Exam 11: Chemical Equilibria

arrow
  • Select Tags
search iconSearch Question
  • Select Tags

For the reaction 2NOCl(g) → 2NO(g)+ Cl2(g),K = 98 at a certain temperature.If the equilibrium concentrations in a 1 L container are [NOCl(g)] = 1.0 M,[NO(g)] = 3.5 M and [Cl2(g)] = 8.0 M,and 2.0 mol of each gas is added,in which direction does the reaction shift?

(Short Answer)
4.9/5
(78)

Calculate the vapor pressure of ethyl alcohol,C2H5OH(l),at 298 K.The standard free energies of formation of C2H5OH(l)and C2H5OH(g)are -174.8 and -168.6 kJ.mol-1,respectively.

(Multiple Choice)
4.9/5
(75)

Which of the following reactions is not affected by an increase in pressure?

(Multiple Choice)
4.7/5
(84)

Consider the following reaction: Ni(CO)4(g) → Ni(s)+ 4CO(g) If the initial concentration of Ni(CO)4(g)is 1.0 M,and x is the equilibrium concentration of CO(g),what is the correct equilibrium relation?

(Multiple Choice)
4.8/5
(85)

Consider the reaction PCl5(g) →PCl3(g)+ Cl2(g) At a certain temperature,if the initial concentration of PCl5(g)is 2.0 M,at equilibrium the concentration of Cl2(g)is 0.30 M.Calculate the value of Kc at this temperature.

(Multiple Choice)
4.8/5
(92)

Consider the following reaction at a certain temperature: PCl5(g) →PCl3(g)+ Cl2(g) Kc = 0.100 At equilibrium,[PCl5] = 2.00 M and [PCl3] = [Cl2] = 1.00 M.If suddenly 1.00 M PCl5(g),PCl3(g),and Cl2(g)is added,what is the equilibrium concentration of PCl5(g)?

(Multiple Choice)
4.8/5
(84)

The equilibrium constant for the reaction HNO2(aq)+ H2O(l) →NO2 →\rightarrow (aq)+ H3O+(aq) is 4.3 * 10-4 at 25 ∘\circ C.Will nitrous acid spontaneously dissociate when [HNO2(aq)] = 1.0 M and [NO2-(aq)] = [H3O+(aq)] = 1.0 * 10-5 M? Show your calculations.

(Short Answer)
4.8/5
(77)

Given: 2SO2(g)+ O2(g) →2SO3(g) At equilibrium at a certain temperature,the concentrations of SO3(g),SO2(g),and O2(g)are 0.24 M,0.82 M,and 0.33 M,respectively.Calculate the value of Kc for this reaction.

(Multiple Choice)
4.9/5
(86)

Consider the reaction CuSO4(s) →\rightarrow CuO(s)+ SO3(g) If Δ\Delta G ∘\circ = -14.6 kJ at 950 ∘\circ C for this reaction,what is Δ\Delta G for an SO3(g)pressure of 50 bar at this temperature?

(Multiple Choice)
4.8/5
(81)

Consider the reaction PCl5(g) →PCl3(g)+ Cl2(g) At a certain temperature,if the initial concentration of PCl5(g)is 3.0 M,at equilibrium the concentration of Cl2(g)is 0.80 M.Calculate the value of Kc at this temperature.

(Multiple Choice)
4.9/5
(77)

Consider the following reaction at a certain temperature: Ni(s)+ 4CO(g) →Ni(CO)4(g) Calculate K for this reaction if,at equilibrium,the partial pressures of CO(g)and Ni(CO)4(g)are 1.25 and 6.65 atm over 1.00 kg of nickel.

(Short Answer)
4.9/5
(78)

If a 1-L flask containing D2(g),N2(g),and ND3(g)at equilibrium at 300 K and a 1-L flask of H2(g),N2(g),and NH3(g)at equilibrium at 300 K are mixed,analysis of the reaction mixture shows that HD(g),NHD2(g),and NH2D(g)are also present.What conclusion(s)can be drawn?

(Short Answer)
4.8/5
(81)

Consider the reaction CO(g)+ 2H2(g) →CH3OH(g) At room temperature,K is approximately 2 * 104,but at a higher temperature K is substantially smaller.Which of the following is true?

(Multiple Choice)
4.8/5
(92)

Given: SO2(g) →O2(g)+ S(s) Kc = 2.5 * 10-53 SO3(g) →Given: SO<sub>2</sub>(g) →O<sub>2</sub>(g)+ S(s) K<sub>c</sub> = 2.5 * 10<sup>-53</sup> SO<sub>3</sub>(g) →  O<sub>2</sub>(g)+ SO<sub>2</sub>(g) K<sub>c</sub> = 4.0 * 10<sup>-13</sup> Calculate K<sub>c</sub> for the reaction 2S(s)+ 3O<sub>2</sub>(g) →2SO<sub>3</sub>(g) O2(g)+ SO2(g) Kc = 4.0 * 10-13 Calculate Kc for the reaction 2S(s)+ 3O2(g) →2SO3(g)

(Multiple Choice)
4.9/5
(70)

Consider the following N2O4(g) →2NO2(g) The equilibrium constant for this reaction will decrease with an increase in temperature.

(True/False)
4.9/5
(73)

Consider the reaction 2Fe2O3(s)+ 3C(s) →\rightarrow 4Fe(s)+ 3CO2(g), Δ\Delta H ∘\circ = 462 kJ, Δ\Delta S ∘\circ = 558 J.K-1 Calculate the equilibrium constant for this reaction at 525 ∘\circ C.

(Multiple Choice)
4.9/5
(67)

If Δ\Delta Gro = 27.1 kJ∙mol-1 at 25 ∘\circ C for the dissociation of acetic acid in aqueous solution,what is K for the reaction CH3COO-(aq)+ H3O+(aq) → CH3COOH(aq)+ H2O(l)

(Short Answer)
4.9/5
(76)

The equilibrium constant expression for the reaction CuSO4(s) → CuO(s)+ SO3(g) is K = [CuO(s)][SO3(g)]/[CuSO4(s)].

(True/False)
4.9/5
(86)

For the reaction NH3(g)+ H2S(g) →NH4HS(s) Kc = 9.7 at 900 K.If the initial concentrations of NH3(g)and H2S(g)are 2.0 M,what is the equilibrium concentration of NH3(g)?

(Multiple Choice)
4.7/5
(77)

At 25 ∘\circ C,Kc = 1.58 * 10-8 for the reaction NH4(NH2CO2)(s)b 2NH3(g)+ CO2(g) Calculate K at 25 ∘\circ C for this reaction.

(Multiple Choice)
4.7/5
(71)
Showing 41 - 60 of 94
close modal

Filters

  • Essay(0)
  • Multiple Choice(0)
  • Short Answer(0)
  • True False(0)
  • Matching(0)