Exam 10: Physical Equilibria

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Estimate the enthalpy of vaporization of CCl4 given that at 25 ∘\circ C and 58 ∘\circ C its vapor pressure is 107 and 405 Torr,respectively.Assume that the enthalpy of vaporization is independent of the temperature.

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Calculate the number of moles of oxygen that will dissolve in 45 L of water at 20 ∘\circ C if the partial pressure of oxygen is 0.21 atm.Henry's constant for oxygen is 0.0013 mol.L-1.atm-1.

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Which of the following has the highest vapor pressure?

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The freezing point of seawater is about -1.85 ∘\circ C.If seawater is an aqueous solution of sodium chloride,calculate the molality of seawater.The kf for water is 1.86 K/m.

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What is the molality of carbon tetrachloride in a solution of toluene,given that the mole fraction is 0.200?

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The phase diagram for a pure substance is shown below. The phase diagram for a pure substance is shown below.   At 100 atm and 250 K,the substance exists as At 100 atm and 250 K,the substance exists as

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The lattice enthalpy and the enthalpy of hydration are both always positive.

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Aqueous ammonia (28%)is 15.0 M and has a density of 0.90 g.mL-1.Calculate the molality of ammonia in this solution.

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What is the vapor pressure of carbon disulfide at its normal boiling point?

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In a pressure cooker,the boiling point of water is less than 100 ∘\circ C.True or false?

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Which of the following pairs have a vant Hoff i factor of 2?

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In a solution of NaClO4 prepared by dissolving 125 g of sodium perchlorate monohydrate in 500.0 g water,what is the solution molality?

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The vapor pressure of water at 37 ∘\circ C is 47.1 Torr and its enthalpy of vaporization is 44.0 kJ.mol-1 .Estimate the vapor pressure of water at 87 ∘\circ C.Assume that the enthalpy of vaporization of water is independent of temperature.

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Blood,sweat,and tears are about 0.15 M in sodium chloride.Estimate the osmotic pressure of these solutions at 37 ∘\circ C.The gas constant is 0.0821 L.atm.mol-1.K-1.

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The phase diagram for a pure substance is given below.What is the critical temperature? The phase diagram for a pure substance is given below.What is the critical temperature?

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The vapor pressure of methanol at 25 ∘\circ C is 123 Torr and its enthalpy of vaporization is 35.3 kJ.mol-1 .Estimate the normal boiling point of methanol.Assume the enthalpy of vaporization is independent of temperature.

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For AlF3,the lattice enthalpy is 5220 kJ.mol-1 and the enthalpy of solution is -27 kJ.mol-1 at 25 ∘\circ C.Calculate the enthalpy of hydration of AlF3 at this temperature.

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A plot of ln(vapor pressure)versus 1/T for methanol gives a straight line with an intercept of 13.6.The enthalpy of vaporization of methanol is

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The phase diagram for a pure compound is shown below.The triple point occurs at The phase diagram for a pure compound is shown below.The triple point occurs at

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The phase diagram for a pure substance is given below.The solid sublimes The phase diagram for a pure substance is given below.The solid sublimes

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