Exam 13: Solutions and Their Physical Properties

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Solutions are made that contain 0.1 moles of each of the following compounds below in 100 g of H2O. Choose the compound whose solution will have the lowest freezing point.

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A

Liquid Q is a polar solvent and liquid R is a nonpolar solvent. On the basis of this information, you would expect:

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D

What is the correct value for the weight of Na3PO4 needed to make 100 mL of a 0.50 molar solution?

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B

Which definition is INCORRECT?

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The stronger the forces between solute and solvent molecules, the more exothermic the solution process.

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Molality is independent of temperature, molarity is dependent on temperature.

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The vapor pressures of pure hexane and pure heptane at 25°C are 151.4 mmHg and 45.62 mmHg respectively. A solution contains 0.800 mol fraction n-hexane and 0.200 mol fraction n-heptane. What is the composition of the vapor in equilibrium with this solution at 25°C?

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252 mL of 3.00 M H2SO4 are added to 1.50 L of 0.500 M H2SO4. What is the concentration of the resulting solution?

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Exactly 375.0 mg of an unknown protein is dissolved in enough water to give 50.00 mL of solution and the osmotic pressure determined as 3.25 mmHg at 298 K. Estimate the molar mass of this protein.

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0.0800 g of a compound with the empirical formula C2H2N is dissolved in 10.00 g benzene. The resulting solution freezes at 4.99°C. Benzene freezes at 5.48°C and has a freezing point depression constant of Kf = 4.90°C/m. What is the molecular formula of the compound?

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Which of the following organic substances is most readily soluble in water? Which of the following organic substances is most readily soluble in water?

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Henry's Law states that:

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An isotonic solution will produce an osmotic pressure of 7.84 atm measured against pure water at human body temperature (37.0°C). How many grams of sodium chloride must be dissolved in a liter of water to produce an isotonic solution?

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A solution is called "ideal" when:

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Henry's Law constants for aqueous solutions at 25°C are 8.20 × 10-7 molal/mmHg for N2 and 1.62 × 10-6 molal/mmHg for O2. Determine the solubility of oxygen in water under an atmospheric pressure of 760 mmHg, assuming that air is 80% N2 and 20% O2.

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A solution containing 3.24 g of sulfur in 40 g of benzene boils 0.81°C above the boiling point of pure benzene. Determine the number of S atoms in one molecule of dissolved sulfur. Kb for benzene is 2.53°C m-1.

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Determine the osmotic pressure at 25 °C of an aqueous solution that is 0.028 M NaNO3.

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A solution composed of 5 moles of acetone (CH3COCH3, P°A = 324 mmHg) and 5 moles of chloroform (CHCl3, P°C = 274 mmHg) has a vapor pressure of 236 mmHg. Which one of the following statements is completely true about this solution?

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What is the osmotic pressure in mmHg of 6.00 L of a 0.108 M solution at 30°C if three moles of ions are produced in aqueous solution for every mole of solute dissolved?

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Which compound is most likely to be soluble in water?

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