Exam 3: Alkenes and Alkynes: the Nature of Organic Reactions

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Instructions: Assign E or Z configurations to each alkene below. -Assign: Instructions: Assign E or Z configurations to each alkene below. -Assign:

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The following group is a substituent on a molecule. What is an accepted IUPAC name for this group? The following group is a substituent on a molecule. What is an accepted IUPAC name for this group?

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Instructions: Provide names for each structure below. Be sure to include the cis,trans or E,Z designations where applicable. -Name and designate: Instructions: Provide names for each structure below. Be sure to include the cis,trans or E,Z designations where applicable. -Name and designate:

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Instructions: Pent-2-ene is an example of a disubstituted alkene. Use this alkene to answer the following question(s). Instructions: Pent-2-ene is an example of a disubstituted alkene. Use this alkene to answer the following question(s).   -Refer to instructions. Circle the isomer of pent-2-ene that is most stable. -Refer to instructions. Circle the isomer of pent-2-ene that is most stable.

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Instructions: Add curved arrows to the following reaction(s) to indicate the flow of electrons in each. -Indicate flow: Instructions: Add curved arrows to the following reaction(s) to indicate the flow of electrons in each. -Indicate flow:

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Instructions: Draw structures corresponding to each name below. -Draw: (3E)-3,7-dimethylocta-1,3,6-triene

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Instructions: The reaction below is commonly used as a laboratory preparation of cyclohexene. Use this reaction to answer the following question(s). Instructions: The reaction below is commonly used as a laboratory preparation of cyclohexene. Use this reaction to answer the following question(s).   -Refer to instructions. The forward and reverse reactions are classified, respectively, as: -Refer to instructions. The forward and reverse reactions are classified, respectively, as:

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Name this compound. Name this compound.

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Instructions: Classify each structure below as a nucleophile or electrophile, and briefly explain your choice. -Classify and explain: azide Instructions: Classify each structure below as a nucleophile or electrophile, and briefly explain your choice. -Classify and explain: azide

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Instructions: Provide names for each structure below. Be sure to include the cis,trans or E,Z designations where applicable. -Name and designate: Instructions: Provide names for each structure below. Be sure to include the cis,trans or E,Z designations where applicable. -Name and designate:

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Instructions: In the reaction below: a)Label the nucleophile (Nu) and the electrophile (E). b)Draw arrows on the structures showing electron flow in the reaction. -Label and indicate flow: Instructions: In the reaction below: a)Label the nucleophile (Nu) and the electrophile (E). b)Draw arrows on the structures showing electron flow in the reaction. -Label and indicate flow:

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What is the IUPAC name of the following compound? What is the IUPAC name of the following compound?

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Match each definition to one of the terms below. -A reaction that involves a species with an unpaired electron.

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Instructions: Identify and label the nucleophile and electrophile in each reaction below. -Identify and label: Instructions: Identify and label the nucleophile and electrophile in each reaction below. -Identify and label:

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Instructions: Identify and label the nucleophile and electrophile in each reaction below. -Identify and label: Instructions: Identify and label the nucleophile and electrophile in each reaction below. -Identify and label:

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Predict the product of the following reaction of Prostaglandin H2 by interpreting the flow of electrons as indicated by the curved arrows. Predict the product of the following reaction of Prostaglandin H<sub>2</sub> by interpreting the flow of electrons as indicated by the curved arrows.

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Instructions: Pent-2-ene is an example of a disubstituted alkene. Use this alkene to answer the following question(s). Instructions: Pent-2-ene is an example of a disubstituted alkene. Use this alkene to answer the following question(s).   -Refer to instructions. Draw the cis and trans isomers of pent-2-ene and label them. -Refer to instructions. Draw the cis and trans isomers of pent-2-ene and label them.

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Instructions: Identify the functional groups present in each compound below, and predict the direction of polarity in each. -Identify and predict: mustard gas Cl-CH2CH2-CH2CH2-Cl

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Match each definition to one of the terms below. -A species that lies at an energy maximum during an individual step in a reaction.

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Choose substituents X and Y (listed in order below) for the following compound so as to make a Z isomer. Choose substituents X and Y (listed in order below) for the following compound so as to make a Z isomer.

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