Exam 11: Chemical Equilibria

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Calculate the standard free energy of formation of chloroform,CHCl3(l),at 25°C.The standard free energy of formation of CHCl3(g)is -70.12 kJ.mol-1 and the vapor pressure of chloroform at 25°C is 0.499 atm.

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-71.84 kJ.mol-1

Consider the reaction CuSO4(s) →\rightarrow CuO(s)+ SO3(g) If Δ\Delta G ∘\circ = -14.6 kJ at 950 ∘\circ C for this reaction,what is Δ\Delta G for an SO3(g)pressure of 20 bar at this temperature.

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A

Given: 4NH3(g)+ 5O2(g) → 4NO(g)+ 6H2O(g) K Calculate the equilibrium constant for the following reaction. 2NH3(g)+ Given: 4NH<sub>3</sub>(g)+ 5O<sub>2</sub>(g) → 4NO(g)+ 6H<sub>2</sub>O(g) K Calculate the equilibrium constant for the following reaction. 2NH<sub>3</sub>(g)+   O<sub>2</sub>(g) →2NO(g)+ 3H<sub>2</sub>O(g) O2(g) →2NO(g)+ 3H2O(g)

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E

Calculate Δ\Delta G at 298 K for the reaction C2H5OH(l) →\rightarrow C2H5OH(g,0.0400 bar) Given Δ\Delta G ∘\circ = 6.2 kJ at 298 K.

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For the reaction N2O4(g) →2NO2(g) Which of the following disturbances will cause an increase in NO2(g)concentration?

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The equilibrium constant K for the dissociation of N2O4(g)to NO2(g)is 1700 at 500 K.Predict its value at 300 K.For this reaction, Δ\Delta H ∘\circ is 56.8 kJ.mol-1.

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Consider the reaction 2SO2(g)+ O2(g) ↔\leftrightarrow 2SO3(g) At equilibrium at a certain temperature,the partial pressures of SO2(g),O2(g),and SO3(g)are 0.0012,0.18,and 2.2 bar,respectively.Argon is introduced into the reaction vessel until the partial pressure of argon is 5.0 bar.Predict the final partial pressures of the reactants and products.

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At 25 ∘\circ C,Kc = 4.1 * 108 for the reaction N2(g)+ 3H2(g) →2NH3(g) Calculate K at 25 ∘\circ C for this reaction.

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Consider the reaction 3Fe(s)+ 4H2O(g) → 4H2(g)+ Fe3O4(s) If the volume of the container is reduced,

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If the equilibrium constant for the reaction Ni(s)+ 4CO(g) →Ni(CO)4(g)is 2.72 at a certain temperature,what is the equilibrium constant for the following reaction at the same temperature? Ni(CO)4(g) → Ni(s)+ 4CO(g)

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Given: 2SO2(g)+ O2(g) →2SO3(g) At equilibrium at a certain temperature,the concentrations of SO3(g),SO2(g),and O2(g)are 0.12 M,0.86 M,and 0.33 M,respectively.Calculate the value of Kc for this reaction.

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For the reaction NH3(g)+ H2S(g) →NH4HS(s) Kc = 9.7 at 900 K.If the initial concentrations of NH3(g)and H2S(g)are 2.0 M,what is the equilibrium concentration of H2S(g)?

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If Δ\Delta G ∘\circ = 27.1 kJ at 25 ∘\circ C for the reaction CH3COOH(aq)+ H2O(l) → CH3COO-(aq)+ H3O+(aq) What is Ka for this reaction at 298 K?

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Consider the reaction CO2(g)+ C(s)→ 2CO(g) At equilibrium,at a certain temperature,the partial pressures of CO2(g)and CO(g)are 23.5 and 8.21 atm,respectively.Calculate the value of KP.

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Consider the reaction NO(g)+  Consider the reaction NO(g)+   O<sub>2</sub>(g) \rightarrow  NO<sub>2</sub>(g) If  \Delta H<sup> \circ </sup> = -56.52 kJ and  \Delta S<sup> \circ </sup> = -72.60 J.K<sup>-1</sup> at 298 K,what is the equilibrium constant for the reaction at 298 K? O2(g) →\rightarrow NO2(g) If Δ\Delta H ∘\circ = -56.52 kJ and Δ\Delta S ∘\circ = -72.60 J.K-1 at 298 K,what is the equilibrium constant for the reaction at 298 K?

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Given: P4(s)+ 6Cl2(g)b 4PCl3(l) K Calculate the equilibrium constant for the following reaction. 2PCl3(l) →3Cl2(g)+ Given: P<sub>4</sub>(s)+ 6Cl<sub>2</sub>(g)b 4PCl<sub>3</sub>(l) K Calculate the equilibrium constant for the following reaction. 2PCl<sub>3</sub>(l) →3Cl<sub>2</sub>(g)+   P<sub>4</sub>(s) P4(s)

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What is the relation between K and Kc for the reaction H2(g)+ I2(g) →2HI(g)

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At 25 ∘\circ C, Δ\Delta Gro for the reaction 2SO2(g)+ O2(g) ?2SO3(g)is -141.74 kJ·mol-1.Calculate the value of Kc for this reaction.

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Calculate the value of K at 700 K for the reaction H2(g)+ I2(g) → 2HI(g) Given that Kc = 54 at the same temperature.

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What is the relationship between K and Kc for the reaction below? N2(g)+ 3H2(g) →2NH3(g)

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