Exam 17: Equilibrium: the Extent of Chemical Reactions
Exam 1: Keys to the Study of Chemistry68 Questions
Exam 2: The Components of Matter104 Questions
Exam 3: Stoichiometry of Formulas and Equations96 Questions
Exam 4: Three Major Classes of Chemical Reactions105 Questions
Exam 5: Gases and the Kinetic-Molecular Theory103 Questions
Exam 6: Thermochemistry: Energy Flow and Chemical Change79 Questions
Exam 7: Quantum Theory and Atomic Structure74 Questions
Exam 8: Electron Configuration and Chemical Periodicity81 Questions
Exam 9: Models of Chemical Bonding73 Questions
Exam 10: The Shapes of Molecules108 Questions
Exam 11: Theories of Covalent Bonding56 Questions
Exam 12: Intermolecular Forces: Liquids, Solids, and Phase Changes97 Questions
Exam 13: The Properties of Mixtures: Solutions and Colloids98 Questions
Exam 14: Periodic Patterns in the Main-Group Elements111 Questions
Exam 15: Organic Compounds and the Atomic Properties of Carbon113 Questions
Exam 16: Kinetics: Rates and Mechanisms of Chemical Reactions89 Questions
Exam 17: Equilibrium: the Extent of Chemical Reactions102 Questions
Exam 18: Acid-Base Equilibria106 Questions
Exam 19: Ionic Equilibria in Aqueous Systems115 Questions
Exam 20: Thermodynamics: Entropy, Free Energy, and the Direction of Chemical Reactions85 Questions
Exam 21: Electrochemistry: Chemical Change and Electrical Work102 Questions
Exam 22: The Elements in Nature and Industry56 Questions
Exam 23: The Transition Elements and Their Coordination Compounds92 Questions
Exam 24: Nuclear Reactions and Their Applications90 Questions
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In water, the following equilibrium exists:
In pure water at 25 C, the concentration of H+ ions is 1.00 * 10¯7 mol/L. Calculate the value of the equilibrium constant for the reaction as written above.
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(Multiple Choice)
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Correct Answer:
A
At a high temperature, the following reaction has an equilibrium constant of 1.0 *102.
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If 1.00 mol of each of H2 and F2 are allowed to come to equilibrium in a 10.0 L vessel, calculate the equilibrium amounts of H2 and HF. 0.17 mol of H2 and 1.7 mol of HF
Although a system may be at equilibrium, the rate constants of the forward and reverse reactions will in general be different.
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An equilibrium is established in which both the forward (fwd) and the reverse (rev) reactions are elementary. If the equilibrium constant Kc = 1.6 *10¯2 and the rate constant kfwd = 8.0 * 10¯7 s¯1 what is the value of krev?
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When 0.152 mol of solid PH3BCl3 is introduced into a 3.0 L container at a certain temperature, 8.44 *10¯3 mol of PH3 is present at equilibrium:
PH3BCl3(s)
PH3(g) + BCl3(g)
Construct a reaction table for the process, and use it to calculate Kc at this temperature.
(Essay)
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Carbon monoxide and chlorine combine in an equilibrium reaction to produce the highly toxic product, phosgene (COCl2).
If the equilibrium constant for this reaction is Kc = 248, predict, if possible, what will happen when the reactants and product are combined with the concentrations shown. [CO] = [Cl2] = 0.0200 M; [COCl2] = 0.0992 M
(Multiple Choice)
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Write the mass-action expression, Qc, for the following chemical reaction. 
(Multiple Choice)
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For a solution equilibrium, a change in concentration of a reactant or product does not change Kc.
(True/False)
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There is a direct correlation between the speed of a reaction and its equilibrium constant.
(True/False)
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The two equilibrium constants for the same reaction, Kc and Kp, will always equal one another when
(Multiple Choice)
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In order to write the correct mass-action expression for a reaction one must
(Multiple Choice)
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Consider the equilibrium reaction:
Which of the following correctly describes the relationship between Kc and Kp for the reaction?
(Multiple Choice)
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The equilibrium constant, Kc, for the decomposition of COBr2 
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Given this equilibrium constant data at 25 C,
what is the value of Kc at this temperature for the reaction
(Multiple Choice)
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Methanol can be synthesized by combining carbon monoxide and hydrogen.
A reaction vessel contains these compounds at equilibrium. What effect will be seen when equilibrium is reestablished after decreasing the temperature by 45 C?
(Multiple Choice)
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Increasing the initial amount of the limiting reactant in a reaction will increase the value of the equilibrium constant, Kc.
(True/False)
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For a gas-phase equilibrium, a change in the pressure of any single reactant or product will affect the amounts of other substances involved in the equilibrium.
(True/False)
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Methanol can be synthesized by combining carbon monoxide and hydrogen.
A reaction vessel contains the three gases at equilibrium with a total pressure of 1.00 atm. What will happen to the partial pressure of hydrogen if enough argon is added to raise the total pressure to 1.4 atm?
(Multiple Choice)
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Consider the reactions of cadmium with the thiosulfate anion.
What is the value for the equilibrium constant for the following reaction? 
(Multiple Choice)
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Write the mass-action expression, Qc, for the following chemical reaction. 
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