Exam 13: Reactions of Alkanes, Radicals

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Calculate the overall ΔH° for the reaction shown given the bond dissociation energies (in kcal/mol)below: (CH3)3C-H + Cl-Cl → (CH3)3C - Cl + H-Cl 91 58 78.5 103

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The major type of reactions that alkanes undergo is ________.

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When 1,1,3,3-tetramethylcyclobutane is brominated at 125°C, the relative reactivity of the 1°: 2° :3° hydrogens is approximately 1: 82: 1600. Estimate the amount of each monobromination product.

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What sequence of reagents can be used to accomplish the conversion shown below? What sequence of reagents can be used to accomplish the conversion shown below?

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Provide the major organic product of the following reactions. Provide the major organic product of the following reactions.

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Give the best product for the following reaction. Give the best product for the following reaction.

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Which of the following statements concerning the use of hydrocarbons as fuels is not correct?

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Rank the free radicals (I-III)shown below in order of decreasing stability (i.e., from most stable to least stable). Rank the free radicals (I-III)shown below in order of decreasing stability (i.e., from most stable to least stable).

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Which of the following is the most stable radical? Which of the following is the most stable radical?

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Which of the following is the initiation step for the monobromination of cyclohexane? Which of the following is the initiation step for the monobromination of cyclohexane?

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