Exam 11: Chemical Equilibria
Exam 1: The Quantum World100 Questions
Exam 2: Quantum Mechanics in Action: Atoms100 Questions
Exam 3: Chemical Bonds83 Questions
Exam 4: Molecular Shape and Structure95 Questions
Exam 5: The Properties of Gases94 Questions
Exam 6: Liquids and Solids95 Questions
Exam 7: Inorganic Materials100 Questions
Exam 8: Thermodynamics: The First Law94 Questions
Exam 9: Thermodynamics: The Second and Third Laws95 Questions
Exam 10: Physical Equilibria94 Questions
Exam 11: Chemical Equilibria94 Questions
Exam 12: Acids and Bases94 Questions
Exam 13: Aqueous Equilibria94 Questions
Exam 14: Electrochemistry94 Questions
Exam 15: Chemical Kinetics93 Questions
Exam 16: The Elements: the Main Group Elements189 Questions
Exam 17: The Elements: The D Block94 Questions
Exam 18: Nuclear Chemistry95 Questions
Exam 19: Organic Chemistry I94 Questions
Exam 20: Organic Chemistry II95 Questions
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Calculate the standard free energy of formation of chloroform,CHCl3(l),at 25°C.The standard free energy of formation of CHCl3(g)is -70.12 kJ.mol-1 and the vapor pressure of chloroform at 25°C is 0.499 atm.
Free
(Short Answer)
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Correct Answer:
-71.84 kJ.mol-1
Consider the reaction
CuSO4(s) CuO(s)+ SO3(g)
If G = -14.6 kJ at 950 C for this reaction,what is G for an SO3(g)pressure of 20 bar at this temperature.
Free
(Multiple Choice)
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Correct Answer:
A
Given: 4NH3(g)+ 5O2(g) → 4NO(g)+ 6H2O(g)
K
Calculate the equilibrium constant for the following reaction.
2NH3(g)+
O2(g) →2NO(g)+ 3H2O(g)
Free
(Multiple Choice)
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Correct Answer:
E
Calculate G at 298 K for the reaction C2H5OH(l) C2H5OH(g,0.0400 bar)
Given G = 6.2 kJ at 298 K.
(Multiple Choice)
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For the reaction N2O4(g) →2NO2(g)
Which of the following disturbances will cause an increase in NO2(g)concentration?
(Multiple Choice)
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The equilibrium constant K for the dissociation of N2O4(g)to NO2(g)is 1700 at 500 K.Predict its value at 300 K.For this reaction, H is 56.8 kJ.mol-1.
(Multiple Choice)
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Consider the reaction
2SO2(g)+ O2(g) 2SO3(g)
At equilibrium at a certain temperature,the partial pressures of SO2(g),O2(g),and SO3(g)are 0.0012,0.18,and 2.2 bar,respectively.Argon is introduced into the reaction vessel until the partial pressure of argon is 5.0 bar.Predict the final partial pressures of the reactants and products.
(Short Answer)
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At 25 C,Kc = 4.1 * 108 for the reaction N2(g)+ 3H2(g) →2NH3(g)
Calculate K at 25 C for this reaction.
(Multiple Choice)
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Consider the reaction 3Fe(s)+ 4H2O(g) → 4H2(g)+ Fe3O4(s)
If the volume of the container is reduced,
(Multiple Choice)
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If the equilibrium constant for the reaction Ni(s)+ 4CO(g) →Ni(CO)4(g)is 2.72 at a certain temperature,what is the equilibrium constant for the following reaction at the same temperature?
Ni(CO)4(g) → Ni(s)+ 4CO(g)
(Short Answer)
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Given: 2SO2(g)+ O2(g) →2SO3(g) At equilibrium at a certain temperature,the concentrations of SO3(g),SO2(g),and O2(g)are 0.12 M,0.86 M,and 0.33 M,respectively.Calculate the value of Kc for this reaction.
(Multiple Choice)
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For the reaction NH3(g)+ H2S(g) →NH4HS(s)
Kc = 9.7 at 900 K.If the initial concentrations of NH3(g)and H2S(g)are 2.0 M,what is the equilibrium concentration of H2S(g)?
(Multiple Choice)
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If G = 27.1 kJ at 25 C for the reaction CH3COOH(aq)+ H2O(l) → CH3COO-(aq)+ H3O+(aq)
What is Ka for this reaction at 298 K?
(Multiple Choice)
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Consider the reaction
CO2(g)+ C(s)→ 2CO(g)
At equilibrium,at a certain temperature,the partial pressures of CO2(g)and CO(g)are 23.5 and 8.21 atm,respectively.Calculate the value of KP.
(Short Answer)
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Consider the reaction NO(g)+
O2(g) NO2(g)
If H = -56.52 kJ and S = -72.60 J.K-1 at 298 K,what is the equilibrium constant for the reaction at 298 K?
(Multiple Choice)
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Given: P4(s)+ 6Cl2(g)b 4PCl3(l)
K
Calculate the equilibrium constant for the following reaction.
2PCl3(l) →3Cl2(g)+
P4(s)
(Multiple Choice)
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What is the relation between K and Kc for the reaction H2(g)+ I2(g) →2HI(g)
(Multiple Choice)
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At 25 C, Gro for the reaction 2SO2(g)+ O2(g) ?2SO3(g)is -141.74 kJ·mol-1.Calculate the value of Kc for this reaction.
(Multiple Choice)
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Calculate the value of K at 700 K for the reaction H2(g)+ I2(g) → 2HI(g)
Given that Kc = 54 at the same temperature.
(Multiple Choice)
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What is the relationship between K and Kc for the reaction below?
N2(g)+ 3H2(g) →2NH3(g)
(Multiple Choice)
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