Exam 21: Electrochemistry: Chemical Change and Electrical Work
Exam 1: Keys to the Study of Chemistry68 Questions
Exam 2: The Components of Matter104 Questions
Exam 3: Stoichiometry of Formulas and Equations96 Questions
Exam 4: Three Major Classes of Chemical Reactions105 Questions
Exam 5: Gases and the Kinetic-Molecular Theory103 Questions
Exam 6: Thermochemistry: Energy Flow and Chemical Change79 Questions
Exam 7: Quantum Theory and Atomic Structure74 Questions
Exam 8: Electron Configuration and Chemical Periodicity81 Questions
Exam 9: Models of Chemical Bonding73 Questions
Exam 10: The Shapes of Molecules108 Questions
Exam 11: Theories of Covalent Bonding56 Questions
Exam 12: Intermolecular Forces: Liquids, Solids, and Phase Changes97 Questions
Exam 13: The Properties of Mixtures: Solutions and Colloids98 Questions
Exam 14: Periodic Patterns in the Main-Group Elements111 Questions
Exam 15: Organic Compounds and the Atomic Properties of Carbon113 Questions
Exam 16: Kinetics: Rates and Mechanisms of Chemical Reactions89 Questions
Exam 17: Equilibrium: the Extent of Chemical Reactions102 Questions
Exam 18: Acid-Base Equilibria106 Questions
Exam 19: Ionic Equilibria in Aqueous Systems115 Questions
Exam 20: Thermodynamics: Entropy, Free Energy, and the Direction of Chemical Reactions85 Questions
Exam 21: Electrochemistry: Chemical Change and Electrical Work102 Questions
Exam 22: The Elements in Nature and Industry56 Questions
Exam 23: The Transition Elements and Their Coordination Compounds92 Questions
Exam 24: Nuclear Reactions and Their Applications90 Questions
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What is the E cell for the cell represented by the combination of the following half-reactions?
(Multiple Choice)
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Which of the following elements can be isolated by electrolysis of the aqueous salt shown?
(Multiple Choice)
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A buried iron pipe can be protected against corrosion by connecting it to a rod of copper.
(True/False)
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A concentration cell consists of two Zn/Zn2+ electrodes. The electrolyte in compartment A is 0.10 M Zn(NO3)2 and in compartment B is 0.60 M Zn(NO3)2. What is the voltage of the cell at 25 C?
(Multiple Choice)
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A voltaic cell consists of a Cd/Cd2+ electrode (E = -0.40 V) and a Fe/Fe2+ electrode (E = -0.44 V). If Ecell = 0 and the temperature is 25 C, what is the ratio [Fe2+]/[Cd2+]?
(Multiple Choice)
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A much-studied cell in electrochemistry has the following cell notation:
Bearing in mind that HCl(aq) consists of H+(aq) and Cl¯(aq), and that this solution is in contact with both electrodes (there is no salt bridge), write down balanced equations for
A) the anode half-reaction.
B) the cathode half-reaction.
C) the cell reaction.
(Essay)
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A secondary cell (battery) can operate either as a galvanic or an electrolytic cell.
(True/False)
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The line notation, Pt | H2(g) | H+(aq) || Cu2+(aq) | Cu(s), indicates that
(Multiple Choice)
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Calculate the potential of a voltaic cell (E cell) if it is required to do 5.43 * 10¯3 kJ of work when a charge of 2.50 C is transferred.
(Multiple Choice)
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Calculate E cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous.
Overall reaction:
(Multiple Choice)
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Explain what is meant by a fuel cell. Provide a balanced equation to represent the reaction in any fuel cell of your choice.
(Essay)
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In the shorthand notation for cells, a single vertical line represents a salt bridge.
(True/False)
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If the electrodes of a voltaic cell are connected with an external wire, electrons will flow in this wire from the cathode to the anode.
(True/False)
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Write down equations representing the anode half-reaction, the cathode half-reaction and the overall cell reaction for the lead-acid battery.
(Essay)
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Electrolytic cells utilize electrical energy to drive non-spontaneous redox reactions.
(True/False)
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Chromium metal is electroplated from acidic aqueous solutions containing the dichromate ion, Cr2O72¯. What is the minimum time needed to plate out 10.0 g of chromium metal from such a solution, if the current is 50.0 A?
(Multiple Choice)
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A voltaic cell consists of a Ag/Ag+ electrode (E = 0.80 V) and a Fe2+/Fe3+ electrode (E = 0.77 V) with the following initial molar concentrations: [Fe2+] = 0.30 M; [Fe3+] = 0.10 M; [Ag+] = 0.30 M. What is the equilibrium concentration of Fe3+? (Assume the anode and cathode solutions are of equal volume, and a temperature of 25 C.)
(Multiple Choice)
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Which, if any, of the following metals would be capable of acting as a sacrificial anode when used with iron pipe? E Fe = -0.44 V; all E values refer to the M2+/M half-cell reactions.
(Multiple Choice)
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Which of the following statements about voltaic and electrolytic cells is correct?
(Multiple Choice)
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