Exam 5: Thermochemistry

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Glycine,C2H5O2N,is important for biological energy.The combustion reaction of glycine is described by the following thermochemical equation. 4C2H5O2N(s)+ 9O2(g)→ 8CO2(g)+ 10H2O(l)+ 2N2(g)ΔH°rxn = -3896 kJ/mol What is the standard enthalpy of formation of solid glycine?

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In an endothermic reaction,in going from the reactants to the products at the same temperature,the value of q is negative.

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A system that does no work but which receives heat from the surroundings has

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Sand is converted to pure silicon in a three-step process.The final step in this process is as follows. SiCl4(g)+ 2Mg(s)→ 2MgCl(s)+ Si(s)ΔH°rxn = -625.6 kJ/mol What is the enthalpy change if 25.0 mol of silicon tetrachloride is converted to elemental silicon?

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Using Hess's law,what is ΔH°rxn for the following reaction? WO3(s)+ 3H2(g)→ W(s)+ 3H2O(g) 2W(s)+ 3O2(g)→2WO3(s)ΔH°rxn = -1685.8 kJ/mol 2H2(g)+ O2(g)→ 2H2O(g)ΔH°rxn = -483.6 kJ/mol

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A system initially has an internal energy U of 504 J.It undergoes a process during which it releases 111 J of heat energy to the surroundings,and does work of 222 J.What is the final energy of the system,in J?

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If,as a pioneer,you wished to warm your room by taking an object heated on top of a pot-bellied stove to it,which of the following 15-pound objects,each heated to 100°C,would be the best choice? The specific heat capacity (in J/g·°C)for each substance is given in parentheses.Iron (0.450),copper (0.387),granite (0.79),gold (0.129),water (4.184).

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What is ΔH°rxn for the following reaction? C6H6(l)+ 15/2 O2(g)→ 6CO2(g)+ 3H2O(l) 6C(graphite)+ 3H2(g)→ C6H6(l) ΔH°rxn = +49.0 kJ/mol C(graphite)+ O2(g)→ CO2(g) ΔH°rxn = -393.5 kJ/mol H2(g)+ ½O2(g)→ H2O(l) ΔH°rxn = -285.8 kJ/mol

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The sign of q when heat is absorbed by the system is ___________.

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Ethylene glycol,used as a coolant in automotive engines,has a specific heat capacity of 2.42 J/g°C.Calculate q when 3.65 kg of ethylene glycol is cooled from 132°C to 85°C.

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An exothermic reaction causes the surroundings to

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What is ΔH°rxn for the reaction 2Al2O3(s)→ 4Al(s)+ 3O2(g)? ΔH°f(Al2O3(s))= -1670 kJ/mol

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Which of the following processes always results in an increase in the energy of a system?

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A(n)___________ __________ is a process where heat is released to the surroundings.

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Which equation has a ΔHrxn that is not equal to ΔHof of the product? rev: 04_28_2015_QC_CS-14747

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Cold packs,whose temperatures are lowered when ammonium nitrate dissolves in water,are carried by athletic trainers when transporting ice is not possible.Which of the following is true of this reaction?

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Which relationship is always correct?

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Solid sodium peroxide (Na2O2)reacts with liquid water yielding aqueous sodium hydroxide and oxygen gas.How much heat is released if 327.2 g of oxygen gas is produced from the reaction of sodium peroxide and water under standard-state conditions? Substance ΔH°f(kJ/mol) Na2O2 (s)-510.9 NaOH(aq)-469.6 H2O(l)-285.8

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The highly exothermic thermite reaction,in which aluminum reduces iron(III)oxide to elemental iron,has been used by railroad repair crews to weld rails together. 2Al(s)+ Fe2O3(s)→ 2Fe(s)+ Al2O3(s)ΔH°rxn = -847.6 kJ/mol What mass of iron is formed if 725 kJ of heat are released?

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The work done on the surroundings by the expansion of a gas is w = -PΔV.

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