Question 1

The name of the product formed by reacting CuCl and HCl with benzenediazonium chloride is ________________________.

Accepted Answer

chlorobenzene

Question 2

The following amine can be converted to an aryl diazonium salt.

Accepted Answer

A) True 
 B)False  True

Question 3

Consider the following compounds.   Answer the following questions by filling in the blank with the appropriate number from the diagram or an appropriate term.
-The ammonia ion of substance ____ will have the largest pKa.

Accepted Answer

2
two

Question 4

What is the major organic product obtained form the following sequence of reactions?

Accepted Answer

The answer of What is the major organic product obtained...

Question 5

Identify the type of reaction shown below. ​

Accepted Answer

A)  Balz-Schiemann reaction 
B)  Sandmeyer reaction 
C)  Azo-coupling reaction 
D)  Pschorr reaction 
A)  Balz-Schiemann reaction 
B)  Sandmeyer reaction 
C)  Azo-coupling reaction 
D)  Pschorr reaction

Question 6

What is the major organic product obtained from the following reaction?

Accepted Answer

A)  1 
B)  2 
C)  3 
D)  4 
A)  1 
B)  2 
C)  3 
D)  4

Question 7

_____ is the rapid oscillation of a nitrogen atom from one side of the plane of the three atoms bonded to it to the other side of that plane.

Accepted Answer

The answer of _____ is the rapid oscillation of a...

Question 8

What is the major organic product obtained from the following reaction?

Accepted Answer

A)  1 
B)  2 
C)  3 
D)  4 
A)  1 
B)  2 
C)  3 
D)  4

Question 9

Which of the following amines can be prepared by treatment of a carbonyl compound with sodium cyanide in the presence of acid, followed by reduction?

Accepted Answer

A)  only 1 
B)  only 1 and 2 
C)  only 1, 2 and 3 
D)  1, 2, 3 and 4 
A)  only 1 
B)  only 1 and 2 
C)  only 1, 2 and 3 
D)  1, 2, 3 and 4

Question 10

What is the major organic product obtained from the following reaction?

Accepted Answer

A)  1 
B)  2 
C)  3 
D)  4 
A)  1 
B)  2 
C)  3 
D)  4

Question 11

Consider the following compounds.   Answer the following questions by filling in the blank with the appropriate number from the diagram or an appropriate term.
-Substance _____ is a primary alkyl amine.

Accepted Answer

The answer of Consider the following compounds.   Answer...

Question 12

What is the correct assignment of the names of the functional groups in the following nitrogen-containing compounds?

Accepted Answer

A)  1 = 2° amine; 2 = enamine; 3 = hydrazine 
B)  1 = 2° amine; 2 = amide; 3 = nitrile 
C)  1 =oxime; 2 = hydrazone; 3 = nitrile 
D)  1 = imine; 2 = hydrazone; 3 = amide 
A)  1 = 2° amine; 2 = enamine; 3 = hydrazine 
B)  1 = 2° amine; 2 = amide; 3 = nitrile 
C)  1 =oxime; 2 = hydrazone; 3 = nitrile 
D)  1 = imine; 2 = hydrazone; 3 = amide

Question 13

What is the intermediate in the Cope elimination, in which a 3° amine is treated with hydrogen peroxide followed by heat?

Accepted Answer

A)  a tetraalkylammonium hydroxide salt 
B)  an amine oxide 
C)  a 3° carbocation 
D)  an amide anion 
A)  a tetraalkylammonium hydroxide salt 
B)  an amine oxide 
C)  a 3° carbocation 
D)  an amide anion

Question 14

The name of the product formed by reacting KCN and CuCN with benzenediazonium chloride is ________________________.

Accepted Answer

The answer of The name of the product formed by...

Question 15

Which of the following is the strongest base?

Accepted Answer

A)  ammonia 
B)  dimethylamine 
C)  aniline 
D)  4-nitroaniline 
A)  ammonia 
B)  dimethylamine 
C)  aniline 
D)  4-nitroaniline

Question 16

The pKa of methyl amine is represented by the following reaction. $\mathrm{CH}_{3} \mathrm{NH}_{3}^{+}+\mathrm{H}_{2} \mathrm{O}$$\rightleftharpoons$$\mathrm{CH}_{3} \mathrm{NH}_{3}+\mathrm{H}_{3} \mathrm{O}^{+}$

Accepted Answer

A) True 
 B)False

Question 17

What is the major organic product obtained from the following sequence of reactions?

Accepted Answer

The answer of What is the major organic product obtained...

Question 18

What is the major organic product obtained from the following reaction?

Accepted Answer

A)  1 
B)  2 
C)  3 
D)  4 
A)  1 
B)  2 
C)  3 
D)  4

Question 19

Consider the following compounds.   Answer the following questions by filling in the blank with the appropriate number from the diagram or an appropriate term.
-The ammonia ion of substance ____ will have the smallest pKa.

Accepted Answer

Question 20

The reaction of a 2o amine with nitrous acid gives a nitrosamine.

Accepted Answer

A) True 
 B)False

Exam 23: Amines

The name of the product formed by reacting CuCl and HCl with benzenediazonium chloride is ________________________.

The following amine can be converted to an aryl diazonium salt.

Consider the following compounds. Answer the following questions by filling in the blank with the appropriate number from the diagram or an appropriate term. -The ammonia ion of substance ____ will have the largest pKa.

What is the major organic product obtained form the following sequence of reactions?

Identify the type of reaction shown below. ​

What is the major organic product obtained from the following reaction?

_____ is the rapid oscillation of a nitrogen atom from one side of the plane of the three atoms bonded to it to the other side of that plane.

What is the major organic product obtained from the following reaction?

Which of the following amines can be prepared by treatment of a carbonyl compound with sodium cyanide in the presence of acid, followed by reduction?

What is the major organic product obtained from the following reaction?

Consider the following compounds. Answer the following questions by filling in the blank with the appropriate number from the diagram or an appropriate term. -Substance _____ is a primary alkyl amine.

What is the correct assignment of the names of the functional groups in the following nitrogen-containing compounds?

What is the intermediate in the Cope elimination, in which a 3° amine is treated with hydrogen peroxide followed by heat?

The name of the product formed by reacting KCN and CuCN with benzenediazonium chloride is ________________________.

Which of the following is the strongest base?

The pKa of methyl amine is represented by the following reaction. CH3NH3++H2O\mathrm{CH}_{3} \mathrm{NH}_{3}^{+}+\mathrm{H}_{2} \mathrm{O}CH3​NH3+​+H2​O⇌\rightleftharpoons⇌CH3NH3+H3O+\mathrm{CH}_{3} \mathrm{NH}_{3}+\mathrm{H}_{3} \mathrm{O}^{+}CH3​NH3​+H3​O+

What is the major organic product obtained from the following sequence of reactions?

What is the major organic product obtained from the following reaction?

Consider the following compounds. Answer the following questions by filling in the blank with the appropriate number from the diagram or an appropriate term. -The ammonia ion of substance ____ will have the smallest pKa.

The reaction of a 2o amine with nitrous acid gives a nitrosamine.

Covalent Bonding and Shapes of Molecules

Alkanes and Cycloalkanes

Stereoisomerism and Chirality

Acids and Bases

Alkenes: Bonding, Nomenclature, and Properties

Reactions of Alkenes

Alkynes

Haloalkanes, Halogenation, and Radical Reactions

Nucleophilic Substitution and Beta-Elimination

Alcohols

Ethers, Epoxides, and Sulfides

Infrared Spectroscopy

Nuclear Magnetic Resonance Spectroscopy

Mass Spectrometry

An Introduction to Organometallic Compounds

Aldehydes and Ketones

Carboxylic Acids

Functional Derivatives of Carboxylic Acids

Enolate Anions and Enamines

Dienes, Conjugated Systems, and Pericyclic Reactions

Benzene and the Concept of Aromaticity

Reactions of Benzene and Its Derivatives

Catalytic Carbon-Carbon Bond Formation

Carbohydrates

Lipids

Amino Acids and Proteins

Nucleic Acids

Organic Polymer Chemistry

Filters

Consider the following compounds. Answer the following questions by filling in the blank with the appropriate number from the diagram or an appropriate term. -The ammonia ion of substance ____ will have the largest pK_a.

Identify the type of reaction shown below.

The pK_a of methyl amine is represented by the following reaction. $\mathrm{CH}_{3} \mathrm{NH}_{3}^{+}+\mathrm{H}_{2} \mathrm{O}$ $\rightleftharpoons$ $\mathrm{CH}_{3} \mathrm{NH}_{3}+\mathrm{H}_{3} \mathrm{O}^{+}$

Consider the following compounds. Answer the following questions by filling in the blank with the appropriate number from the diagram or an appropriate term. -The ammonia ion of substance ____ will have the smallest pK_a.

The reaction of a 2^o amine with nitrous acid gives a nitrosamine.