Exam 15: Chemical Equilibrium

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The value of Keq for the equilibrium H2 (g) + I2 (g) The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g) + I<sub>2</sub> (g)   2HI (g) Is 794 at 25 °C. At this temperature, what is the value of K<sub>eq</sub> for the equilibrium below? HI (g)     H<sub>2</sub> (g) +   I<sub>2</sub> (g) 2HI (g) Is 794 at 25 °C. At this temperature, what is the value of Keq for the equilibrium below? HI (g) The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g) + I<sub>2</sub> (g)   2HI (g) Is 794 at 25 °C. At this temperature, what is the value of K<sub>eq</sub> for the equilibrium below? HI (g)     H<sub>2</sub> (g) +   I<sub>2</sub> (g) The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g) + I<sub>2</sub> (g)   2HI (g) Is 794 at 25 °C. At this temperature, what is the value of K<sub>eq</sub> for the equilibrium below? HI (g)     H<sub>2</sub> (g) +   I<sub>2</sub> (g) H2 (g) + The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g) + I<sub>2</sub> (g)   2HI (g) Is 794 at 25 °C. At this temperature, what is the value of K<sub>eq</sub> for the equilibrium below? HI (g)     H<sub>2</sub> (g) +   I<sub>2</sub> (g) I2 (g)

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The expression for Kp for the reaction below is ________. 4CuO (s) + CH4 (g) The expression for K<sub>p</sub> for the reaction below is ________. 4CuO (s) + CH<sub>4</sub> (g)   CO<sub>2</sub> (g) + 4Cu (s) + 2H<sub>2</sub>O (g) CO2 (g) + 4Cu (s) + 2H2O (g)

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For an exothermic reaction, increasing the reaction temperature results in a(n)________ in K.

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A reaction vessel is charged with hydrogen iodide, which partially decomposes to molecular hydrogen and iodine: 2HI (g) A reaction vessel is charged with hydrogen iodide, which partially decomposes to molecular hydrogen and iodine: 2HI (g)   H<sub>2</sub>(g) + I<sub>2</sub>(g) When the system comes to equilibrium at 425 °C, P<sub>HI</sub> = 0.708 atm, and P<sub>H</sub><sub>2</sub> = P<sub>I</sub><sub>2</sub> = 0.0960 atm. The value of K<sub>p</sub> at this temperature is ________. H2(g) + I2(g) When the system comes to equilibrium at 425 °C, PHI = 0.708 atm, and PH2 = PI2 = 0.0960 atm. The value of Kp at this temperature is ________.

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Exactly 3.5 moles if N2O4 is placed in an empty 2.0-L container and allowed to reach equilibrium described by the equation N2O4 (g)⇌ 2NO2 (g) If at equilibrium the N2O4 is 25% dissociated, what is the value of the equilibrium constant for the reaction?

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Acetic acid is a weak acid that dissociates into the acetate ion and a proton in aqueous solution: HC2H3O2 (aq) Acetic acid is a weak acid that dissociates into the acetate ion and a proton in aqueous solution: HC<sub>2</sub>H<sub>3</sub>O<sub>2</sub> (aq)   C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup> (aq) + H<sup>+</sup> (aq) At equilibrium at 25 °C a 0.100 M solution of acetic acid has the following concentrations: [HC<sub>2</sub>H<sub>3</sub>O<sub>2</sub>] = 0.0990 M, [C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup>] = 1.33 × 10<sup>-3</sup><sup> </sup>M and [H+] = 1.33 × 10<sup>-3</sup><sup> </sup>M. The equilibrium constant, K<sub>eq</sub>, for the ionization of acetic acid at 25 °C is ________. C2H3O2- (aq) + H+ (aq) At equilibrium at 25 °C a 0.100 M solution of acetic acid has the following concentrations: [HC2H3O2] = 0.0990 M, [C2H3O2-] = 1.33 × 10-3 M and [H+] = 1.33 × 10-3 M. The equilibrium constant, Keq, for the ionization of acetic acid at 25 °C is ________.

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What role did Karl Bosch play in development of the Haber-Bosch process?

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Nitrosyl bromide decomposes according to the following equation. 2NOBr (g) Nitrosyl bromide decomposes according to the following equation. 2NOBr (g)   2NO (g) + Br<sub>2</sub> (g) A sample of NOBr (0.64 mol)was placed in a 1.00-L flask containing no NO or Br<sub>2</sub>. At equilibrium the flask contained 0.16 mol of NOBr. How many moles of NO and Br<sub>2</sub>, respectively, are in the flask at equilibrium? 2NO (g) + Br2 (g) A sample of NOBr (0.64 mol)was placed in a 1.00-L flask containing no NO or Br2. At equilibrium the flask contained 0.16 mol of NOBr. How many moles of NO and Br2, respectively, are in the flask at equilibrium?

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At constant temperature, reducing the volume of a gaseous equilibrium mixture causes the reaction to shift in the direction that increases the number of moles of gas in the system.

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If the value for the equilibrium constant is much greater than 1, then the equilibrium mixture contains mostly ________.

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Which of the following expressions is the correct equilibrium-constant expression for the reaction below? (NH4)2Se (s) Which of the following expressions is the correct equilibrium-constant expression for the reaction below? (NH<sub>4</sub>)<sub>2</sub>Se (s)   2NH<sub>3</sub> (g) + H<sub>2</sub>Se (g) 2NH3 (g) + H2Se (g)

(Multiple Choice)
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Consider the following chemical reaction: CO (g) + 2H2(g) Consider the following chemical reaction: CO (g) + 2H<sub>2</sub>(g)   CH<sub>3</sub>OH(g) At equilibrium in a particular experiment, the concentrations of CO and H<sub>2</sub> were 0.15 M and 0.36, M respectively. What is the equilibrium concentration of CH<sub>3</sub>OH? The value of K<sub>eq</sub> for this reaction is 14.5 at the temperature of the experiment. CH3OH(g) At equilibrium in a particular experiment, the concentrations of CO and H2 were 0.15 M and 0.36, M respectively. What is the equilibrium concentration of CH3OH? The value of Keq for this reaction is 14.5 at the temperature of the experiment.

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The value of Keq for the equilibrium H2 (g) + I2 (g) The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g) + I<sub>2</sub> (g)   2HI (g) Is 794 at 25 °C. What is the value of K<sub>eq</sub> for the equilibrium below?   H<sub>2</sub> (g) +   I<sub>2</sub> (g)   HI (g) 2HI (g) Is 794 at 25 °C. What is the value of Keq for the equilibrium below? The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g) + I<sub>2</sub> (g)   2HI (g) Is 794 at 25 °C. What is the value of K<sub>eq</sub> for the equilibrium below?   H<sub>2</sub> (g) +   I<sub>2</sub> (g)   HI (g) H2 (g) + The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g) + I<sub>2</sub> (g)   2HI (g) Is 794 at 25 °C. What is the value of K<sub>eq</sub> for the equilibrium below?   H<sub>2</sub> (g) +   I<sub>2</sub> (g)   HI (g) I2 (g) The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g) + I<sub>2</sub> (g)   2HI (g) Is 794 at 25 °C. What is the value of K<sub>eq</sub> for the equilibrium below?   H<sub>2</sub> (g) +   I<sub>2</sub> (g)   HI (g) HI (g)

(Multiple Choice)
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The value of Keq for the equilibrium H2 (g) + I2 (g) The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g) + I<sub>2</sub> (g)   2HI (g) Is 54.0 at 427 °C. What is the value of K<sub>eq</sub> for the equilibrium below? HI (g)     H<sub>2</sub> (g) +   I<sub>2</sub>(g) 2HI (g) Is 54.0 at 427 °C. What is the value of Keq for the equilibrium below? HI (g) The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g) + I<sub>2</sub> (g)   2HI (g) Is 54.0 at 427 °C. What is the value of K<sub>eq</sub> for the equilibrium below? HI (g)     H<sub>2</sub> (g) +   I<sub>2</sub>(g) The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g) + I<sub>2</sub> (g)   2HI (g) Is 54.0 at 427 °C. What is the value of K<sub>eq</sub> for the equilibrium below? HI (g)     H<sub>2</sub> (g) +   I<sub>2</sub>(g) H2 (g) + The value of K<sub>eq</sub> for the equilibrium H<sub>2</sub> (g) + I<sub>2</sub> (g)   2HI (g) Is 54.0 at 427 °C. What is the value of K<sub>eq</sub> for the equilibrium below? HI (g)     H<sub>2</sub> (g) +   I<sub>2</sub>(g) I2(g)

(Multiple Choice)
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Which of the following expressions is the correct equilibrium-constant expression for the equilibrium between dinitrogen tetroxide and nitrogen dioxide? 5N2O4(g) Which of the following expressions is the correct equilibrium-constant expression for the equilibrium between dinitrogen tetroxide and nitrogen dioxide? 5N<sub>2</sub>O4(g)   10NO<sub>2</sub> (g) 10NO2 (g)

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The Keq for the equilibrium below is 0.112 at 700.0 °C. SO2 (g) + The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0 °C. SO<sub>2</sub> (g) +   O<sub>2</sub> (g)   SO<sub>3</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2SO<sub>2</sub> (g) + O<sub>2</sub> (g)   2SO<sub>3</sub> (g) O2 (g) The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0 °C. SO<sub>2</sub> (g) +   O<sub>2</sub> (g)   SO<sub>3</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2SO<sub>2</sub> (g) + O<sub>2</sub> (g)   2SO<sub>3</sub> (g) SO3 (g) What is the value of Keq at this temperature for the following reaction? 2SO2 (g) + O2 (g) The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0 °C. SO<sub>2</sub> (g) +   O<sub>2</sub> (g)   SO<sub>3</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2SO<sub>2</sub> (g) + O<sub>2</sub> (g)   2SO<sub>3</sub> (g) 2SO3 (g)

(Multiple Choice)
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Of the following equilibria, only ________ will shift to the right in response to a decrease in volume.

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The value of Keq for the following reaction is 0.25: SO2 (g) + NO2 (g) The value of K<sub>eq</sub> for the following reaction is 0.25: SO<sub>2</sub> (g) + NO<sub>2</sub> (g)   SO<sub>3</sub> (g) + NO (g) The value of K<sub>eq</sub> at the same temperature for the reaction below is ________. 3SO<sub>2</sub> (g) + 3NO<sub>2</sub> (g)   3SO<sub>3</sub> (g) + 3NO (g) SO3 (g) + NO (g) The value of Keq at the same temperature for the reaction below is ________. 3SO2 (g) + 3NO2 (g) The value of K<sub>eq</sub> for the following reaction is 0.25: SO<sub>2</sub> (g) + NO<sub>2</sub> (g)   SO<sub>3</sub> (g) + NO (g) The value of K<sub>eq</sub> at the same temperature for the reaction below is ________. 3SO<sub>2</sub> (g) + 3NO<sub>2</sub> (g)   3SO<sub>3</sub> (g) + 3NO (g) 3SO3 (g) + 3NO (g)

(Multiple Choice)
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Consider the following reaction at equilibrium: 2CO2 (g) Consider the following reaction at equilibrium: 2CO<sub>2</sub> (g)   2CO (g) + O<sub>2</sub> (g)ΔH° = -514 kJ Le Châtelier's principle predicts that an increase in temperature will ________. 2CO (g) + O2 (g)ΔH° = -514 kJ Le Châtelier's principle predicts that an increase in temperature will ________.

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Consider the following reaction at equilibrium. 2CO2 (g) Consider the following reaction at equilibrium. 2CO<sub>2</sub> (g)   2CO (g) + O<sub>2</sub> (g)ΔH° = -514 kJ Le Châtelier's principle predicts that the equilibrium partial pressure of CO (g)can be maximized by carrying out the reaction ________. 2CO (g) + O2 (g)ΔH° = -514 kJ Le Châtelier's principle predicts that the equilibrium partial pressure of CO (g)can be maximized by carrying out the reaction ________.

(Multiple Choice)
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