Exam 19: Electrochemistry

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When the following redox equation is balanced with the smallest whole number coefficients,the coefficient for the hydrogen sulfate ion will be ______. Al(s)+ HSO4-(aq)+ OH-(aq)→ Al2O3(s)+ S2-(aq)+ H2O(l)

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At equilibrium E° = 0.

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Iron objects such as storage tanks and underground pipelines can be protected from corrosion by connecting them through a wire to a piece of

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What is the oxidizing agent in the (unbalanced)reaction? Cu(s)+ H+(aq)+ NO3-(aq)→ NO(g)+ H2O(l)+ Cu2+(aq)

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The Faraday constant represents the charge of 1 mole of electrons.

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A voltaic cell consists of a Hg/Hg22+ electrode (E°= 0.85 V)and a Sn/Sn2+ electrode (E°= -0.14 V).Calculate [Sn2+] if [Hg22+] = 0.24 M and Ecell = 1.04 V at 25°C.

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The voltaic cell composed of Co(s),Co2+(aq),Cu(s),and Cu2+(aq)has E°cell = 0.62 V.If E° of the cathode half-cell is 0.34 V,what is E° of the anode half-cell? Cu2+(aq)+ Co(s)→ Cu(s)+ Co2+(aq)

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A salt bridge allows movement of cations and anions from one half-cell to the other.

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A cell can be prepared from copper and tin.What is the E°cell for the galvanic cell that forms from the following half-reactions? Cu2+(aq)+ 2e- A cell can be prepared from copper and tin.What is the E°<sub>cell</sub> for the galvanic cell that forms from the following half-reactions? Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Cu(s)E° = 0.34V Sn<sup>4+</sup>(aq)+ 2e<sup>-</sup>   Sn<sup>2+</sup>(aq)E° = 0.13V Cu(s)E° = 0.34V Sn4+(aq)+ 2e- A cell can be prepared from copper and tin.What is the E°<sub>cell</sub> for the galvanic cell that forms from the following half-reactions? Cu<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Cu(s)E° = 0.34V Sn<sup>4+</sup>(aq)+ 2e<sup>-</sup>   Sn<sup>2+</sup>(aq)E° = 0.13V Sn2+(aq)E° = 0.13V

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What is E°cell for a galvanic cell represented by the combination of the following half-reactions? ClO4-(aq)+ 8 H+(aq)+8e- What is E°<sub>cell</sub> for a galvanic cell represented by the combination of the following half-reactions? ClO<sub>4</sub><sup>-</sup>(aq)+ 8 H<sup>+</sup>(aq)+8e<sup>-</sup> <sup> </sup>   Cl<sup>-</sup>(aq)+4H<sub>2</sub>O(l)E° = 1.389V VO<sub>2</sub><sup>+</sup>(aq)+ 2H<sup>+</sup>(aq)+e<sup>-</sup> <sup> </sup>   VO<sup>+</sup>(aq)+H<sub>2</sub>O(l)E° = 0.991V Cl-(aq)+4H2O(l)E° = 1.389V VO2+(aq)+ 2H+(aq)+e- What is E°<sub>cell</sub> for a galvanic cell represented by the combination of the following half-reactions? ClO<sub>4</sub><sup>-</sup>(aq)+ 8 H<sup>+</sup>(aq)+8e<sup>-</sup> <sup> </sup>   Cl<sup>-</sup>(aq)+4H<sub>2</sub>O(l)E° = 1.389V VO<sub>2</sub><sup>+</sup>(aq)+ 2H<sup>+</sup>(aq)+e<sup>-</sup> <sup> </sup>   VO<sup>+</sup>(aq)+H<sub>2</sub>O(l)E° = 0.991V VO+(aq)+H2O(l)E° = 0.991V

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In the electrolyte of an electrochemical cell,current is carried by electrons moving from the anode to the cathode.

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What is the equilibrium constant at 25°C for the following reaction? (R = 8.314 J/K • mol,F = 96,500 C • mol-1) Sn2+(aq)+ Fe(s) What is the equilibrium constant at 25°C for the following reaction? (R = 8.314 J/K • mol,F = 96,500 C • mol<sup>-1</sup>) Sn<sup>2+</sup>(aq)+ Fe(s)   Sn(s)+ Fe<sup>2+</sup>(aq)E°<sub>cell</sub> = 0.30V Sn(s)+ Fe2+(aq)E°cell = 0.30V

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Based on the data presented below,which is the strongest reducing agent? E°(V) Al3+ + 3e- → Al(s)-1.66 AgBr(s)+ e- → Ag(s)+Br- +0.07 Sn4+ + 2e- → Sn2+ +0.14 Fe3+ + e- → Fe2+ +0.77

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What would you observe if you set up the following electrochemical cell: Ag|AgNO3(0.001 M)||AgNO3(1 M)|Ag?

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What is E°cell for the following reaction,and is it spontaneous or nonspontaneous under standard-state conditions? 2Fe3+(aq)+ 2H2O(l)→ H2O2(aq)+ 2H+(aq)+ 2Fe2+(aq) Given: H2O2(aq)+ 2H+(aq)+ 2e- What is E°<sub>cell</sub> for the following reaction,and is it spontaneous or nonspontaneous under standard-state conditions? 2Fe<sup>3+</sup>(aq)+ 2H<sub>2</sub>O(l)→ H<sub>2</sub>O<sub>2</sub>(aq)+ 2H<sup>+</sup>(aq)+ 2Fe<sup>2+</sup>(aq) Given: H<sub>2</sub>O<sub>2</sub>(aq)+ 2H<sup>+</sup>(aq)+ 2e<sup>-</sup> <sup> </sup>   2H<sub>2</sub>O(l)E° = 1.77V Fe<sup>3+</sup>(aq)+ e<sup>-</sup>   Fe<sup>2+</sup>(aq)E° = 0.77V 2H2O(l)E° = 1.77V Fe3+(aq)+ e- What is E°<sub>cell</sub> for the following reaction,and is it spontaneous or nonspontaneous under standard-state conditions? 2Fe<sup>3+</sup>(aq)+ 2H<sub>2</sub>O(l)→ H<sub>2</sub>O<sub>2</sub>(aq)+ 2H<sup>+</sup>(aq)+ 2Fe<sup>2+</sup>(aq) Given: H<sub>2</sub>O<sub>2</sub>(aq)+ 2H<sup>+</sup>(aq)+ 2e<sup>-</sup> <sup> </sup>   2H<sub>2</sub>O(l)E° = 1.77V Fe<sup>3+</sup>(aq)+ e<sup>-</sup>   Fe<sup>2+</sup>(aq)E° = 0.77V Fe2+(aq)E° = 0.77V

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Complete and balance the following redox equation.When properly balanced using the smallest whole-number coefficients,the coefficient of S is H2S + HNO3 → S + NO + H2O (acidic solution)

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Consider the following redox equation. Mn(OH)2(s)+ MnO4-(aq)→ MnO42-(aq) (basic solution) When the equation is balanced with the smallest whole number coefficients,what is the coefficient for OH-(aq)and on which side of the equation is OH-(aq)present?

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Complete and balance the following redox equation using the set of smallest whole numbers coefficients.What is the sum of the coefficients? HI + HNO3 → I2 + NO (acidic solution)

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Based on the following electrochemical cell,what is the standard reduction potential of metal M at 298 K? Based on the following electrochemical cell,what is the standard reduction potential of metal M at 298 K?   Half-Reaction E° (V) Ni<sup>2+</sup>(aq)+ 2e<sup>-</sup> →Ni(s)-0.25 Half-Reaction E° (V) Ni2+(aq)+ 2e- →Ni(s)-0.25

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What is the minimum voltage required for the electrolysis of 1.0 M NaCl in neutral solution? 2H2O + 2Cl- (1.0 M)→ H2(1 atm)+ Cl2(1 atm)+ 2OH-(1 × 10-7 M) Note that 2H2O(l)+ 2e- → H2(g)+2OH-(aq),E° = -0.83 V, 2H2O(l)+ 2e- → H2(g)+2OH-(aq),E = -0.41 V([OH-] = 1 × 10-7M), O2(g)+ 4H+(aq)+ 4e- →2H2O(l),E° = +1.23 V, Cl2(g)+ 2e- → 2Cl-(aq)E° = +1.36 V,and Na+(aq)+ e- → Na(s)E° = -2.71 V

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