Exam 18: Electrochemistry

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What is the total number of moles (n) of electrons exchanged between the oxidizing agent and the reducing agent in the overall redox equation: 5Fe2+(aq) + MnO4-(aq) + 8H+(aq) →\rarr 5Fe3+(aq) + Mn2+(aq) + 4H2O(l)

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For the electrochemical cell, Cd(s) | Cd2+(aq) || Co2+(aq) | Co(s), determine the equilibrium constant (Keq) at 25 ∘\circ C for the reaction that occurs.

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The overall reaction 2Co3+(aq) + 2Cl-(aq) →\rarr 2Co2+(aq) + Cl2(g) has the standard cell voltage E ∘\circ cell= 0.46 V. Given E ∘\circ = 1.36 V for the reaction Cl2(g) + 2e- →\rarr 2Cl-(aq), calculate the standard reduction potential for the following the half reaction at 25 ∘\circ C: Co3+ + e- →\rarr Co2+

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When an aqueous solution of NaCl is electrolyzed, Na(l) is produced at the cathode, and Cl2(g) is evolved at the anode.

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Aluminum does not corrode as does iron, because

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H2(g) will form when Cu is placed in 1.0 M HCl.

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Consider a Galvanic cell constructed from the following half cells, linked by an external circuit and by a KCl salt bridge.- an Al(s) electrode in 1.0 M Al(NO3)3 solution - a Pb(s) electrode in 1.0 M Pb(NO3)2 solution The balanced overall (net) cell reaction is

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Consider the following standard reduction potentials in acid solution: +3\rightarrow =-0.74 +2\rightarrow =-0.28 +8+5\rightarrow+4 =+1.51 The strongest oxidizing agent listed above is

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Complete and balance the following redox equation. What is the coefficient of H2S when the equation is balanced using the set of smallest whole-number coefficients H2S + MnO4- →\rarr Mn2+ + SO42- (acidic solution)

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How many moles of silver metal are produced in 1.2 hours by the electrolysis of AgNO3(aq) using a current of 6.0 A

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Which one of the following reactions will occur spontaneously at standard-state conditions and 25 ∘\circ C

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Calculate E ∘\circ cell for the following reaction: 2Fe2+(aq) + Cd2+(aq) →\rarr 2Fe3+(aq) + Cd(s)

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Which of the following would be considered a fuel cell

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Calculate the minimum voltage required for the electrolysis of 1.0 M NaCl in neutral solution.2H2O + 2Cl- (1.0 M) →\rarr H2(1 atm) + Cl2(1 atm) + 2OH- (1 * 10-7 M)

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A current of 0.80 A was applied to an electrolytic cell containing molten CdCl2 for 2.5 hours. Calculate the mass of cadmium metal deposited.

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Calculate Δ\Delta G ∘\circ (kJ/mol) for the following electrochemical cell: Cd(s) | Cd2+(aq) || Ni2+(aq)| Ni(s)

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Consider the following reaction: 2Fe2+(aq) + Cu2+ →\rarr 2Fe3+(aq) + Cu.When the reaction comes to equilibrium, what is the cell voltage

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What current is needed to deposit 0.500 g of chromium metal from a solution of Cr3+ in a period of 1.00 hr

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Under acidic conditions, the correctly balanced equation for the redox reaction Cr2O72-(aq) + I-(aq) →\rarr Cr3+(aq) + IO3-(aq) Is: Cr2O72-(aq) + I-(aq) + 8H+(aq) →\rarr 2Cr3+(aq) + IO3-(aq) + 4H2O(l)

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A standard hydrogen electrode is immersed in an acetic acid solution. This electrode is connected by an external circuit to an iron nail dipping into 0.10 M FeCl2. If Ecell is found to be 0.24 V, what is the pH of the acetic acid solution

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