Exam 7: Thermochemistry
Exam 1: Matter - Its Properties and Measurement94 Questions
Exam 2: Atoms and the Atomic Theory100 Questions
Exam 3: Chemical Compounds100 Questions
Exam 4: Chemical Reactions100 Questions
Exam 5: Introduction to Reactions in Aqueous Solutions97 Questions
Exam 6: Gases100 Questions
Exam 7: Thermochemistry101 Questions
Exam 8: Electrons in Atoms100 Questions
Exam 9: The Periodic Table and Some Atomic Properties96 Questions
Exam 10: Chemical Bonding I: Basic Concepts97 Questions
Exam 11: Chemical Bonding II: Additional Aspects97 Questions
Exam 12: Intermolecular Forces: Liquids and Solids102 Questions
Exam 13: Solutions and Their Physical Properties100 Questions
Exam 14: Chemical Kinetics92 Questions
Exam 15: Principles of Chemical Equilibrium99 Questions
Exam 16: Acids and Bases100 Questions
Exam 17: Additional Aspects of Acid-Base Equilibria99 Questions
Exam 18: Solubility and Complex-Ion Equilibria95 Questions
Exam 19: Spontaneous Change: Entropy and Free Energy101 Questions
Exam 20: Electrochemistry103 Questions
Exam 21: Main Group Elements I: Groups 1, 2, 13, and 14116 Questions
Exam 22: Main Group Elements II: Groups 18, 17, 16, 15, and Hydrogen100 Questions
Exam 23: The Transition Elements102 Questions
Exam 24: Complex Ions and Coordination Compounds100 Questions
Exam 25: Nuclear Chemistry 1-41100 Questions
Exam 26: Structures of Organic Compounds96 Questions
Exam 27: Reactions of Organic Compounds94 Questions
Exam 28: Chemistry of the Living State99 Questions
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Many people believe that coffee (sp ht = 4.18 J/g °C) may be cooled by placing a silver spoon (sp ht = 0.237 J/g °C) in the coffee. If 250 ml (d = 1.00 g/mL) of coffee at 200°F had a spoon at 70°F placed in it, what would be the final Celsius temperature of the spoon and coffee, assuming that no heat is lost to the surroundings? The mass of the spoon is 35 g.
(Multiple Choice)
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Calculate the standard enthalpy of formation of Cl-(aq), given the following thermochemical data at 1 atm, and knowing that the standard enthalpies of formation of H2(g) and H+(aq) are both zero. HCl(g) → H+(aq) + Cl-(aq) -75.15 kJ
H2(g) + Cl2(g) → 2HCl(g) -184.62 kJ
(Multiple Choice)
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The standard enthalpy of formation of NH4Cl(s) is -315.4 kJ/mol. The equation that describes this △H°f is:
(Multiple Choice)
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What is the reaction for the standard enthalpy of formation for HCl(g)?
(Multiple Choice)
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Given the heat of formation of the following compounds:
CO2(g) ΔH°f = -393.5 kJ/mol
H2O(l) ΔH°f = -285.9 kJ/mol
CH3OH(l) ΔH°f = -238.6 kJ/mol
What is the value of ΔH for the reaction:
CH3OH(l) + 3/2 O2(g) → CO2(g) + 2 H2O(l)
(Multiple Choice)
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500 g of Al is heated to 100.0°C and dropped into a l00.0 g glass beaker that contains 200.0 g of H2O. The temperature of the glass and water is 20.0°C. What is the final temperature? (Specific heat of Al = 0.29 J/g °C, specific heat of glass = 0.84 J/g °C)
(Multiple Choice)
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Calculate the work needed to make room for products in the combustion of sulfur, S8(s), to SO2(g) at STP.
(Multiple Choice)
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What is the reaction for the standard enthalpy of formation for Mn2O3(s)? (Mn(s) is the stable form of manganese.)
(Multiple Choice)
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How much work, in joules, is done when the pressure is suddenly released from 4.56 atm to 1.23 atm on 45.4 g of O2 at 44°C?
(Multiple Choice)
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How much heat is required to raise the temperature of 175 g of aluminum from 21.0°C to 145°C? The specific heat of aluminum is 0.903 J g-1 °C-1.
(Multiple Choice)
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Determine the enthalpy change in the following equation:
Cl2(g) + H2O(l) → 2 HCl(g) + 1/2 O2(g)
ΔH°f H2O(l) = -285.8 kJ/mol
ΔH°f HCl(g) = -92.31 kJ/mol
(Multiple Choice)
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Consider the reaction:
CO2(g) + 2HCl(g) → COCl2(g) + H2O(l) ΔH°f -393.51 -92.30 -223.01 -285.85 kJ/mol
Compute ΔH° for this reaction.
(Multiple Choice)
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The complete combustion of propane, C3H8(g), is represented by the equation: C3H8(g) + 5 O2(g) → 3 CO2(g) + 4 H2O(l) ΔH° = -2220 kJ
How much heat is evolved in the complete combustion of 12.5 L C3H8(g) at 25°C and 790 mmHg?
(Multiple Choice)
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Determine the enthalpy change in the following equation:
2/3 H2S(g) + O2(g) → 2/3 SO2(g) + 2/3 H2O(l)
ΔH°f H2O(l) = -285.8 kJ/mol
ΔH°f H2S(g) = -20.63 kJ/mol
ΔH°f SO2(g) = -296.8 kJ/mol
(Multiple Choice)
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Given the following thermochemical equations: (kJ)
4 FeS2(s) + 11O2(g) → 2 Fe2O3(s) + 8 SO2(g) ΔH° = -3307.9
2 H2S(g) + 3O2(g) → 2 H2O(l) + 2 SO2(g) - 1125.2
4 FeO(s) + O2(g) → 2 Fe2O3(s) - 578.2
2 Fe(s) + O2(g) → 2 FeO(s) - 544
H2(g) + S(rh) → H2S(g) - 20.2
2 H2(g) + O2(g) → 2 H2O(l) - 571.7
Compute the ΔH°f for FeS2(s) in kJ/mol.
(Multiple Choice)
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100.0 g of nickel at 150 °C was placed in 1.00 L of water at 25.0°C. The final temperature of the nickel-water mixture was 26.3°C. What is the specific heat of the nickel?
(Multiple Choice)
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The standard enthalpy for diamond and graphite are the same value.
(True/False)
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