Exam 5: Alkenes Thermodynamics and Kinetics

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Given an activation energy of 15 kcal/mol, use the Arrhenius equation to estimate how much faster the reaction will occur if the temperature is increased from Given an activation energy of 15 kcal/mol, use the Arrhenius equation to estimate how much faster the reaction will occur if the temperature is increased from   to   R = 1.987 cal/mol ∙ K. to Given an activation energy of 15 kcal/mol, use the Arrhenius equation to estimate how much faster the reaction will occur if the temperature is increased from   to   R = 1.987 cal/mol ∙ K. R = 1.987 cal/mol ∙ K.

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Draw the structure of (Z)-4-ethyl-3-methylheptene.

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Based on the following energy diagram, which compound, A or C, is formed faster from B? Which is more stable, A or C? Explain. Based on the following energy diagram, which compound, A or C, is formed faster from B? Which is more stable, A or C? Explain.

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Which of the following is not a nucleophile?

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Draw (E)-2-methyl-3-hexen-1-ol.

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Consider the single step interconversion of A and B shown below. How is the equilibrium constant K related to the rate constants k1 and k -1 and to the amounts of A and B present at equilibrium? Consider the single step interconversion of A and B shown below. How is the equilibrium constant K related to the rate constants k<sub>1</sub> and k <sub>-1</sub> and to the amounts of A and B present at equilibrium?

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Calculate the enthalpy for the following reaction. Calculate the enthalpy for the following reaction.   DH CH<sub>2</sub>=CH<sub>2</sub>, 62 kcal/mole H-Cl, 103 kcal/mole CH<sub>3</sub>CH<sub>2</sub>-H, 101 kcal/mole CH<sub>3</sub>CH<sub>2</sub>-Cl, 85 kcal/mole DH CH2=CH2, 62 kcal/mole H-Cl, 103 kcal/mole CH3CH2-H, 101 kcal/mole CH3CH2-Cl, 85 kcal/mole

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Give the possibilities in structure for a compound with a formula of C6H10.

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Draw the structure of propyl vinyl ether.

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Draw the curved arrows to show how CH3CH=CHCH3 reacts with HBr to form a carbocation.

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Give the mechanism for the following reaction. Give the mechanism for the following reaction.

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A hydrocarbon with molecular formula C20H34 has what degree of substitution?

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Name the structure. Name the structure.

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Consider the one-step conversion of F to G. Given that the reaction is endergonic by 5 kcal/mol and that the energy difference between G and the transition state for the process is 15 kcal/mol, sketch a reaction-energy profile for this reaction. Make sure to show how the given energy differences are consistent with your sketch.

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How many transition states are present in the following reaction diagram? How many transition states are present in the following reaction diagram?

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Provide the IUPAC name for the alkene shown below. Provide the IUPAC name for the alkene shown below.

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Provide the systematic name of the alkene below. Provide the systematic name of the alkene below.

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Identify the nucleophiles and electrophiles. -OH, BH3, H2O, +CH3, NH3, Br-

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Draw vinyl bromide.

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What is the value of ΔH in kcal/mole for the reaction shown? (CH3)3C-H + Cl-Cl → (CH3)3C-Cl + H-Cl Bond energies are: (CH3)3C-H = 91 kcal/mole (CH3)3C-Cl = 78.5 kcal/mole Cl-Cl = 58 kcal/mole H-Cl = 103 kcal/mole

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