Exam 7: Energy, Rate and Equilibrium

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The rate of a chemical reaction increases with an increase in concentration of one or more of the reactants.This is best explained by which of the following statements?

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When a sample of aqueous hydrochloric acid was neutralized with aqueous sodium hydroxide in a calorimeter, the temperature of 100.0 g of water surrounding the reaction increased from 25.0°C to 31.5°C.If the specific heat of water is 1.00 cal/(g•°C), calculate the quantity of energy in calories involved in this neutralization reaction.

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Consider the reversible reaction: Consider the reversible reaction:   What is the correct expression for the equilibrium constant, Keq, for this reaction? What is the correct expression for the equilibrium constant, Keq, for this reaction?

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For the reaction A(g) → 2B(g), Keq = 4.5 × 105.Which statement is TRUE for the system at equilibrium?

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Which of the following pairs of substances has the substance with the highest entropy listed first?

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Which of the following statements concerning the reaction below is FALSE? 2HgO(s) → 2Hg(l) + O2(g) ∆H = 182 kJ

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One effect of a catalyst being added to a reaction mixture is

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The equilibrium constant expression for a reaction can be written if the balanced equation is known.

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A reaction that leads to an increase in the entropy of the system is always spontaneous.

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A carbohydrate sample weighing 0.235 g was found to have a fuel value of 3.84 kJ.What is the fuel value of one gram of this carbohydrate, in nutritional Calories?

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A catalyst increases the equilibrium constant for a reaction.

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Which one of the following, if changed, would change the value of the equilibrium constant, Keq, of a reaction?

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How many small calories are equivalent to one nutritional Calorie?

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Which statement concerning a reversible reaction at equilibrium is FALSE?

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Endothermic reactions are never spontaneous.

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In kinetics, the order of a reaction

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Which statement concerning energy changes in chemical reactions is FALSE?

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Ethylene glycol has a specific heat of 0.578 cal/(g•°C).If 23.2 g of ethylene glycol absorbs 75.6 cal of heat energy, what will the temperature increase be?

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Changing the temperature alters the value of the equilibrium constant for a reaction.

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A reaction that leads to a decrease in the enthalpy of the system is always spontaneous.

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