Exam 14: Aqueous Equilibria: Acids and Bases

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Vinegar is a 5.0% solution by weight of acetic acid (CH3CO2H)in water.Given that the pH for acetic acid is 2.41,the Ka = 1.8 × 10-5 and assuming the density of vinegar to be 1.00 g/cm3,what is the percent dissociation of acetic acid in vinegar?

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Para-Aminobenzoic acid (PABA),p-H2NC6H4(COOH),is used in some sunscreens and hair conditioning products.Calculate the pH of an aqueous solution with [PABA] = 0.030 M and Ka = 2.2 × 10-5.

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A solution with a hydrogen ion concentration of 3.25 × 10-2 M is ________ and has a hydroxide concentration of ________.

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  -Of the elements indicated on the periodic table shown above,which forms the strongest binary acid,H<sub>2</sub>X or HX,where X = A,B,C,or D? -Of the elements indicated on the periodic table shown above,which forms the strongest binary acid,H2X or HX,where X = A,B,C,or D?

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Aniline, (C6H5NH2,Kb = 4.3 × 10-10 at 25°C)is an industrially important amine used in the making of dyes.Determine the pH of an aniline solution made by dissolving 6.90 g of aniline in enough water to make 100 mL of solution.

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  -Of the elements indicated on the periodic table shown above,which forms the weakest oxoacid acid with the formula H<sub>2</sub>XO<sub>3</sub> or HXO<sub>3</sub>,where X = A,B,C,or D? -Of the elements indicated on the periodic table shown above,which forms the weakest oxoacid acid with the formula H2XO3 or HXO3,where X = A,B,C,or D?

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If an equal number of moles of the weak acid HCN and the strong base KOH are added to water,is the resulting solution acidic,basic,or neutral?

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The following pictures represent aqueous solutions of three acids HA (A = X,Y,or Z);water molecules have been omitted for clarity. The following pictures represent aqueous solutions of three acids HA (A = X,Y,or Z);water molecules have been omitted for clarity.   -Which acid solution has the lowest pH? -Which acid solution has the lowest pH?

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What is the conjugate acid of the Br∅nsted-Lowry base HAsO42-?

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The following pictures represent equal volumes of aqueous solutions of three acids HA (A = X,Y,or Z);water molecules have been omitted for clarity. The following pictures represent equal volumes of aqueous solutions of three acids HA (A = X,Y,or Z);water molecules have been omitted for clarity.   -Arrange the acids in order of increasing value of K<sub>a</sub>. -Arrange the acids in order of increasing value of Ka.

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Determine the acid dissociation constant for a 0.010 M nitrous acid solution that has a pH of 2.70.Nitrous acid is a weak monoprotic acid and the equilibrium equation of interest is HNO2(aq)+ H2O(l)⇌ H3O+(aq)+ NO2-(aq).

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What is the approximate pH of a solution X that gives the following responses with the indicators shown? What is the approximate pH of a solution X that gives the following responses with the indicators shown?

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Calculate the pH of a 0.60 M H2SO3,solution that has the stepwise dissociation constants Ka1 = 1.5 × 10-2 and Ka2 = 6.3 × 10-8.

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The pH of 0.255 M HCN is 4.95.What is the value of Ka for hydrocyanic acid?

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Which Br∅nsted-Lowry acid has the strongest conjugate base?

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Which of the following Br∅nsted-Lowry acids does not behave as a strong acid when it is dissolved in water?

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In order for the reaction HA + HSO3- ⇌ A- + H2SO3 to have an equilibrium constant Kc < 1,the Ka of HA must be ________ (greater,less)than the Ka of HSO3-.

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What is the selenide ion concentration [Se2-] for a 0.100 M H2Se solution that has the stepwise dissociation constants of Ka1 = 1.3 × 10-4 and Ka2 = 1.0 × 10-11?

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At the normal body temperature of 37°C,Kw = 2.42 × 10-14.The H3O+ concentration of normal blood ranges from 3.5 × 10-8 to 4.5 × 10-8.The OH- concentration of normal blood ranges from ________ to ________,and blood is ________ (acidic,basic,neutral).

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Potassium hydrogen phthalate (molar mass = 204.2 g/mol)is one of the most commonly used acids for standardizing solutions containing bases.KHP is a monoprotic weak acid with Ka = 3.91 × 10-6.Calculate the pH of the solution that results when 0.40 g of KHP is dissolved in enough water to produce 25.0 mL of solution.

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