Exam 20: Thermodynamics: Entropy, Free Energy, and the Direction of Chemical Reactions

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In which one of these pairs will the entropy of the first substance be greater than that of the second? Assume P and T are the same for each pair, unless stated otherwise.

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Given: H2O(l) →\rightarrow H2O(g), Δ\Delta H °\degree = 40.7 kJ at 373K, what is the entropy change in the system ( Δ\Delta S) when one mole of water vaporizes at 100 °\degree C and a pressure of one atmosphere?

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Consider the reaction  Consider the reaction   If the concentrations of the Cu<sup>+</sup> and I¯ ions in equilibrium at 298 K are both equal to 1.03 *10¯<sup>6</sup> M, what is the value of  \Delta G \degree for the reaction? If the concentrations of the Cu+ and I¯ ions in equilibrium at 298 K are both equal to 1.03 *10¯6 M, what is the value of Δ\Delta G °\degree for the reaction?

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For a chemical reaction to be spontaneous only at high temperatures, which of the following conditions must be met?

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Which of the following pairs has the member with the greater molar entropy listed first? All systems are at 25 °\degree C.

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