Exam 27: Synthetic Polymers

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Kevlar is an example of ________.

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Give the product of the following polymerization. Give the product of the following polymerization.

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Show how branching could occur during the free-radical polymerization of styrene.

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Name the monomer used in the production of neoprene.

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Explain why some monomers are better able to undergo chain-growth polymerization by a radical mechanism.

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Draw the monomer for poly(vinyl acetate).

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Describe what plasticizers are and give an example.

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List the two main groups of polymers and give one example of each.

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Which of the following is more likely to form non-terminated polymeric chains called living polymers?

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A substituted ethylene polymer in which the substituents are randomly oriented is called ________.

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Draw the structure of Nylon 66.

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When 2,2-dimethyloxirane (see figure below)undergoes anionic polymerization, the nucleophile attacks the least substituted carbon of the epoxide, but when it undergoes cationic polymerization, the nucleophile attacks the most substituted carbon of the epoxide. Explain why this is so. When 2,2-dimethyloxirane (see figure below)undergoes anionic polymerization, the nucleophile attacks the least substituted carbon of the epoxide, but when it undergoes cationic polymerization, the nucleophile attacks the most substituted carbon of the epoxide. Explain why this is so.

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From which of the following monomers is neoprene synthesized?

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Identify the monomers that undergo cationic polymerization.

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What is the structure of the monomer from which the following polymer is made? What is the structure of the monomer from which the following polymer is made?

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What is the structure of the monomer from which the following polymer is made? What is the structure of the monomer from which the following polymer is made?    What is the structure of the monomer from which the following polymer is made?

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Propose a mechanism for the following polymerization reaction: Propose a mechanism for the following polymerization reaction:

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Chain-growth polymerization exhibits a marked preference for ________.

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Identify the monomers that undergo radical polymerization.

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What monomers formed the following polymer? What monomers formed the following polymer?    What monomers formed the following polymer?

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