl(s)given the following data:  \Delta H(sublimation)Li = 155.2 kJ/mol I<sub>1</sub> (Li)= 520 kJ/mol Bond energy (Cl-Cl)= 242.7 kJ/mol EA (Cl)= 349 kJ/mol Lattice energy (LiCl(s))= 828 kJ/mol )for LiCl(s)given the following data: Δ\Delta H(sublimation)Li = 155.2 kJ/mol I1 (Li)= 520 kJ/mol Bond energy (Cl-Cl)= 242.7 kJ/mol EA (Cl)= 349 kJ/mol Lattice energy (LiCl(s))= 828 kJ/mol

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Which of the elements listed below is the least electronegative?

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Which of the following pairs of elements would be most likely to form an ionic compound?

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Which one of the following compounds does not follow the octet rule?

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How many covalent bonds will be drawn to bromine in BrO3- for the dot structure that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s)?

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Which of the bonds below would have the greatest polarity (i.e., highest percent ionic character)?

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Of the species NO2, NO, and N2, only NO2 is an exception to the octet rule.

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Which one of these polar covalent bonds would have the greatest percent ionic character?

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Which one of the following is most likely to be a covalent compound?

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Which of the following ionic solids would have the largest lattice energy?

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Use the Born-Haber cycle to calculate the lattice energy of KCl(s)given the following data: Δ\Delta H(sublimation)K = 79.2 kJ/mol I1 (K)= 418.7 kJ/mol Bond energy (Cl-Cl)= 242.8 kJ/mol EA (Cl)= 348 kJ/mol Δ\Delta H  Use the Born-Haber cycle to calculate the lattice energy of KCl(s)given the following data:  \Delta H(sublimation)K = 79.2 kJ/mol I<sub>1</sub> (K)= 418.7 kJ/mol Bond energy (Cl-Cl)= 242.8 kJ/mol EA (Cl)= 348 kJ/mol  \Delta H   (KCl(s))= -435.7 kJ/mol (KCl(s))= -435.7 kJ/mol

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The Si - Cl bond has less ionic character than the C - Cl bond.

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The bond in which of the following pairs of atoms would have the greatest percent ionic character (i.e., most polar)?

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The bond in F2 is described as polar covalent.

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Estimate the enthalpy change for the combustion of one mole of acetylene, C2H2, to form carbon dioxide and water vapor. BE(C-H)= 456 kJ/mol BE(C ≡\equiv C)= 962 kJ/mol BE(O=O)= 499 kJ/mol BE(C=O)= 802 kJ/mol BE(O-H)= 462 kJ/mol

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Write a Lewis structure for the chlorate ion, ClO3-, that obeys the octet rule, showing all non-zero formal charges, and give the total number of resonance structures for ClO3- that obey the octet rule.

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The number of resonance structures for the sulfur dioxide molecule that satisfy the octet rule is

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