Exam 1: Introduction and Review

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Draw the line-angle formula for three compounds with molecular formula C3H8O.

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Consider the species CH3O-, NH2-, and CH3COO-. Rank these ions in order of increasing basicity, and explain your rationale.

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Use the curved arrow formalism to show the movement of electron pairs in the following reaction. Use the curved arrow formalism to show the movement of electron pairs in the following reaction.

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Stabilization of a charged species usually results when this species can be more accurately depicted as a hybrid of several resonance forms. Why is this the case?

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One or more of the atoms in the structure shown should have nonzero formal charges. Redraw the structure and indicate any such charges. One or more of the atoms in the structure shown should have nonzero formal charges. Redraw the structure and indicate any such charges.

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Compute the empirical and molecular formulas for the compound of molecular weight 86 g/mol which is shown to contain 55.8% C and 7.0% H by elemental analysis.

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Which of the following condensed formulas correctly represents the line-angle structure shown below? Which of the following condensed formulas correctly represents the line-angle structure shown below?

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