Exam 15: Chemical Equilibrium
Exam 1: Introduction: Matter and Measurement163 Questions
Exam 2: Atoms, Molecules, and Ions250 Questions
Exam 3: Stoichiometry: Calculations With Chemical Formulas and Equations178 Questions
Exam 4: Aqueous Reactions and Solution Stoichiometry180 Questions
Exam 5: Thermochemistry154 Questions
Exam 6: Electronic Structure of Atoms186 Questions
Exam 7: Periodic Properties of the Elements176 Questions
Exam 8: Basic Concepts of Chemical Bonding147 Questions
Exam 9: Molecular Geometry and Bonding Theories183 Questions
Exam 10: Gases175 Questions
Exam 11: Liquids and Intermolecular Forces124 Questions
Exam 12: Solids and Modern Materials84 Questions
Exam 13: Properties of Solutions160 Questions
Exam 14: Chemical Kinetics134 Questions
Exam 15: Chemical Equilibrium97 Questions
Exam 16: Acid-Base Equilibria139 Questions
Exam 17: Additional Aspects of Aqueous Equilibria116 Questions
Exam 18: Chemistry of the Environment126 Questions
Exam 19: Chemical Thermodynamics125 Questions
Exam 20: Electrochemistry114 Questions
Exam 21: Nuclear Chemistry178 Questions
Exam 22: Chemistry of the Nonmetals194 Questions
Exam 23: Transition Metals and Coordination Chemistry165 Questions
Exam 24: The Chemistry of Life: Organic and Biological Chemistry131 Questions
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In which of the following reactions would increasing pressure at constant temperature change the concentrations of reactants and products, based on Le Châteliers principle?
(Multiple Choice)
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Consider the following reaction at equilibrium: 2CO2 (g)
2CO (g) + O2 (g)ΔH° = -514 kJ
Le Châtelier's principle predicts that removing O2 (g)to the reaction container will ________.
(Multiple Choice)
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Phosphorous trichloride and phosphorous pentachloride equilibrate in the presence of molecular chlorine according to the reaction: PCl3 (g)+ Cl2 (g) → PCl5 (g)
An equilibrium mixture at 450 K contains
PPCl3 = 0.224 atm,
PCl2 = 0.284 atm, and
PPCl5 = 4.24 atm. What is the value of Kp at this temperature?
(Multiple Choice)
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Which of the following expressions is the correct equilibrium-constant expression for the following reaction? CO2 (g)+ 2H2 (g)
CH3OH (g)
(Multiple Choice)
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Consider the following reaction at equilibrium: C (s) + H2O (g)
CO (g) + H2 (g)
Which of the following conditions will decrease the partial pressure of CO?
(Multiple Choice)
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At 400 K, the equilibrium constant for the reaction Br2 (g) + Cl2 (g)
2BrCl (g)
Is Kp = 7.0. A closed vessel at 400 K is charged with 1.00 atm of Br2 (g), 1.00 atm of Cl2 (g), and 2.00 atm of BrCl (g). Use Q to determine which of the statements below is true.
(Multiple Choice)
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At 24° C, Kp = 0.080 for the equilibrium: NH4HS (s)
NH3 (g) + H2S (g)
A sample of solid NH4HS is placed in a closed vessel and allowed to equilibrate. Calculate the equilibrium partial pressure (atm)of ammonia, assuming that some solid NH4HS remains.
(Multiple Choice)
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The Kp for the reaction below is 1.49 × 108 at 100.0 °C: CO (g)+ Cl2 (g) → COCl2 (g)
In an equilibrium mixture of the three gases, PCO = PCl2 = 1.00 × 10-4 atm. The partial pressure of the product, phosgene (COCl2), is ________ atm.
(Multiple Choice)
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The equilibrium constant (Kp)for the interconversion of PCl5 and PCl3 is 0.0121: PCl5 (g)
PCl3 (g) + Cl2 (g)
A vessel is charged with PCl5 giving an initial pressure of 0.123 atm. At equilibrium, the partial pressure of PCl3 is ________ atm.
(Multiple Choice)
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Given the following reaction at equilibrium at 300.0 K: NH4HS (s)
NH3 (g) + H2S (g)
If pNH3 = pH2S = 0.105 atm, Kp = ________.
(Multiple Choice)
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Consider the following chemical reaction: H2 (g) + I2 (g)
2HI (g)
At equilibrium in a particular experiment, the concentrations of H2, I2, and HI were 0.20 M, 0.034 M, and 0.55 M, respectively. The value of Keq for this reaction is ________.
(Multiple Choice)
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The Keq for the equilibrium below is 5.4 × 1013 at 480.0 °C. 2NO (g) + O2 (g)
2NO2 (g)
What is the value of Keq at this temperature for the following reaction?
NO2 (g)
NO (g) +
O2 (g)
(Multiple Choice)
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Dinitrogen tetroxide partially decomposes according to the following equilibrium: N2O4 (g) → 2NO2 (g)
A 1.000-L flask is charged with 9.20 × 10-3 mol of N2O4. At equilibrium, 5.98 × 10-3 mol of N2O4 remains. Keq for this reaction is ________.
(Multiple Choice)
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The equilibrium-constant expression depends on the ________ of the reaction.
(Multiple Choice)
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In what year was Fritz Haber awarded the Nobel Prize in chemistry for his development of a process for synthesizing ammonia directly from nitrogen and hydrogen?
(Multiple Choice)
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Which of the following expressions is the correct equilibrium-constant expression for the equilibrium between dinitrogen tetroxide and nitrogen dioxide? N2O4 (g)
2NO2 (g)
(Multiple Choice)
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Which of the following expressions is the correct equilibrium-constant expression for the reaction below? HF (aq)+ H2O (l)
H3O+ (aq)+ F- (aq)
(Multiple Choice)
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