Exam 7: Energy, Rate and Equilibrium

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Consider the decomposition of calcium carbonate shown below.Which of the following statements correctly describes this reaction as it occurs in a test tube? CaCO3(s) + 42.5 kcal → CaO(s) + CO2(g)

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B

When a cold-pack is activated, a chemical reaction occurs and the temperature of the pack contents drops sharply.Which of the following is a correct description of the reaction occurring in the pack?

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C

Lowering the activation energy of a reaction will increase its rate.

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True

According to the second law of thermodynamics, a system and its surroundings spontaneously tend toward increasing order.

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In general, which state of matter has the lowest entropy?

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In general, a liquid state will have higher entropy than a solid state.

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What instrument is used for measuring the heat energy absorbed or released in a chemical reaction?

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The reaction shown below is at equilibrium.Use LeChatelier's principle to predict the effect of adding ammonia gas to the equilibrium reaction mixture. The reaction shown below is at equilibrium.Use LeChatelier's principle to predict the effect of adding ammonia gas to the equilibrium reaction mixture.

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Which of the following statements concerning the reversible reaction below is FALSE? Which of the following statements concerning the reversible reaction below is FALSE?

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The formation of rust (Fe2O3) on an exposed piece of metal typically takes several months.Which of the following statements is NOT a reasonable assumption about this chemical reaction? 4Fe(s) + 3O2(g) → 2Fe2O3(s)

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What is the term used to describe the energy barrier the reactants must overcome in order to form products in a chemical reaction?

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Which term describes the measure of the randomness or disorder of a chemical system?

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In the industrial synthesis of ammonia, the equilibrium constant expression may be written as: In the industrial synthesis of ammonia, the equilibrium constant expression may be written as:   Calculate the value of this equilibrium constant, if the equilibrium concentration of nitrogen in the reaction mixture at 600°C if [N<sub>2</sub>] = 4.53 M; [H<sub>2</sub>] = 2)49 M; and [NH<sub>3</sub>] = 7.62 M. Calculate the value of this equilibrium constant, if the equilibrium concentration of nitrogen in the reaction mixture at 600°C if [N2] = 4.53 M; [H2] = 2)49 M; and [NH3] = 7.62 M.

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The amount of heat necessary to raise 1 gram of a substance by 1 degree Celsius is known as which of the following?

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A reversible reaction is said to have reached equilibrium when which of the following conditions is established?

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The order of a reaction with respect to any reactant is shown in the rate equation.

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Which one of the following actions can alter the activation energy of a reaction?

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Which statement concerning energy changes in chemical reactions is FALSE?

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Exothermic reactions are always spontaneous.

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Reactants and products that are aqueous solutions do not appear in the equilibrium constant expression.

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