Exam 7: Thermochemistry

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Many people believe that coffee (sp ht = 4.18 J/g °C) may be cooled by placing a silver spoon (sp ht = 0.237 J/g °C) in the coffee. If 250 ml (d = 1.00 g/mL) of coffee at 200°F had a spoon at 70°F placed in it, what would be the final Celsius temperature of the spoon and coffee, assuming that no heat is lost to the surroundings? The mass of the spoon is 35 g.

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Calculate the standard enthalpy of formation of Cl-(aq), given the following thermochemical data at 1 atm, and knowing that the standard enthalpies of formation of H2(g) and H+(aq) are both zero. HCl(g) → H+(aq) + Cl-(aq) -75.15 kJ H2(g) + Cl2(g) → 2HCl(g) -184.62 kJ

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The standard enthalpy of formation of NH4Cl(s) is -315.4 kJ/mol. The equation that describes this △H°f is:

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What is the reaction for the standard enthalpy of formation for HCl(g)?

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Kinetic energy is the energy of motion.

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Given the heat of formation of the following compounds: CO2(g)   ΔH°f = -393.5 kJ/mol H2O(l)    ΔH°f = -285.9 kJ/mol CH3OH(l)  ΔH°f = -238.6 kJ/mol What is the value of ΔH for the reaction: CH3OH(l) + 3/2 O2(g) → CO2(g) + 2 H2O(l)

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500 g of Al is heated to 100.0°C and dropped into a l00.0 g glass beaker that contains 200.0 g of H2O. The temperature of the glass and water is 20.0°C. What is the final temperature? (Specific heat of Al = 0.29 J/g °C, specific heat of glass = 0.84 J/g °C)

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Calculate the work needed to make room for products in the combustion of sulfur, S8(s), to SO2(g) at STP.

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What is the reaction for the standard enthalpy of formation for Mn2O3(s)? (Mn(s) is the stable form of manganese.)

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How much work, in joules, is done when the pressure is suddenly released from 4.56 atm to 1.23 atm on 45.4 g of O2 at 44°C?

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How much heat is required to raise the temperature of 175 g of aluminum from 21.0°C to 145°C? The specific heat of aluminum is 0.903 J g-1 °C-1.

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Determine the enthalpy change in the following equation: Cl2(g) + H2O(l) → 2 HCl(g) + 1/2 O2(g)    ΔH°f H2O(l) = -285.8 kJ/mol    ΔH°f HCl(g) = -92.31 kJ/mol

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Enthalpy is defined as:

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Consider the reaction: CO2(g) + 2HCl(g) → COCl2(g) + H2O(l)  ΔH°f -393.51  -92.30  -223.01  -285.85 kJ/mol Compute ΔH° for this reaction.

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The complete combustion of propane, C3H8(g), is represented by the equation: C3H8(g) + 5 O2(g) → 3 CO2(g) + 4 H2O(l)     ΔH° = -2220 kJ How much heat is evolved in the complete combustion of 12.5 L C3H8(g) at 25°C and 790 mmHg?

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Determine the enthalpy change in the following equation: 2/3 H2S(g) + O2(g) → 2/3 SO2(g) + 2/3 H2O(l)    ΔH°f H2O(l) = -285.8 kJ/mol    ΔH°f H2S(g) = -20.63 kJ/mol    ΔH°f SO2(g) = -296.8 kJ/mol

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Given the following thermochemical equations: (kJ) 4 FeS2(s) + 11O2(g) → 2 Fe2O3(s) + 8 SO2(g) ΔH° = -3307.9 2 H2S(g) + 3O2(g) → 2 H2O(l) + 2 SO2(g) - 1125.2 4 FeO(s) + O2(g) → 2 Fe2O3(s) - 578.2 2 Fe(s) + O2(g) → 2 FeO(s) - 544 H2(g) + S(rh) → H2S(g) - 20.2 2 H2(g) + O2(g) → 2 H2O(l) - 571.7 Compute the ΔH°f for FeS2(s) in kJ/mol.

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The enthalpy of a system is the internal energy minus work

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100.0 g of nickel at 150 °C was placed in 1.00 L of water at 25.0°C. The final temperature of the nickel-water mixture was 26.3°C. What is the specific heat of the nickel?

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The standard enthalpy for diamond and graphite are the same value.

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