Exam 7: Thermochemistry

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A mixture of 125 g of iron and 250 g of water is heated from 25.0°C to 70.0°C. How much heat is absorbed by the mixture? (Specific heat of water = 4.18 J/g °C; iron = 0.473 J/g °C)

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Two solutions, 50.0 mL of 1.00 M BaCl2(aq) and 50.0 mL of 1.00 M Na2SO4(aq), both initially at 21.5°C, are added to a calorimeter with a total heat capacity, after the solutions are added, of 1.10 kJ/°C and the temperature rises to 22.7°C. Determine qrxn per mole of BaSO4(s) formed in the reaction.

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Choose the INCORRECT statement.

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Calculate the enthalpy change for the following reaction at 25°C. The value of ΔH°f in kJ/mol is given below each species: Al3+ (aq) + 3 OH- (aq) → Al(OH)3(s) -531     -230.0      -1276

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How much work, in joules, is done when the pressure is suddenly released from 2.05 atm to 1.87 atm on 27.5 g of He at 27°C?

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A 12-inch diameter ball of pure cobalt metal at 225°C was placed in 10.0 gal. of water at 15.0°C. What is the final temperature of the water? Assume no heat is lost to the surroundings. (sp ht for cobalt is 0.421 J/g °C, density of cobalt = 8.862 g/cm3, 1 gal. = 3.785 L, 1 in = 2.54 cm, V(sphere) = 4/3 πr3)

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Compute ΔH°rxn for the following reaction. The value of ΔH°f in kJ/mol is given below each species: 2 CaO(s) + 2 SO2(g) + O2(g) → 2 CaSO4(s) -635.5   -296.9     0.0     -1432.7

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How much heat is needed to raise the temperature of 5.28 gal of water from 25.0°C to 88.0°C (1 gal = 3.785 L)?

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H2S(g) + H<sub>2</sub>S(g) +   O<sub>2</sub>(g) → H<sub>2</sub>O (liq) + SO<sub>2</sub>(g)       ΔH° = -562.3 kJ 1/8 S<sub>8</sub>(s) + O<sub>2</sub>(g) → SO(g)       ΔH° = -297.0 kJ H<sub>2</sub>(g) +   O<sub>2</sub> → H<sub>2</sub>O (liq) ΔH° = -266.9 kJ Compute ΔH° for H<sub>2</sub>(g) + 1/8 S8 (s) → H<sub>2</sub>S(g) in kJ. O2(g) → H2O (liq) + SO2(g)     ΔH° = -562.3 kJ 1/8 S8(s) + O2(g) → SO(g)     ΔH° = -297.0 kJ H2(g) + H<sub>2</sub>S(g) +   O<sub>2</sub>(g) → H<sub>2</sub>O (liq) + SO<sub>2</sub>(g)       ΔH° = -562.3 kJ 1/8 S<sub>8</sub>(s) + O<sub>2</sub>(g) → SO(g)       ΔH° = -297.0 kJ H<sub>2</sub>(g) +   O<sub>2</sub> → H<sub>2</sub>O (liq) ΔH° = -266.9 kJ Compute ΔH° for H<sub>2</sub>(g) + 1/8 S8 (s) → H<sub>2</sub>S(g) in kJ. O2 → H2O (liq) ΔH° = -266.9 kJ Compute ΔH° for H2(g) + 1/8 S8 (s) → H2S(g) in kJ.

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What is the heat of combustion in kJ/g of benzoic acid (HC7H5O2) if the initial temperature was 22.62°C, the final temperature was 31.10°C, the heat capacity of the bomb calorimeter was 4.88 kJ/°C, and 1.567 grams were combusted?

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Oxygen gas at 34.5°C is compressed from 45.7 L to 34.5 L against a constant pressure of 750 mmHg. What is the work done in joules by the system?

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Using the heat of combustion of methanol as -726.6 kJ and the following data: C(graph) + 1/2O2 → CO(g)  ΔH° = -110.5 kJ C(graph) + O2(g) → CO2(g) ΔH° = -393.5 kJ H2(g) + 1/2O2(g) → H2O(l)  ΔH° = -285.8 kJ Determine ΔH° for the following reaction: CO(g) + 2 H2(g) → CH3OH(l)

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What is the work done in joules by the system when H2 expands against a constant pressure of 75 atm at 45.3°C? The change in volume is 24.0 L.

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5.04 × 10-3 mole of a compound is added to 41.0 g of water in a styrofoam cup and stirred until it dissolves. The temperature of the solution changes from 23.460°C to 23.420°C. What is the heat of solution of the compound expressed in kJ/mol? Assume the specific heat of the solution is 4.18 J/g °C.

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Consider the reaction:     4 NH3(g) + 5 O2(g) → 4 NO2(g) + 6 H2O(l) ΔH°f -46.19     0.00     90.37     -285.85 kJ/mol Compute ΔH° for this reaction.

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1219 joules of heat raise the temperature of 250 g of metal by 64°C. What is the specific heat in J/(g °C? )

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Calculate ΔH°f of octane, C8H18(l), given the enthalpy of combustion of octane to CO2(g) and H2O(l), -5471 kJ/mol, and the standard enthalpies of formation of CO2(g) and H2O(l), -393.5 kJ/mol and -285.8 kJ/mol, respectively.

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How much heat is involved in the complete combustion of 2.50 kg propane, C3H8? ΔHcomb = -2219 kJ/mol.

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2 LiOH(s) → Li2O(s) + H2O(l) ΔH° = 379.1 kJ LiH(s) + H2O(l) → LiOH(s) + H2(g) ΔH° = -111.0 kJ 2 H2(g) + O2(g) → 2 H2O(l) ΔH° = -285.9 kJ Compute ΔH° in kJ for 2 LiH(s) + O2(g) → Li2O(s) + H2O(l)

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A system that absorbs heat is an exothermic system.

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