Exam 20: Thermodynamics: Entropy, Free Energy, and the Direction of Chemical Reactions

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Nitric oxide reacts with chlorine to form NOCl. The data refer to 298 K.  Nitric oxide reacts with chlorine to form NOCl. The data refer to 298 K.     What is the value of  \Delta G \degree for this reaction at 550 K?  Nitric oxide reacts with chlorine to form NOCl. The data refer to 298 K.     What is the value of  \Delta G \degree for this reaction at 550 K? What is the value of Δ\Delta G °\degree for this reaction at 550 K?

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A certain process has Δ\Delta Suniv > 0 at 25 °\degree C. What does one know about the process?

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Which relationship best describes Δ\Delta S °\degree for the following reaction? CO(g) + H2O(g) →\rightarrow CO2(g) + H2(g)

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Calculate Δ\Delta S °\degree for the reaction  Calculate  \Delta S \degree  for the reaction      Calculate  \Delta S \degree  for the reaction

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When a sky diver free-falls through the air, the process is

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In order for a process to be spontaneous,

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Which of the following is always true for an endothermic process?

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Consider the figure below which shows Δ\Delta G °\degree for a chemical process plotted against absolute temperature.  Consider the figure below which shows  \Delta G \degree   for a chemical process plotted against absolute temperature.   From this plot, it is reasonable to conclude that: From this plot, it is reasonable to conclude that:

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Sulfuryl dichloride is formed when sulfur dioxide reacts with chlorine. The data refer to 298 K.  Sulfuryl dichloride is formed when sulfur dioxide reacts with chlorine. The data refer to 298 K.     What is the value of  \Delta G \degree for this reaction at 600 K?  Sulfuryl dichloride is formed when sulfur dioxide reacts with chlorine. The data refer to 298 K.     What is the value of  \Delta G \degree for this reaction at 600 K? What is the value of Δ\Delta G °\degree for this reaction at 600 K?

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For a chemical reaction to be non-spontaneous at any temperature, which of the following conditions must be met?

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Which of the following is necessary for a process to be spontaneous?

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Which of the following is always true for an exothermic process?

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Which of the following is true for pure oxygen gas, O2(g) at 25 °\degree C?

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Which relationship best describes Δ\Delta S °\degree for the following reaction? 8H2(g) + S8(s) →\rightarrow 8H2S(g)

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Calculate Δ\Delta G °\degree for the reaction  Calculate  \Delta G  \degree for the reaction      Calculate  \Delta G  \degree for the reaction

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The formation constant for the reaction Ag+(aq) + 2NH3(aq)  The formation constant for the reaction Ag<sup>+</sup>(aq) + 2NH<sub>3</sub>(aq)   Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq) is K<sub>f</sub> = 1.7 *10<sup>7</sup> at 25 \degree C. What is  \Delta G \degree at this temperature? Ag(NH3)2+(aq) is Kf = 1.7 *107 at 25 °\degree C. What is Δ\Delta G °\degree at this temperature?

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Iron(III) oxide can be reduced by carbon monoxide.

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Calculate Δ\Delta S °\degree for the reaction  Calculate  \Delta S \degree  for the reaction      Calculate  \Delta S \degree  for the reaction

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Calculate Δ\Delta S °\degree for the combustion of propane.  Calculate \Delta S \degree  for the combustion of propane.      Calculate \Delta S \degree  for the combustion of propane.

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In some spontaneous processes, the entropy of the surroundings decreases.

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