Exam 7: Energy, Rate and Equilibrium

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A candy sample is completely combusted in a bomb calorimeter.The calorimeter contains 982 g of water, and the measured temperature increase is 2.62°C.What is the fuel value of the candy sample in nutritional Calories? [SHw = 1.00 cal/g•°C]

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What is the name and symbol of the thermodynamic quantity that represents the heat absorbed or liberated in a chemical reaction at constant pressure?

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A reaction will be spontaneous at all temperatures under which conditions?

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What thermodynamic quantity is the ultimate predictor of reaction spontaneity?

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A collision between reactant molecules that produces one or more product molecules is called an effective collision.

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Which of the following will NOT increase the rate of a reaction?

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Removal of a gaseous product from an equilibrium reaction mixture shifts the equilibrium toward formation of more products.

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In the potential energy diagram for a chemical reaction, what is the name used for the unstable species corresponding to the top of the energy barrier separating reactants from products?

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Thermodynamics is best described as which of the following?

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Which of the following is a process with a negative ∆S?

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A reaction that leads to a decrease in the free energy of the system is always spontaneous.

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Which of the following represents an exothermic reaction?

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10.0 grams of octane are burned in a bomb calorimeter containing 2.00 × 102 g H2O.If the water temperature increases from 25.00oC to 37.00oC, how much energy was released by the system?

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Which of the following is the equilibrium constant expression for the reaction? 2NO(g) + O2(g) → 2NO2(g)

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Under normal conditions, which of the following would have the highest entropy?

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LeChatelier's principle states that if a stress is placed on a system at equilibrium, the system will respond by altering the equilibrium composition in such a way as to relieve the stress.

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Which of the following is FALSE about the energy diagram shown? Which of the following is FALSE about the energy diagram shown?

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Which of the following is a TRUE statement concerning the specific heat of a substance?

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A granola bar contains 185 nutritional Calories.How many kilojoules is this? [1 cal = 4.18 J]

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Ammonia is synthesized industrially by the reaction of nitrogen and hydrogen in the presence of an iron catalyst according to the reaction equation below.What effect would removing the iron catalyst have on this reaction? Ammonia is synthesized industrially by the reaction of nitrogen and hydrogen in the presence of an iron catalyst according to the reaction equation below.What effect would removing the iron catalyst have on this reaction?

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