Exam 12: Infrared Spectroscopy

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MATCH each of the following groups of bond-types to the region of the infrared spectrum in which their absorptions occur. Place the letter of the region in the blank to the left of the bond-type. -_____ triple bond stretching vibrations.

(Multiple Choice)
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The given molecule shows a stretching absorption peak at 2200-2250 cm−1 due to the presence of a _____. ​ The given molecule shows a stretching absorption peak at 2200-2250 cm<sup>−1</sup> due to the presence of a _____. ​

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Which of the following functional groups is likely to be present in a molecule that has peaks in the infrared spectrum at 3200-3650 cm−1 (strong), but does not have peaks at 1630-1820 or 1000-1250 cm−1

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Which of the following compounds gives an infrared spectrum with a peak in the range of 1630-1820 cm−1 (strong peak), but does not have peaks at 3200-3650 or 1000-1250 cm−1? Which of the following compounds gives an infrared spectrum with a peak in the range of 1630-1820 cm−<sup>1</sup> (strong peak), but does not have peaks at 3200-3650 or 1000-1250 cm−<sup>1</sup>?

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Which of the following bonds (circled) gives a very weak or no stretching absorption in the infrared spectrum? Which of the following bonds (circled) gives a very weak or no stretching absorption in the infrared spectrum?

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Which of the following laws relates the frequency of a stretching vibration to the masses and spring constant of a simple harmonic oscillator?

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MATCH a structure from the list below to the following IR spectra. Place the letter of the structure in the blank provided. -_____ MATCH a structure from the list below to the following IR spectra. Place the letter of the structure in the blank provided. -_____   Spectrum obtained from: SDBSWeb: http://www.aist.go.jp/RIODB/SDBS/ Spectrum obtained from: SDBSWeb: http://www.aist.go.jp/RIODB/SDBS/

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Why KBr and NaCl are used for sample preparation in the infrared spectroscopic analysis of compounds?

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MATCH a structure from the list below to the following IR spectra. Place the letter of the structure in the blank provided. -_____ MATCH a structure from the list below to the following IR spectra. Place the letter of the structure in the blank provided. -_____   Spectrum obtained from: SDBSWeb: http://www.aist.go.jp/RIODB/SDBS/ Spectrum obtained from: SDBSWeb: http://www.aist.go.jp/RIODB/SDBS/

(Multiple Choice)
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MATCH each of the following groups of bond-types to the region of the infrared spectrum in which their absorptions occur. Place the letter of the region in the blank to the left of the bond-type. -_____ C=O, C=N, and C=C bond absorptions.

(Multiple Choice)
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Which of the following compounds gives an infrared spectrum with peaks in the ranges of 3200-3650 (strong, broad), but does not have peaks at 1630-1820 (strong) or 1600-1640 cm−1 (medium)? Which of the following compounds gives an infrared spectrum with peaks in the ranges of 3200-3650 (strong, broad), but does not have peaks at 1630-1820 (strong) or 1600-1640 cm−<sup>1</sup> (medium)?

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Which of the following compounds does not give an infrared spectrum with peak at ∼1750 cm−1? ​ Which of the following compounds does not give an infrared spectrum with peak at ∼1750 cm−<sup>1</sup>? ​   ​ ​

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What range of wavelengths corresponds to the infrared region of the electromagnetic spectrum?

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Which of the following compounds gives an infrared spectrum with a peak at ∼1750 cm−1, but no significant peaks at 3000-3500 cm−1 or 1050-1250 cm−1? ​ Which of the following compounds gives an infrared spectrum with a peak at ∼1750 cm−<sup>1</sup>, but no significant peaks at 3000-3500 cm−<sup>1</sup> or 1050-1250 cm−<sup>1</sup>? ​   ​ ​

(Multiple Choice)
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Which of the following compounds gives an infrared spectrum with peaks in the ranges of 3200-3650 (strong, broad) and 1600-1640 cm−1 (medium); but does not have peaks at 1630-1820 (strong)? Which of the following compounds gives an infrared spectrum with peaks in the ranges of 3200-3650 (strong, broad) and 1600-1640 cm−<sup>1</sup> (medium); but does not have peaks at 1630-1820 (strong)?

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Which of the following bonds gives rise to a medium strength absorbance at approximately 1600-1680 cm−1 in the infrared spectrum?

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Which of the following bonds undergoes stretching at the highest frequency?

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MATCH each of the following molecules to the region of the infrared spectrum in which they may show a significant absorption. Place the letter of the region in the blank to the left of the bond-type. -_______ MATCH each of the following molecules to the region of the infrared spectrum in which they may show a significant absorption. Place the letter of the region in the blank to the left of the bond-type. -_______

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The radio wave region of the electromagnetic spectrum would have sufficient energy to produce the following energy transition. The radio wave region of the electromagnetic spectrum would have sufficient energy to produce the following energy transition.

(True/False)
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Which of the following bonds undergoes stretching at the highest frequency?

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