Exam 21: Electrochemistry: Chemical Change and Electrical Work

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The voltaic cell made up of cobalt, copper and their M2+ ions, has E °\degree cell = 0.62 V. If E °\degree of the cathode half-cell is 0.34 V, what is E °\degree of the anode half-cell? Cu2+(aq) + Co(s) →\rightarrow Cu(s) + Co2+(aq)

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The line notation, Al(s) | Al3+(aq) || Co2+(aq) | Co(s), indicates that

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In the shorthand notation for cells, a double vertical line is used to separate the reduced and oxidized forms of a redox couple.

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Examine the following half-reactions and select the strongest reducing agent among the species listed. Examine the following half-reactions and select the strongest reducing agent among the species listed.

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The following half-reactions occur in the mercury battery used in calculators. If E °\degree 1U1B1cell = 1.357 V, calculate the equilibrium constant for the cell reaction at 25 °\degree C. (Assume the stoichiometric coefficients in the cell reaction are all equal to 1.) HgO(s) + H2O(l) + 2e¯  The following half-reactions occur in the mercury battery used in calculators. If E \degree 1U1B1cell</sub> = 1.357 V, calculate the equilibrium constant for the cell reaction at 25 \degree C. (Assume the stoichiometric coefficients in the cell reaction are all equal to 1.) HgO(s) + H<sub>2</sub>O(l) + 2e¯   Hg(l) + 2OH¯(aq) ZnO(s) + H<sub>2</sub>O(l) + 2e¯   Zn(s) + 2OH¯(aq) Hg(l) + 2OH¯(aq) ZnO(s) + H2O(l) + 2e¯  The following half-reactions occur in the mercury battery used in calculators. If E \degree 1U1B1cell</sub> = 1.357 V, calculate the equilibrium constant for the cell reaction at 25 \degree C. (Assume the stoichiometric coefficients in the cell reaction are all equal to 1.) HgO(s) + H<sub>2</sub>O(l) + 2e¯   Hg(l) + 2OH¯(aq) ZnO(s) + H<sub>2</sub>O(l) + 2e¯   Zn(s) + 2OH¯(aq) Zn(s) + 2OH¯(aq)

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Calculate Δ\Delta G °\degree for the reaction of iron(II) ions with one mole of permanganate ions.  Calculate  \Delta G \degree for the reaction of iron(II) ions with one mole of permanganate ions.

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What is the value of the equilibrium constant for the cell reaction below at 25 °\degree C? E °\degree cell = 0.30 V Sn2+(aq) + Fe(s)  What is the value of the equilibrium constant for the cell reaction below at 25 \degree C?  E \degree <sub>cell</sub> = 0.30 V Sn<sup>2+</sup>(aq) + Fe(s)   Sn(s) + Fe<sup>2+</sup>(aq) Sn(s) + Fe2+(aq)

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Which of the following elements could be prepared by electrolysis of the aqueous solution shown?

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Which component of the following cell notation is the anode? P | Q || R | S

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In the electrolyte of an electrochemical cell, current is carried by anions moving toward the anode and cations moving in the opposite direction.

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Which one of the following is not a redox reaction?

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Which one of the following pairs of substances could be used to construct a single redox electrode (i.e., they have an element in common, but in different oxidation states)?

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In the electrolyte of an electrochemical cell, current is carried by electrons moving from the anode to the cathode.

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In the electrolysis of water, how many grams of oxygen gas will be produced for every gram of hydrogen gas formed? Reaction: 2H2O(l) →\rightarrow 2H2(g) + O2(g)

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Examine the following half-reactions and select the weakest oxidizing agent among the species listed. Examine the following half-reactions and select the weakest oxidizing agent among the species listed.

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Which one of the following statements relating to the glass electrode is correct?

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A voltaic cell consists of an Au/Au3+ electrode (E °\degree = 1.50 V) and a Cu/Cu2+ electrode (E °\degree = 0.34 V). Calculate [Au3+] if [Cu2+] = 1.20 M and Ecell = 1.13 V at 25 °\degree C.

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Which, if any, of the following metals would not be capable of acting as a sacrificial anode when used with iron E °\degree Fe = -0.44 V; all E °\degree values refer to the M2+/M half-cell reactions.

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Consider the reaction in the lead-acid cell  Consider the reaction in the lead-acid cell   for which E  \degree <sub>cell</sub> = 2.04 V at 298 K.  \Delta G  \degree for this reaction is for which E °\degree cell = 2.04 V at 298 K. Δ\Delta G °\degree for this reaction is

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Predict the products of the cell reaction when a molten salt mixture of sodium bromide and calcium fluoride is electrolyzed (spectator ions are not considered to be products).

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