Exam 11: Chemical Equilibria
Exam 1: The Quantum World100 Questions
Exam 2: Quantum Mechanics in Action: Atoms100 Questions
Exam 3: Chemical Bonds83 Questions
Exam 4: Molecular Shape and Structure95 Questions
Exam 5: The Properties of Gases94 Questions
Exam 6: Liquids and Solids95 Questions
Exam 7: Inorganic Materials100 Questions
Exam 8: Thermodynamics: The First Law94 Questions
Exam 9: Thermodynamics: The Second and Third Laws95 Questions
Exam 10: Physical Equilibria94 Questions
Exam 11: Chemical Equilibria94 Questions
Exam 12: Acids and Bases94 Questions
Exam 13: Aqueous Equilibria94 Questions
Exam 14: Electrochemistry94 Questions
Exam 15: Chemical Kinetics93 Questions
Exam 16: The Elements: the Main Group Elements189 Questions
Exam 17: The Elements: The D Block94 Questions
Exam 18: Nuclear Chemistry95 Questions
Exam 19: Organic Chemistry I94 Questions
Exam 20: Organic Chemistry II95 Questions
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For the reaction 2NOCl(g) → 2NO(g)+ Cl2(g),K = 98 at a certain temperature.If the equilibrium concentrations in a 1 L container are [NOCl(g)] = 1.0 M,[NO(g)] = 3.5 M and [Cl2(g)] = 8.0 M,and 2.0 mol of each gas is added,in which direction does the reaction shift?
(Short Answer)
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Calculate the vapor pressure of ethyl alcohol,C2H5OH(l),at 298 K.The standard free energies of formation of C2H5OH(l)and C2H5OH(g)are -174.8 and -168.6 kJ.mol-1,respectively.
(Multiple Choice)
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Which of the following reactions is not affected by an increase in pressure?
(Multiple Choice)
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Consider the following reaction: Ni(CO)4(g) → Ni(s)+ 4CO(g)
If the initial concentration of Ni(CO)4(g)is 1.0 M,and x is the equilibrium concentration of CO(g),what is the correct equilibrium relation?
(Multiple Choice)
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Consider the reaction PCl5(g) →PCl3(g)+ Cl2(g)
At a certain temperature,if the initial concentration of PCl5(g)is 2.0 M,at equilibrium the concentration of Cl2(g)is 0.30 M.Calculate the value of Kc at this temperature.
(Multiple Choice)
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Consider the following reaction at a certain temperature:
PCl5(g) →PCl3(g)+ Cl2(g)
Kc = 0.100
At equilibrium,[PCl5] = 2.00 M and [PCl3] = [Cl2] = 1.00 M.If suddenly 1.00 M PCl5(g),PCl3(g),and Cl2(g)is added,what is the equilibrium concentration of PCl5(g)?
(Multiple Choice)
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The equilibrium constant for the reaction
HNO2(aq)+ H2O(l) →NO2 (aq)+ H3O+(aq)
is 4.3 * 10-4 at 25 C.Will nitrous acid spontaneously dissociate when
[HNO2(aq)] = 1.0 M and [NO2-(aq)] = [H3O+(aq)] = 1.0 * 10-5 M?
Show your calculations.
(Short Answer)
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Given: 2SO2(g)+ O2(g) →2SO3(g) At equilibrium at a certain temperature,the concentrations of SO3(g),SO2(g),and O2(g)are 0.24 M,0.82 M,and 0.33 M,respectively.Calculate the value of Kc for this reaction.
(Multiple Choice)
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Consider the reaction
CuSO4(s) CuO(s)+ SO3(g)
If G = -14.6 kJ at 950 C for this reaction,what is G for an SO3(g)pressure of 50 bar at this temperature?
(Multiple Choice)
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Consider the reaction PCl5(g) →PCl3(g)+ Cl2(g)
At a certain temperature,if the initial concentration of PCl5(g)is 3.0 M,at equilibrium the concentration of Cl2(g)is 0.80 M.Calculate the value of Kc at this temperature.
(Multiple Choice)
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Consider the following reaction at a certain temperature:
Ni(s)+ 4CO(g) →Ni(CO)4(g)
Calculate K for this reaction if,at equilibrium,the partial pressures of CO(g)and Ni(CO)4(g)are 1.25 and 6.65 atm over 1.00 kg of nickel.
(Short Answer)
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If a 1-L flask containing D2(g),N2(g),and ND3(g)at equilibrium at 300 K and a 1-L flask of H2(g),N2(g),and NH3(g)at equilibrium at 300 K are mixed,analysis of the reaction mixture shows that HD(g),NHD2(g),and NH2D(g)are also present.What conclusion(s)can be drawn?
(Short Answer)
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Consider the reaction CO(g)+ 2H2(g) →CH3OH(g)
At room temperature,K is approximately 2 * 104,but at a higher temperature K is substantially smaller.Which of the following is true?
(Multiple Choice)
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Given: SO2(g) →O2(g)+ S(s)
Kc = 2.5 * 10-53
SO3(g) →
O2(g)+ SO2(g)
Kc = 4.0 * 10-13
Calculate Kc for the reaction
2S(s)+ 3O2(g) →2SO3(g)
(Multiple Choice)
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Consider the following
N2O4(g) →2NO2(g)
The equilibrium constant for this reaction will decrease with an increase in temperature.
(True/False)
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Consider the reaction 2Fe2O3(s)+ 3C(s) 4Fe(s)+ 3CO2(g), H = 462 kJ, S = 558 J.K-1
Calculate the equilibrium constant for this reaction at 525 C.
(Multiple Choice)
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If Gro = 27.1 kJ∙mol-1 at 25 C for the dissociation of acetic acid in aqueous solution,what is K for the reaction
CH3COO-(aq)+ H3O+(aq) → CH3COOH(aq)+ H2O(l)
(Short Answer)
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The equilibrium constant expression for the reaction
CuSO4(s) → CuO(s)+ SO3(g)
is K = [CuO(s)][SO3(g)]/[CuSO4(s)].
(True/False)
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For the reaction NH3(g)+ H2S(g) →NH4HS(s)
Kc = 9.7 at 900 K.If the initial concentrations of NH3(g)and H2S(g)are 2.0 M,what is the equilibrium concentration of NH3(g)?
(Multiple Choice)
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At 25 C,Kc = 1.58 * 10-8 for the reaction NH4(NH2CO2)(s)b 2NH3(g)+ CO2(g)
Calculate K at 25 C for this reaction.
(Multiple Choice)
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