Exam 11: Reactions of Alcohols

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Provide the major organic product of the following. Provide the major organic product of the following.

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Provide the major organic product of the reaction shown. Provide the major organic product of the reaction shown.

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What series of synthetic steps could be used to carry out the transformation shown below? What series of synthetic steps could be used to carry out the transformation shown below?

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Name the alcohol that would be used in the Fischer esterification synthesis of ethyl propanoate (CH3CH2O2CCH2CH3).

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Provide the structure of the major organic product in the reaction below. (CH3)2CHCH2OH Provide the structure of the major organic product in the reaction below. (CH<sub>3</sub>)<sub>2</sub>CHCH<sub>2</sub>OH

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Draw the tosylate ion and explain why it is a particularly good leaving group.

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What reagents are necessary for the following conversion? What reagents are necessary for the following conversion?

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Which of the following reagents is not typically viewed as an oxidizing agent?

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Provide the major organic product of the following. Provide the major organic product of the following.

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Provide the reagents necessary to carry out the multistep synthesis shown below. Provide the reagents necessary to carry out the multistep synthesis shown below.

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Provide the major organic product of the following reaction. Provide the major organic product of the following reaction.

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It is necessary to add ZnCl2 to promote the reaction of HCl with some alcohols while these same alcohols react with HBr quite readily. Explain.

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Poisonings by methanol and ethylene glycol are relatively common. How are these poisonings treated clinically?

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Provide the structure of the major organic product in the reaction below. Provide the structure of the major organic product in the reaction below.

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Provide the major organic product of the reaction shown. Provide the major organic product of the reaction shown.

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Provide the major organic product of the following. Provide the major organic product of the following.

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What compound results when 1-butanol is treated with P/I2?

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Given a sample of (R)-2,3-dimethylhexan-3-ol, which of the following would be the best synthesis of (R)-3-chloro-2,3-dimethylhexane?

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Provide the structure of the major organic product in the reaction below. Provide the structure of the major organic product in the reaction below.

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Circle all carbon centers that are at the same oxidation state as a carboxylic acid. Circle all carbon centers that are at the same oxidation state as a carboxylic acid.

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