Exam 13: Aqueous Equilibria

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The curve for the titration of 50.0 mL of 0.0200 M C6H5COOH(aq)with 0.100 M NaOH(aq)is given below.What are the main species in the solution after 7.5 mL of base have been added? The curve for the titration of 50.0 mL of 0.0200 M C<sub>6</sub>H<sub>5</sub>COOH(aq)with 0.100 M NaOH(aq)is given below.What are the main species in the solution after 7.5 mL of base have been added?

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You have available the following reagents as 0.10 M aqueous solutions: NaOH,HCl,phenol (pKa = 9.89),aniline (pKb = 9.37),HNO2 (pKa = 3.37),CH3NH2 (pKb = 3.44).Which two reagents would you use to make a buffer with a pH of 10.5?

(Multiple Choice)
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Which of the following indicators would be most suitable for the titration of 0.10 M (CH3)3N(aq)with 0.10 M HClO4(aq)? For trimethyamine,pKb = 4.19.

(Multiple Choice)
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A buffer solution contains 0.25 M NaNO2(aq)and 0.80 M HNO2(aq)(pKa = 3.37).What is the pH after 0.10 mol HBr are added to 1.00 L of this buffer?

(Multiple Choice)
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The following compounds are available as 0.10 M aqueous solutions. The following compounds are available as 0.10 M aqueous solutions.   Pick two solutions that could be used to prepare a buffer with a pH of ~ 4. Pick two solutions that could be used to prepare a buffer with a pH of ~ 4.

(Short Answer)
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How many moles of KOH(s)must be added to 1.00 L of 0.782 M HF(aq)to produce a buffer with a pH = 4.00?

(Short Answer)
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What is the equilibrium constant for the titration reaction involving HClO4(aq)and Ba(OH)2(aq)?

(Multiple Choice)
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If 10.0 mmol of sodium hydroxide is added to 1.00 L of a buffer that is 0.200 M HClO(aq)and 0.155 M NaHClO(aq),the final concentrations of HClO(aq)and ClO-(aq),respectively,are

(Multiple Choice)
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If equal volumes of 0.004 M Pb(NO3)2(aq)and 0.004 M KI(aq)are mixed,what reaction,if any,occurs? The value of Ksp for PbI2 is 1.4 * 10-8.

(Multiple Choice)
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What is the pH of an aqueous solution that is 0.10 M HCOOH (Ka =1.8 * 10-4)and 0.10 M NaHCO2?

(Multiple Choice)
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A buffer solution contains 0.75 mol KH2PO4 and 0.75 mol K2HPO4.What is the pH after 0.10 mol KOH is added to 1.00 L of this buffer? The pKa of H2PO4- is 7.21.

(Multiple Choice)
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The Ksp for mercury(I)iodide is 1.2 * 10-28.What is the solubility of mercury(I)iodide?

(Multiple Choice)
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What is the main factor that determines the pH of any buffer?

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A buffer contains equal concentrations of a weak acid,HA,and its conjugate base,A-.If the value of Ka for HA is 1.0 * 10-9,what is the pH of the buffer?

(Multiple Choice)
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You have available the following reagents as 0.10 M aqueous solutions: NaOH,HCl,HCN (pKa = 9.31),aniline (pKb = 9.13),HNO2 (pKa = 3.25),and CH3NH2 (pKb = 3.34).Which two reagents would you use to make a buffer with a pH of 10.6?

(Multiple Choice)
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A buffer solution contains 0.0200 M acetic acid and 0.0200 M sodium acetate.What is the pH after 2.0 mmol of NaOH are added to 1.00 L of this buffer? pKa = 4.75 for acetic acid.

(Multiple Choice)
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Consider the titration of 15.0 mL of 0.200 M H3PO4(aq)with 0.200 M NaOH(aq).What is/are the major species in solution after the addition of 30.0 mL of base?

(Multiple Choice)
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What is the equilibrium constant for the reaction HCN(aq)+ OH-(aq) →CN-(aq)+ H2O(l)

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A solution is prepared by mixing equal volumes of 0.40 M HF(aq)with 0.20 M KOH(aq).This solution is a buffer.

(True/False)
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What is the equilibrium constant for the titration reaction involving CH3NH2(aq)and HBr(aq)?

(Multiple Choice)
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