Exam 14: Chemical Kinetics

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The rate data from a chemical reaction shows that doubling the concentration of A with the concentration of B remaining constant causes the rate to increase by a factor of four. What is the reaction order for [A]?

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Substance A decomposes by a first-order reaction. Starting initially with [A] = 2.00 M, after 150 min [A] = 0.50 M. For this reaction what is t1/2?

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In the Arrhenius equation, ln k = -Ea/RT + ln A, the symbol A denotes the initial concentration of A.

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For the reaction: C2H4Br2 + 3KI → C2H4 + 2KBr + KI3 Initial rate data at 60°C are: For the reaction: C<sub>2</sub>H<sub>4</sub>Br<sub>2</sub> + 3KI → C<sub>2</sub>H<sub>4</sub> + 2KBr + KI<sub>3</sub> Initial rate data at 60°C are:   The rate law is ________. The rate law is ________.

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For the second order reaction A → products, the following data are obtained: [A] = 3.024 M, t = 0 min [A] = 2.935 M, t = 1.0 min [A] = 2.852 M, t = 2.0 min What is the rate constant, k?

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Given the following initial rate data, calculate the specific rate constant. Given the following initial rate data, calculate the specific rate constant.

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Given the following initial rate data, write the rate law expression.Given the following initial rate data, write the rate law expression.

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For the second-order reaction A → products, the following data are obtained: [A] = 1.512 M, t = 0 min [A] = 1.490 M, t = 1.0 min [A] = 1.469 M, t = 2.0 min What is the initial rate of the reaction in the experiment?

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The rate constant for a first-order reaction is k = 0.00073 s-1. Determine the percent of reactant that has decomposed after 500 s.

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For the second-order reaction A → products, the following data are obtained: [A] = 3.024 M, t = 0 min [A] = 2.935 M, t = 1.0 min [A] = 2.852 M, t = 2.0 min What is the initial rate of the reaction?

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A heterogeneous catalyst is a catalyst that is in two phases of matter.

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For the reaction: 2N2O5(g) → 4NO2(g) + O2(g) the rate law is: For the reaction: 2N<sub>2</sub>O<sub>5</sub>(g) → 4NO<sub>2</sub>(g) + O<sub>2</sub>(g) the rate law is:   = k[N<sub>2</sub>O<sub>5</sub>] At 300 K, the half-life is 2.50 × 10<sup>4</sup> seconds and the activation energy is 103.3 kJ/mol. What is the rate constant at 350 K? = k[N2O5] At 300 K, the half-life is 2.50 × 104 seconds and the activation energy is 103.3 kJ/mol. What is the rate constant at 350 K?

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