Exam 21: Electrochemistry: Chemical Change and Electrical Work

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Calculate E °\degree cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous.  Calculate E  \degree <sub>cell</sub> and indicate whether the overall reaction shown is spontaneous or nonspontaneous.   Overall reaction: 2Cr(s) + 3I<sub>2</sub>(s)  \rightarrow  2Cr<sup>3+</sup>(aq) + (aq) + 6I¯(aq) Overall reaction: 2Cr(s) + 3I2(s) →\rightarrow 2Cr3+(aq) + (aq) + 6I¯(aq)

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A voltaic cell is prepared using copper and silver. Its cell notation is shown below. A voltaic cell is prepared using copper and silver. Its cell notation is shown below.   Which of the following processes occurs at the cathode? Which of the following processes occurs at the cathode?

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The value of the equilibrium constant for the reaction of nickel(II) ions with cadmium metal is 1.17 * 105. Calculate Δ\Delta G °\degree or the reaction at 25 °\degree C.

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In the electrolysis of aqueous potassium nitrate using inert electrodes, which one of the following species is oxidized?

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A) Write a balanced equation to represent the overall reaction you would expect to occur in the electrolysis of molten KCl. B) Write a balanced equation to represent the overall reaction you would expect to occur in the electrolysis of aqueous KCl. C) Clearly explain why the products of the two processes are not the same.

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In the electrolysis of aqueous sodium sulfate at electrodes of platinum, predict the products of the cell reaction.

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Calculate Δ\Delta G °\degree for the oxidation of 3 moles of copper by nitric acid.  Calculate \Delta G \degree for the oxidation of 3 moles of copper by nitric acid.

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In the absence of oxygen, iron will rust as long as moisture is present.

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When the following redox equation is balanced with smallest whole number coefficients, the coefficient for Sn(OH)3¯ will be _____. When the following redox equation is balanced with smallest whole number coefficients, the coefficient for Sn(OH)<sub>3</sub>¯ will be _____.

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A current of 250. A flows for 24.0 hours at an anode where the reaction occurring is Mn2+(aq) + 2H2O(l) →\rightarrow MnO2(s) + 4H+(aq) + 2e¯ What mass of MnO2 is deposited at this anode?

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A voltaic cell prepared using aluminum and nickel has the following cell notation. A voltaic cell prepared using aluminum and nickel has the following cell notation.   Which of the following reactions occurs at the anode? Which of the following reactions occurs at the anode?

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Which one of the following statements about electrochemical cells is correct?

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A voltaic cell has a standard cell potential equal to 0.74 V. If the standard electrode (reduction) potential for the anode is -0.22 V, what is the standard electrode potential for the cathode?

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Examine the following half-reactions and select the strongest oxidizing agent among the species listed. Examine the following half-reactions and select the strongest oxidizing agent among the species listed.

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A voltaic cell prepared using aluminum and nickel has the following cell notation. A voltaic cell prepared using aluminum and nickel has the following cell notation.   Which of the following represents the correctly balanced spontaneous reaction equation for the cell? Which of the following represents the correctly balanced spontaneous reaction equation for the cell?

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When the following redox equation is balanced with smallest whole number coefficients, the coefficient for nitrogen dioxide will be _____. When the following redox equation is balanced with smallest whole number coefficients, the coefficient for nitrogen dioxide will be _____.

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A primary battery is one which can be recharged.

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Consider the following redox equation Consider the following redox equation   When the equation is balanced with smallest whole number coefficients, what is the coefficient for OH¯(aq) and on which side of the equation is OH¯(aq) present? When the equation is balanced with smallest whole number coefficients, what is the coefficient for OH¯(aq) and on which side of the equation is OH¯(aq) present?

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Calculate E °\degree cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous.  Calculate E \degree <sub>cell</sub> and indicate whether the overall reaction shown is spontaneous or nonspontaneous.   Overall reaction:   Overall reaction:  Calculate E \degree <sub>cell</sub> and indicate whether the overall reaction shown is spontaneous or nonspontaneous.   Overall reaction:

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Which of the following solids is commonly used as an inactive electrode in electrochemical cells?

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