Exam 13: Aqueous Equilibria

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The following compounds are available as 0.10 M aqueous solutions. The following compounds are available as 0.10 M aqueous solutions.   Pick two solutions that could be used to prepare a buffer with a pH of ~ 10.8.More than one answer may be possible. Pick two solutions that could be used to prepare a buffer with a pH of ~ 10.8.More than one answer may be possible.

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A buffer solution contains 0.0200 M acetic acid and 0.0200 M sodium acetate.What is the pH after 2.0 mmol of HCl is added to 1.00 L of this buffer? pKa = 4.75 for acetic acid.

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If you wish to increase the solubility of silver benzoate,a preservative,you would

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The solubility of silver bromide is greater in 0.10 M NaBr than in pure water.

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The Cu2+ ion can be separated from Ag+,Ca2+,and K+ in aqueous solution by

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Which of the following mixtures gives a buffer with a pH greater than 7.0? For HCNO,Ka = 2.2 * 10-4 and for NH3,Kb = 1.8 * 10-5.

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Consider the titration of 50.0 mL of 0.0200 M C6H5COOH(aq),with 0.100 M NaOH(aq).What is the formula of the main species in the solution after the addition of 10.0 mL of base? Do not consider spectator ions.

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What is the pH of an aqueous solution that is 0.20 M HNO2 (Ka = 4.3 * 10-4)and 0.20 M NaNO2?

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What is the main factor that directly determines the pH of any buffer?

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Calculate the equilibrium constant for the reaction that occurs when sodium hydroxide is added to the buffer B(aq)/BHCl(aq).The Kb of B is 1.5 * 10-5.

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What is the pH of an aqueous solution that is 0.011 M HF (Ka = 3.5 * 10-4)and 0.015 M NaF?

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What is the pH at the stoichiometric point for the titration of 0.100 M CH3COOH(aq)with 0.100 M KOH(aq)? The value of Ka for acetic acid is 1.8 * 10-5.

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A certain weak acid has a Ka of 2.0 * 10-5.What is the equilibrium constant for the reaction of this acid with a strong base?

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Consider the titration of 15.0 mL of 0.200 M H3PO4(aq)with 0.200 M NaOH(aq).What is(are)the major species in solution after the addition of 30.0 mL of base?

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What is the relationship between the solubility in water,s,and Ksp for the ionic solid Ca3(PO4)2?

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If 50.0 mL of 0.22 M NaCl(aq)is mixed with 50.0 mL of 0.0050 M AgNO3(aq),will AgCl(s)precipitate? Ksp(AgCl)= 1.6 × 10-10.

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When sodium nitrite is added to HNO2(aq),

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A buffer contains equal concentrations of NH3(aq)and NH4Cl(aq).What is the pH of the buffer? (Kb (NH3)= 1.8 * 10-5)

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The following compounds are available as 0.10 M aqueous solutions. The following compounds are available as 0.10 M aqueous solutions.   Which two solutions could be used to prepare a buffer with a pH of ~ 9? More than one answer may be possible. Which two solutions could be used to prepare a buffer with a pH of ~ 9? More than one answer may be possible.

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In the titration of 0.300 M H3PO4(aq)with 0.300 M NaOH(aq),the first stoichiometric point occurs at pH < 7 whereas in the titration of 0.300 M HCOOH(aq)with 0.300 M NaOH(aq)the stoichiometric point occurs at pH > 7.Explain.

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