Exam 15: Chemical Equilibrium

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At elevated temperatures, molecular hydrogen and molecular bromine react to partially form hydrogen bromide: H2 (g) + Br2 (g) At elevated temperatures, molecular hydrogen and molecular bromine react to partially form hydrogen bromide: H<sub>2</sub> (g) + Br<sub>2 </sub>(g)   2HBr (g) A mixture of 0.682 mol of H<sub>2</sub> and 0.440 mol of Br<sub>2</sub> is combined in a reaction vessel with a volume of 2.00 L. At equilibrium at 700 K, there are 0.546 mol of H<sub>2</sub> present. At equilibrium, there are ________ mol of Br<sub>2</sub> present in the reaction vessel. 2HBr (g) A mixture of 0.682 mol of H2 and 0.440 mol of Br2 is combined in a reaction vessel with a volume of 2.00 L. At equilibrium at 700 K, there are 0.546 mol of H2 present. At equilibrium, there are ________ mol of Br2 present in the reaction vessel.

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The value of Keq for the equilibrium CO2 (g) + 2H2 (g) The value of K<sub>eq</sub> for the equilibrium CO<sub>2</sub> (g) + 2H<sub>2</sub> (g)   CH<sub>3</sub>OH (g) Is 14.5 at 483 °C. What is the value of K<sub>eq</sub> for the equilibrium below?   CO<sub>2</sub> + H<sub>2</sub> (g)     CH<sub>3</sub>OH (g) CH3OH (g) Is 14.5 at 483 °C. What is the value of Keq for the equilibrium below? The value of K<sub>eq</sub> for the equilibrium CO<sub>2</sub> (g) + 2H<sub>2</sub> (g)   CH<sub>3</sub>OH (g) Is 14.5 at 483 °C. What is the value of K<sub>eq</sub> for the equilibrium below?   CO<sub>2</sub> + H<sub>2</sub> (g)     CH<sub>3</sub>OH (g) CO2 + H2 (g) The value of K<sub>eq</sub> for the equilibrium CO<sub>2</sub> (g) + 2H<sub>2</sub> (g)   CH<sub>3</sub>OH (g) Is 14.5 at 483 °C. What is the value of K<sub>eq</sub> for the equilibrium below?   CO<sub>2</sub> + H<sub>2</sub> (g)     CH<sub>3</sub>OH (g) The value of K<sub>eq</sub> for the equilibrium CO<sub>2</sub> (g) + 2H<sub>2</sub> (g)   CH<sub>3</sub>OH (g) Is 14.5 at 483 °C. What is the value of K<sub>eq</sub> for the equilibrium below?   CO<sub>2</sub> + H<sub>2</sub> (g)     CH<sub>3</sub>OH (g) CH3OH (g)

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The equilibrium constant for the gas phase reaction N2 (g) + O2 (g) The equilibrium constant for the gas phase reaction N<sub>2</sub> (g) + O<sub>2</sub> (g)   2NO (g) Is K<sub>eq</sub> = 4.20 × 10<sup>-31</sup> at 30 °C. At equilibrium, ________. 2NO (g) Is Keq = 4.20 × 10-31 at 30 °C. At equilibrium, ________.

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The reaction below is exothermic: 2SO2 (g) + O2 (g) The reaction below is exothermic: 2SO<sub>2</sub> (g) + O<sub>2</sub> (g)   2SO<sub>3</sub> (g) Le Châtelier's Principle predicts that ________ will result in an increase in the number of moles of SO<sub>3</sub> (g)in the reaction container. 2SO3 (g) Le Châtelier's Principle predicts that ________ will result in an increase in the number of moles of SO3 (g)in the reaction container.

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The equilibrium constant for reaction 1 is K. The equilibrium constant for reaction 2 is ________. (1) SO2 (g) + (1/2)O2 (g) The equilibrium constant for reaction 1 is K. The equilibrium constant for reaction 2 is ________. (1) SO<sub>2</sub> (g) + (1/2)O<sub>2</sub> (g)   SO<sub>3</sub> (g) (2) 2SO<sub>3</sub> (g)   2SO<sub>2</sub> (g) + O<sub>2</sub> (g) SO3 (g) (2) 2SO3 (g) The equilibrium constant for reaction 1 is K. The equilibrium constant for reaction 2 is ________. (1) SO<sub>2</sub> (g) + (1/2)O<sub>2</sub> (g)   SO<sub>3</sub> (g) (2) 2SO<sub>3</sub> (g)   2SO<sub>2</sub> (g) + O<sub>2</sub> (g) 2SO2 (g) + O2 (g)

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For the endothermic reaction CaCO3 (s) For the endothermic reaction CaCO<sub>3</sub> (s)   CaO (s) + CO<sub>2</sub> (g) Le Châtelier's principle predicts that ________ will result in an increase in the number of moles of CO<sub>2</sub>. CaO (s) + CO2 (g) Le Châtelier's principle predicts that ________ will result in an increase in the number of moles of CO2.

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The equilibrium expression for Kp for the reaction below is ________. N2 (g) + O2 (g) The equilibrium expression for K<sub>p</sub> for the reaction below is ________. N<sub>2</sub> (g) + O<sub>2</sub> (g)   2NO (g) 2NO (g)

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If the reaction quotient Q for a reaction is less than the value of the equilibrium constant K for that reaction at a given temperature, ________ must be converted to ________ for the system to reach equilibrium.

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In the coal-gasification process, carbon monoxide is converted to carbon dioxide via the following reaction: CO (g) + H2O (g) In the coal-gasification process, carbon monoxide is converted to carbon dioxide via the following reaction: CO (g) + H<sub>2</sub>O (g)   CO<sub>2</sub> (g) + H<sub>2</sub> (g) In an experiment, 0.35 mol of CO and 0.40 mol of H<sub>2</sub>O were placed in a 1.00-L reaction vessel. At equilibrium, there were 0.22 mol of CO remaining. K<sub>eq</sub> at the temperature of the experiment is ________. CO2 (g) + H2 (g) In an experiment, 0.35 mol of CO and 0.40 mol of H2O were placed in a 1.00-L reaction vessel. At equilibrium, there were 0.22 mol of CO remaining. Keq at the temperature of the experiment is ________.

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In which of the following reactions would increasing pressure at constant temperature not change the concentrations of reactants and products, based on Le Châtelier's principle?

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The expression of Keq for the following reaction will not include ________. A(g) + B (g) The expression of K<sub>eq</sub> for the following reaction will not include ________. A(g) + B (g)   C (l) + D (g) C (l) + D (g)

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At equilibrium, ________.

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The value of Keq for the following reaction is 0.50: A (g) + 2B (g) The value of K<sub>eq</sub> for the following reaction is 0.50: A (g) + 2B (g)   C (g) + 4D (g) The value of K<sub>eq</sub> at the same temperature for the reaction below is ________.   A (g) + B (g)     C (g) + 2D (g) C (g) + 4D (g) The value of Keq at the same temperature for the reaction below is ________. The value of K<sub>eq</sub> for the following reaction is 0.50: A (g) + 2B (g)   C (g) + 4D (g) The value of K<sub>eq</sub> at the same temperature for the reaction below is ________.   A (g) + B (g)     C (g) + 2D (g) A (g) + B (g) The value of K<sub>eq</sub> for the following reaction is 0.50: A (g) + 2B (g)   C (g) + 4D (g) The value of K<sub>eq</sub> at the same temperature for the reaction below is ________.   A (g) + B (g)     C (g) + 2D (g) The value of K<sub>eq</sub> for the following reaction is 0.50: A (g) + 2B (g)   C (g) + 4D (g) The value of K<sub>eq</sub> at the same temperature for the reaction below is ________.   A (g) + B (g)     C (g) + 2D (g) C (g) + 2D (g)

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The Keq for the equilibrium below is 7.16 × 10-2 at 440.0 °C. 2Cl2 (g) + 2H2O (g) The K<sub>eq</sub> for the equilibrium below is 7.16 × 10<sup>-2</sup> at 440.0 °C. 2Cl<sub>2</sub> (g) + 2H<sub>2</sub>O (g)   4HCl (g) + O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? Cl<sub>2</sub> (g) + H<sub>2</sub>O (g)   2HCl (g) +   O<sub>2</sub> (g) 4HCl (g) + O2 (g) What is the value of Keq at this temperature for the following reaction? Cl2 (g) + H2O (g) The K<sub>eq</sub> for the equilibrium below is 7.16 × 10<sup>-2</sup> at 440.0 °C. 2Cl<sub>2</sub> (g) + 2H<sub>2</sub>O (g)   4HCl (g) + O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? Cl<sub>2</sub> (g) + H<sub>2</sub>O (g)   2HCl (g) +   O<sub>2</sub> (g) 2HCl (g) + The K<sub>eq</sub> for the equilibrium below is 7.16 × 10<sup>-2</sup> at 440.0 °C. 2Cl<sub>2</sub> (g) + 2H<sub>2</sub>O (g)   4HCl (g) + O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? Cl<sub>2</sub> (g) + H<sub>2</sub>O (g)   2HCl (g) +   O<sub>2</sub> (g) O2 (g)

(Multiple Choice)
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Consider the following equilibrium. 2 SO2 (g) + O2 (g) Consider the following equilibrium. 2 SO<sub>2</sub> (g) + O<sub>2</sub> (g)   2 SO<sub>3</sub> (g) The equilibrium cannot be established when ________ is/are placed in a 1.0-L container. 2 SO3 (g) The equilibrium cannot be established when ________ is/are placed in a 1.0-L container.

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If Reaction A + Reaction B = Reaction C, then Kc Reaction C = ________.

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The effect of a catalyst on an equilibrium is to ________.

(Multiple Choice)
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Given the following reaction: CO (g) + 2 H2(g) Given the following reaction: CO (g) + 2 H<sub>2</sub>(g)   CH<sub>3</sub>OH (g) In an experiment, 0.42 mol of CO and 0.42 mol of H<sub>2</sub> were placed in a 1.00-L reaction vessel. At equilibrium, there were 0.29 mol of CO remaining. K<sub>eq</sub> at the temperature of the experiment is ________. CH3OH (g) In an experiment, 0.42 mol of CO and 0.42 mol of H2 were placed in a 1.00-L reaction vessel. At equilibrium, there were 0.29 mol of CO remaining. Keq at the temperature of the experiment is ________.

(Multiple Choice)
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The effect of a catalyst on a chemical reaction is to react with product, effectively removing it and shifting the equilibrium to the right.

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Given the following reaction at equilibrium, if Kp = 1.10 at 250.0 °C, Kc = ________. PCl5 (g) Given the following reaction at equilibrium, if K<sub>p</sub> = 1.10 at 250.0 °C, K<sub>c</sub> = ________. PCl<sub>5</sub> (g)   PCl<sub>3</sub> (g) + Cl<sub>2</sub> (g) PCl3 (g) + Cl2 (g)

(Multiple Choice)
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